Selective hydrogenation of furfural to cyclopentanone over Cu-Ni-Al hydrotalcite-based catalysts

Hongyan Zhu,Guomin Xiao,Minghao Zhou,Zuo Zeng,Rui Xiao 한국화학공학회 2014 Korean Journal of Chemical Engineering Vol.31 No.4

A series of Cu-Ni-Al hydrotalcites derived oxides with a (Cu+Ni)/Al mole ratio of 3 with varied Cu/Nimole ratio (from 0.017 to 0.5, with a Cu ratio of 0.0125 to 0.25) were prepared by co-precipitation method, then appliedto the hydrogenation of furfural in aqueous. Their catalytic performance for liquid phase hydrogenation of furfural toprepare cyclopentanone was described in detail, considering reaction temperature, catalyst composition, reaction timeand so on. The yield of cyclopentanone was influenced by the mole ratio of Cu-Ni-Al based heterogeneous catalystand depended on the reaction conditions. The yield of cyclopentanone was up to 95.8% when the reaction was carriedout under 413 K with H2 pressure of 40 bar for 8 h. The catalysts were characterized by X-ray powder diffraction (XRD),scanning electron microscope (SEM) and H2 temperature-programmed reduction (H2-TPR).

Research on facility layout optimization algorithm of deep-water semi-submersible drilling platform

Hongyan Wang,Wensheng Xiao,Lei Wu,Keke Wei,Congcong Xu,Chao Hou,Junguo Cui,Jie Li 대한기계학회 2019 JOURNAL OF MECHANICAL SCIENCE AND TECHNOLOGY Vol.33 No.2

We aimed to create a facility layout design of semi-submersible drilling platform (DSDP) with performance constraints. The Boltzmann survival mechanism of simulated annealing algorithm was introduced into the replacement strategy of genetic algorithm to form an improved genetic algorithm called genetic and simulated annealing algorithm (GASA). The new algorithm alleviates the “combination explosion” and premature convergence of the traditional genetic algorithm. The layout problem of DSDP is efficiently solved by using this new algorithm. When the number of layout objects increases, GASA’s performance is better than that of the genetic algorithm.

A newly characterized exopolysaccharide from Sanghuangporus sanghuang

Xiao-kui Ma,Xu She,Eric Charles Peterson,Yu Zhen Wang,Peng Zheng,Hongyan Ma,Kexin Zhang,Jian Liang 한국미생물학회 2019 The journal of microbiology Vol.57 No.9

Sanghuangporus sanghuang is a well-known pharmacodynamic and economically important edible fungus associated with mulberry (Morus spp.). A distinctly new exopolysaccharide (EPS), designated SHP-2 was obtained from S. sanghuang P0988 broth, and its structure and anti-aging prosperity were characterized. SHP-2 was found to be composed of a backbone of 4)-β-Manp-(1 4)-α-Araf-(1 3,4)-α-Glcp(1 3,4)-α-Glcp-(1 3,4)-α-Glcp-(1 3,4)-α-Glcp-(1 3,4)-α- Glcp-(1 6)-α-Galp-(1 4)-β-Manp-(1 and five branches, including four α-D-Glcp-(1 and one α-D-Manp-(1 SHP-2 was shown to increase antioxidant enzyme activities including catalase (CAT) and superoxide dismutase (SOD) activities, as well as trolox equivalent antioxidant (TEAC) capacity in serum of mice pre-treated with D-Gal, while reducing lipofuscin levels. SHP-2 exerted a favorable influence on immune organ coefficients and ameliorated the histopathological hepatic lesions and apoptosis in hepatocytes of Dgalactose- aged mice almost in a dose-dependent manner. Using the same analytical methods, on comparison with previously studied EPS compounds (i.e. SHP-1), SHP-2 was found to have more complex structure, larger molecule weight, and different anti-aging properties. The results presented here suggest that not only does EPS bioactivity vary with respect to molecular structures and molecule weight, but that multiple structures with different activity can be expressed by a single fungal strain. These results may help understanding the antiaging prosperity of these polysaccharides for use in health foods or dietary supplements.

Degradation of Lignocelluloses in Rice Straw by BMC-9, a Composite Microbial System

( Hongyan Zhao ),( Hai Ru Yu ),( Xu Feng Yuan ),( Ren Zhe Piao ),( Hu Lin Li ),( Xiao Fen Wang ),( Zong Jun Cui ) 한국미생물 · 생명공학회 2014 Journal of microbiology and biotechnology Vol.24 No.5

To evaluate the potential utility of pretreatment of raw biomass with a complex microbial system, we investigated the degradation of rice straw by BMC-9, a lignocellulose decomposition strain obtained from a biogas slurry compost environment. The degradation characteristics and corresponding changes in the bacterial community were assessed. The results showed that rapid degradation occurred from day 0 to day 9, with a peak total biomass bacterium concentration of 3.3 × 10(8) copies/ml on day 1. The pH of the fermentation broth declined initially and then increased, and the mass of rice straw decreased steadily. The highest concentrations of volatile fatty acid contents (0.291 mg/l lactic acid, 0.31 mg/l formic acid, 1.93 mg/l acetic acid, and 0.73 mg/l propionic acid) as well as the highest xylanse activity (1.79 U/ml) and carboxymethyl cellulase activity (0.37 U/ml) occurred on day 9. The greatest diversity among the microbial community also occurred on day 9, with the presence of bacteria belonging to Clostridium sp., Bacillus sp., and Geobacillus sp. Together, our results indicate that BMC-9 has a strong ability to rapidly degrade the lignocelluloses of rice straw under relatively inexpensive conditions, and the optimum fermentation time is 9 days.

An Improved Soft Actor-Critic-Based Energy Management Strategy of Fuel Cell Hybrid Vehicles with a Nonlinear Fuel Cell Degradation Model

Dongfang Zhang,Yunduan Cui,Yao Xiao,Shengxiang Fu,Suk Won Cha,Namwook Kim,Hongyan Mao,Chunhua Zheng 한국정밀공학회 2024 International Journal of Precision Engineering and Vol.11 No.1

With the rapid development of artificial intelligence, deep reinforcement learning (DRL)-based energy management strategies (EMSs) have become an important research direction for hybrid electric vehicles recently, which still face some problems such as fragile convergence characteristics, slower convergence speed, and unsatisfactory optimization effects. In this research, a novel DRL algorithm, i.e. an improved soft actor-critic (ISAC) algorithm is applied to the EMS of a fuel cell hybrid vehicle (FCHV), in which the priority experience replay (PER) and emphasizing recent experience (ERE) methods are adopted to improve the convergence performance of the algorithm and to enhance the FCHV fuel economy. In addition, the fuel cell durability is also considered in the proposed EMS based on a nonlinear fuel cell degradation model while considering the fuel economy. Results indicate that the FCHV fuel consumption of the proposed EMS is decreased by 7.87%, 2.79%, and 2.44% compared to that of the deep deterministic policy gradient (DDPG)-based, the twin delayed deep deterministic policy gradient (TD3)-based, and the SAC-based EMSs respectively while the fuel consumption gap to the dynamic programming-based EMS is narrowed to 2.37% by the proposed EMS. Moreover, the proposed EMS presents the best training performance considering both the convergence speed and stability, and the convergence speed of the proposed EMS is increased by an average of 47.89% compared to that of the other DRL-based EMSs. Furthermore, the fuel cell durability is improved by more than 95% using the proposed EMS compared to that of the EMS without considering the fuel cell degradation.

Oridonin Alleviates Visceral Hyperalgesia in a Rat Model of Postinflammatory Irritable Bowel Syndrome: Role of Colonic Enterochromaffin Cell and Serotonin Availability

Kai-hong Zang,Yun-yun Shao,Xiao Zuo,Zhi Rao,Hongyan Qin 한국식품영양과학회 2016 Journal of medicinal food Vol.19 No.6

The aim of this present study was to investigate the effect of oridonin on visceral hyperalgesia and colonic serotonin availability in a rat model of trinitrobenzenesulfonic acid-induced postinflammatory irritable bowel syndrome (PI-IBS). Rats were randomly divided into five groups: normal control, PI-IBS model, PI-IBS+low-dose oridonin (5 mg/kg), PI-IBS+median-dose oridonin (10 mg/kg), and PI-IBS+high-dose oridonin (20 mg/kg). Rats in control and model groups were orally administered with water by gavage, whereas rats in oridonin-treated groups were orally administered with different dosages of oridonin, and drugs were given for 14 consecutive days. Compared with the control group, the pain threshold pressure was significantly reduced in PI-IBS rats. The colonic enterochromaffin (EC) cell number, serotonin content, and the protein expression of tryptophan hydroxylase (TPH) were markedly increased and the protein expression of serotonin reuptake transporter was significantly decreased in PI-IBS rats. The spleen index in PI-IBS rats was decreased, and the levels of tumor necrosis factor (TNF)-α, interferon (IFN)-γ, interleukin (IL)-4, and IL-13 in the colon of PI-IBS rats were also markedly decreased. Oridonin treatment dose dependently increased pain threshold pressure, and markedly decreased colon EC cell numbers, TPH expression, and serotonin content in PI-IBS rats. Oridonin treatment also significantly increased the spleen index as well as the levels of TNF-α, IFN-γ, IL-4, and IL-13 in the colon of PI-IBS rats. Results of this study demonstrate that the analgesic effect of oridonin in PI-IBS rats is associated with reduced colonic EC cell hyperplasia and 5-HT availability, the regulatory effect of oridonin on colonic cytokine production may be correlated with its effect on colonic EC cell number.

A prospective randomized multicenter trial for lymphadenectomy in early- stage ovarian cancer: LOVE study

Ting Deng,Kaijiang Liu,Liang Chen,Xiao-jun Chen,Hua Wen Li,Hongyan Guo,Huijiao Zhang,Libing Xiang,Xin Feng,Xiaoyu Wang,Hextan Y. S. Ngan,Jianguo Zhao,Dongling Zou,Qing Liu,Jihong Liu 대한부인종양학회 2023 Journal of Gynecologic Oncology Vol.34 No.3

Background: The Lymphadenectomy in Ovarian Neoplasms (LION) study revealed that systemic lymphadenectomy did not bring survival benefit for advanced ovarian cancer patients with clinically normal lymph nodes and was associated with a higher incidence of operative complications. However, there is no consensus on whether lymphadenectomy has survival benefit or not in early epithelial ovarian cancer (EOC). Methods: We designed the LOVE study, a multicenter, randomized controlled, phase III trial to compare the efficacy and safety of comprehensive staging surgery with or without lymphadenectomy in stages IA-IIB EOC and fallopian tube carcinomas (FTC). The hypothesis is that the oncological outcomes provided by comprehensive staging surgery without lymphadenectomy are non-inferior to those of conventional completion staging surgery in early-stage EOC and FTC patients who have indications for post-operative adjuvant chemotherapy. Patients assigned to experimental group will undergo comprehensive staging surgery, but lymphadenectomy. Patients assigned to comparative group will undergo completion staging surgery including systematic pelvic and para-aortic lymphadenectomy. All subjects will receive 3–6 cycles of standard adjuvant chemotherapy. Major inclusion criteria are pathologic confirmed stage IA-IIB EOC or FTC, and patients have indications for adjuvant chemotherapy either confirmed by intraoperative fast frozen section or previous pathology after an incomplete staging surgery. Major exclusion criteria are non-epithelial tumors and low-grade serous carcinoma. Patients with severe rectum involvement which lead to partial rectum resection will be excluded. The sample size is 656 subjects. Primary endpoint is disease-free survival.

Superhydrophobic Ag/Viscose Non-woven Fabrics with Excellent Electric Heating and High-efficient Electromagnetic Interference Shielding

Shan Jiang,Ce Cui,Weijie Wang,Erhui Ren,Hongyan Xiao,Mi Zhou,Jinzhong Tang,Cheng Cheng,Ronghui Guo 한국섬유공학회 2022 Fibers and polymers Vol.23 No.11

Multifunctional flexible conductive materials have attracted significant attention as next-generation portablewearable electronics. However, designing robust electronics fabrics with high-performance electromagnetic interference(EMI) shielding and reliable use in all-weather environments remains a challenge. Herein, a practical and optimizedmethodology was provided to achieve surface metallization of insulating fabrics for conductive devices. The Ag seeds weresuccessfully embedded on the surface of viscose nonwovens as catalytic centers, and ammonia-free silver plating was carriedout at room temperature. Subsequently, the Ag-wrapped fabric was impregnated with 1-octadecanethiol so that the surface ofthe obtained fabric showed super-hydrophobicity and water contact angle can reach 152.3 °. The Ag/viscose exhibitsultrahigh conductivity (up to 538 S/cm) and the EMI shielding effectiveness (SE) reaches as high as 94.1 dB in the range of1-18 GHz. The obtained Ag/viscose possesses outstanding waterproof, strong mechanical durability, excellent Joule heatingeffect and antibacterial, which can be potentially applied for multifunctional wearable electronics and smart clothing.