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The Band Offset at CdS/Cu2ZnSnS4 Heterojunction Interface
Ji Li,Qingyang Du,Weifeng Liu,Guoshun Jiang,Xuefei Feng,Wenhua Zhang,Junfa Zhu,Changfei Zhu 대한금속·재료학회 2012 ELECTRONIC MATERIALS LETTERS Vol.8 No.4
The band offset at the CdS/Cu2ZnSnS4 heterojunction interface is studied by measuring the valence band spectra using synchrotron radiation photoemission spectroscopy. The Cu2ZnSnS4 thin films are prepared by the sulfurization of electrodeposited Cu-Zn-Sn precursors. A CdS overlayer is sequentially grown on the Cu2ZnSnS4 thin films from a chemical bath deposition process. Valence band spectra were obtained before and after each period of growth to study the electronic structure at the heterojunction interface. The valence band offset was determined to be 0.96 eV, and the conduction band offset was determined to be .0.06 eV. This means that the CdS/Cu2ZnSnS4 hetrojunction has a ‘type II’ band alignment which will cause largescale recombination at the interfaces and will not be suitable for solar cells fabrication.
Changes in structure of coal liquefied pitch during liquid‑phase carbonization process
Yaming Zhu,Xuefei Zhao,Ji Yuan,Chunlei Zhao,Chaoshuai Hu 한국탄소학회 2019 Carbon Letters Vol.29 No.1
residue as the raw material. As one of the preconceived raw material to produce high-quality coal-based carbon material, the changes of structure of CLP during liquid-phase carbonization process have been detailed investigated in this study. Actually, FTIR and curve-fitted method were used to quantitative analyze the aromaticity index (Iar), the ratio of CH3/ CH2, and basic functional groups (C=C, C=O, and C–O) of CLP and its liquid-phase carbonization products. Polarizing microscope, XRD and curve-fitted methods were used to characterize the microstructures of CLP and derived products. The results show that, branched chain and C=O group are the active reaction point in liquid-phase carbonization process. What’s more, 450 °C is a critical temperature point on the severe thermal polycondensation of CLP. The XRD and curve-fitted analysis of CLP and its liquid-phase carbonization products shows that, the stacking height (Lc), parallel layers (N), and the numbers of aromatic ring in each layer (n) are gradually larger with the improve of liquid-phase carbonization temperature.
( Jeong Yoon Kim ),( Ji Hye Lee ),( Yeong Hun Song ),( Won Min Jeong ),( Xuefei Tan ),( Zia Uddin ),( Ki Hun Park ) 한국응용생명화학회 2015 Journal of Applied Biological Chemistry (J. Appl. Vol.58 No.3
Human neutrophil elastase (HNE) represents a good therapeutic target for the treatment of inflammatory diseases as well as invasion of microorganism. The methanol extract of a aerial part of Chelidonium majus L. showed high activity against the neutrophil elastase with an IC50 value of 100 μg/mL. Due to its potency, subsequent bioactivity-guided fractionation of methanol extract led to six alkaloids (1-6), which were identified as dihydrosanguinarine (1), (s)-stylopine (2), arnottianamide (3), (+)-chelidonine (4), spallidamine (5), and N-transferuloyltyramine (6). Among of them, three alkaloids (2, 5, and 6) inhibited HNE in a dose-dependent manner with IC50 ranging between 11.6 and 51.0 μM. Lineweaver-Burk and Dixon plots, and their secondary replots showed that alkaloids (2, 5, and 6) were mixed inhibitors of HNE. The analysis of KI and KIS value proved that all inhibitors (2, 5, and 6) had reversible mixed type I mechanism.
Qing Jiao,Libo Zou,Peng Liu,Qian Xu,Yifei Zhang,Ying Yu,Lu Zou,Tianyan Chi,Xuefei Ji 한국식품영양과학회 2014 Journal of medicinal food Vol.17 No.10
Xanthoceraside, a saponin extracted from the husks of Xanthoceras sorbifolia Bunge, suppresses inflammation and oxidative stress. However, the antitumor properties of xanthoceraside as well as its mechanism of action remain unclear. Therefore, we proposed to investigate its potential anticancer property. In this study, the viability of cells was measured by the MTT assay. Cell cycle and mitochondrial membrane potential were measured by flow cytometry, and the expressions of procaspase-9, procaspase-3, Cyto.c, Apaf-1, Bcl-2, Bcl-xL, Bad, p53, and IGF-1R/Raf/MEK/ERK were tested by Western blotting. Xanthoceraside significantly inhibited the proliferation of human melanoma A375.S2 cells in a concentration- and time-dependent manner but did not impair the viability of normal cells (peripheral blood mononuclear cells). Further analysis revealed that xanthoceraside induced apoptosis by activating caspase-3 and caspase-9 in a time-dependent manner through the mitochondrial pathway but did not activate caspase-8 in the cells. In addition, xanthoceraside inhibited the expression of the insulin-like growth factor-1 receptor (IGF-1R), which is an important prosurvival, antiapoptotic signaling growth factor receptor that is frequently overexpressed in cancer cells and used as a therapeutic target for multiple cancers. Interestingly, xanthoceraside also decreased the expression of Raf, p-MEK, and p-ERK, the downstream effectors of IGF-1R. Taken together, these findings indicate that xanthoceraside induces apoptosis through a mitochondria-mediated apoptotic pathway, which is induced by the downregulation of IGF-1R/Raf/MEK/ERK cascades in A375.S2 cells.