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New Polytriazoleimides with High Thermal and Chemical Stabilities
E, Yanpeng,Wan, Liqiang,Li, Yujing,Huang, Farong,Du, Lei Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.7
A series of novel polytriazoleimides were prepared from various aromatic dianhydrides and a new kind of 1,2,3-triazole-containing aromatic diamine synthesized by the Cu (I)-catalyzed 1,3-dipolar cycloaddition reaction in DMAc, and characterized by FT-IR, $^1H$-NMR, XRD, DSC and TGA techniques. The results show the polytriazoleimides are soluble in most of strong polar solvents and have inherent viscosity values of 0.51-0.62 dL/g(DMAc). The polytriazoleimide films exhibit a tensile strength of 62.3-104.5 MPa and an elongation at breakage of 4.0-8.1%, a glass transition temperature ($T_g$) of $257-275^{\circ}C$, a decomposition temperature (at 5% weight loss) of $350-401^{\circ}C$ in $N_2$ atmosphere, and a dielectric constant of 2.47-3.01 at 10 MHz, which depend on the structure of the polymers. The polytriazoleimides perform good resistance to acid and alkali solution.
New Polytriazoleimides with High Thermal and Chemical Stabilities
Yanpeng E,Liqiang Wan,Yujing Li,Farong Huang,Lei Du 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.7
A series of novel polytriazoleimides were prepared from various aromatic dianhydrides and a new kind of 1,2,3-triazole-containing aromatic diamine synthesized by the Cu (I)-catalyzed 1,3-dipolar cycloaddition reaction in DMAc, and characterized by FT-IR, 1H-NMR, XRD, DSC and TGA techniques. The results show the polytriazoleimides are soluble in most of strong polar solvents and have inherent viscosity values of 0.51-0.62 dL/g(DMAc). The polytriazoleimide films exhibit a tensile strength of 62.3-104.5 MPa and an elongation at breakage of 4.0-8.1%, a glass transition temperature (Tg) of 257-275 oC, a decomposition temperature (at 5% weight loss) of 350-401 oC in N2 atmosphere, and a dielectric constant of 2.47-3.01 at 10 MHz, which depend on the structure of the polymers. The polytriazoleimides perform good resistance to acid and alkali solution.
Hongwen He,Liqiang Cao,Lixi Wan,Haiyan Zhao,Guangchen Xu,Fu Guo 대한금속·재료학회 2012 ELECTRONIC MATERIALS LETTERS Vol.8 No.4
The electromigration test was conducted in Cu/Sn-58Bi/Cu solder joint with high current density of 104 A/cm2. Results showed that a large number of whiskers with natural weed appearance were observed at the cathode side in such a short current stressing time. Furthermore, some secondary whiskers were attached to the primary whiskers, which has never been reported before. We presumed the vapor-solid (VS) mechanism to explain the oxide whiskers growth, which was quite different from the traditional theory that the compressive stress took on the driving force. In conclusion, due to the over-Joule heating effect, the metal oxide whiskers were synthesized in bulk quantities by thermal evaporation of Sn oxide and Bi oxide.
Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene
Xiao’an Zhou,Lei Du,Liqiang Wan,Xiaofei Wang,Yanpeng E,Farong Huang 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.9
Novel soluble triazoleimide oligomers terminated with arylacetylene terminated were synthesized by the Cu(I)-catalysed 1,3-dipolar cycloaddition polymerization of diazides and imide-containing dialkyne. Several molecular weight triazoleimide oligomers were prepared from diazide and dialkyne monomers with different stoichiometric combinations. The curing behaviors of the oligomers were tested by differential scanning calorimetry (DSC). The thermal properties of the cured products were evaluated by DSC and thermogravimetric analysis (TGA). These cured oligomers showed the glass transition temperature of about 225 - 235 oC and the decomposition temperature (at 5% weight loss) of about 385 - 393 oC in nitrogen.
Synthesis and Characteristic of Novel Soluble Triazoleimide Oligomers with Terminated Arylacetylene
Zhou, Xiao'an,Du, Lei,Wan, Liqiang,Wang, Xiaofei,E, Yanpeng,Huang, Farong Korean Chemical Society 2010 Bulletin of the Korean Chemical Society Vol.31 No.9
Novel soluble triazoleimide oligomers terminated with arylacetylene terminated were synthesized by the Cu(I)-catalysed 1,3-dipolar cycloaddition polymerization of diazides and imide-containing dialkyne. Several molecular weight triazoleimide oligomers were prepared from diazide and dialkyne monomers with different stoichiometric combinations. The curing behaviors of the oligomers were tested by differential scanning calorimetry (DSC). The thermal properties of the cured products were evaluated by DSC and thermogravimetric analysis (TGA). These cured oligomers showed the glass transition temperature of about $225-235^{\circ}C$ and the decomposition temperature (at 5% weight loss) of about $385-393^{\circ}C$ in nitrogen.