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Rekha Dom,Pramod H. Borse,Kyong-Soo Hong,Seyong Choi,Byeong Seob Lee,Myoung Gyu Ha,Jong Pil Kim,Euh Duck Jeong,Hyun Gyu Kim 한국물리학회 2015 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.67 No.9
Magnesium ferrite (MgFe2O4) exhibiting a spinel phase was synthesized by using the polymerized complex and the solid-state reaction methods, and its physico-chemical properties were studied to explore the water-splitting under visible light photons. The study revealed the potential for using MgFe2O4 particles for photo-catalytic application. The structural study provided information on ferrite nano-crystallites fabricated by using the polymer complex method. The morphological studies demonstrated that, in contrast to the solid-state reaction method, a homogenous, monodispersed ferrite photocatalyst could be formed by using the polymerized complex method. The optical study revealed a larger visible-light absorption capability for the nanosized MgFe2O4 photocatalysts prepared by using the polymer complex methods, and indicated a red-shift of the bandgap by 0.06 eV as compared to the bandgap of the bulk. These nanocrystallites were highly photoactive with respect to the photodegradation and photocatalytic hydrogen evolution applications. The electrochemical analysis showed that they exhibited favorable bandedge positions suitable for photocatalytic H2 evolution. Thus, nanocrystalline MgFe2O4 is an active visible-light photocatalyst, that might be useful for the decomposition of water.
Design and Analysis of a Frequency Reconfigurable Penta-Band Antenna for WLAN and 5G Applications
Rekha Shanmugam 한국전자파학회JEES 2021 Journal of Electromagnetic Engineering and Science Vol.21 No.3
This paper presents a discussion on a low-profile, frequency-reconfigurable penta-band antenna. This antenna consists of two asymmetric L-shaped rectangular patches electrically connected by a single PIN diode. The proposed antenna operates at five frequency bands depending upon the switching states of the PIN diode. It operates at 2.4 ㎓ (WLAN) and 5.3 ㎓ (5G) during forward bias of the diode, 3.3 ㎓ (5G) and 5.9 ㎓ (WLAN) during reverse bias of the diode and 4 ㎓ during zero bias condition providing a wide bandwidth (3.6–4.8 ㎓) at this state. The antenna has voltage standing wave ratio (VSWR) ranges from 1 to 2, gain value ranges from 2.6 to 5.0 ㏈i, and a maximum radiation efficiency of 85%. This antenna can be integrated with modern devices such as smart phones, laptops, and other handheld devices due to its simplistic geometry. A prototype of the model is fabricated, and the results are validated.
Leaching of rare earth metals (REMs) from Korean monazite concentrate
Rekha Panda,Manis Kumar Jha,이진영,Archana Kumari,Jhumki Hait,Vinay Kumar,J. Rajesh Kumar 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.4
Systematic scientific studies for dephosphorization and acid leaching of Korean monazite are reported here. 50% NaOH (w/v) solubilizes 99.99% phosphate, at 170 ℃, 100 g/L pulp density in 4 h. Kinetics of phosphate leaching fitted well with model ‘‘chemical reaction control,’’ i.e. 1 - (1 - X)1/2 = kct, Ea = 58.04 kJ/mol. Further, rare earth hydroxides (REHs) was leached using 6 N HCl at 90 ℃, 60 g/L pulp density for 2 h to recover ~95% REMs. Leach liquor generated can be further processed using solvent extraction/ion exchange techniques. From the pure solutions, metal/salts could be obtained using evaporation, precipitation, etc.
Performance of fly ash stabilized clay reinforced with human hair fiber
Rekha, L. Abi,Keerthana, B.,Ameerlal, H. Techno-Press 2016 Geomechanics & engineering Vol.10 No.5
Industrialization and urbanization are the two phenomena that are going relentless all over the world. The consequence of this economic success has been a massive increase in waste on one hand and increasing demand for suitable sites for construction on the other. Owing to the surplus raw materials and energy requirement needed for manufacturing synthetic fibers, applications of waste fibers for reinforcing soils evidenced to offer economic and environmental benefits. The main objective of the proposed work is to explore the possibilities of improving the strength of soil using fly ash waste as an admixture and Human Hair Fiber (HHF) as reinforcement such that they can be used for construction of embankments and land reclamation projects. The effect of fiber content on soil - fly ash mixture was observed through a series of laboratory tests such as compaction tests, CBR and unconfined compression tests. From the stress - strain curves, it was observed that the UCC strength for the optimised soil - flyash mixture reinforced with 0.75% human hair fibers is nearly 2.85 times higher than that of the untreated soil. Further, it has been noticed that there is about 7.73 times increase in CBR for the reinforced soil compared to untreated soil. This drastic increase in strength may be due to the fact that HHF offer more pull-out resistance which makes the fibers act like a bridge to prevent further cracking and thereby it improves the toughness which in turn prevent the brittle failure of soil-flyash specimen. Hence, the test results reveal that the inclusion of randomly distributed HHF in soil significantly improves the engineering properties of soil and can be effectively utilized in pavements. SEM analysis explained the change of microstructures and the formation of hydration products that offered increase in strength and it was found to be in accordance with strength tests.