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Cui, Lianmeng,Zhou, Limin,Zhang, Kai,Xiong, Fangyu,Tan, Shuangshuang,Li, Maosheng,An, Qinyou,Kang, Yong-Mook,Mai, Liqiang Elsevier 2019 Nano energy Vol.65 No.-
<P><B>Abstract</B></P> <P>Benefiting from high volumetric energy density and generally dendrite-free growth of Mg metal, rechargeable magnesium batteries (MBs) become a promising next-generation energy storage system. Organic electrode materials, with characteristic of sustainable resource and flexible structure, have been widely studied in alkali metal ion batteries, but are rarely reported in MBs. Herein, we demonstrate that 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) serves as a cathode material for MBs in non-aqueous system, which realizes a fast diffusion kinetics and remarkable Mg-storage performance through a salt-dissolution inhibition approach for the electrolyte. The PTCDA exhibits a reversible capacity of 126 mAh g<SUP>−1</SUP> (at 200 mA g<SUP>−1</SUP>), excellent rate performance, and good cycling stability (100 mAh g<SUP>−1</SUP> even after 150 cycles). Furthermore, the evolution mechanism of the PTCDA electrode based on the transformation between carbonyl groups (CO) and enolate groups (C–O) is revealed by <I>ex-situ</I> phase characterization and functional group analysis. Besides, the dissolution inhibition of the PTCDA could also be realized through the incorporation of other soluble salt (KCl or NaCl) into all phenyl complex (APC) electrolyte, resulting in an enhanced cycling capacity. Considering the designable configuration of the organic materials, this work would pave way for their utilization on multi-valent ion batteries and provide efficient strategy to realize high voltage and satisfied cycle life.</P> <P><B>Highlights</B></P> <P> <UL> <LI> The magnesium anode in organic system was realized combined with the solubility inhibition of the host materials. </LI> <LI> Compared with other inorganic cathode materials, the PTCDA is eligible to offset the defect of Mg<SUP>2+</SUP> transport dynamics. </LI> <LI> Compared with other Mg-storage materials reported, the PTCDA demonstrates a high working voltage plateau and a small polarization. </LI> <LI> The electrochemical mechanism of the PTCDA is proved to be the transformation between carbonyl groups and enolate groups. </LI> <LI> The incorporation of dissolvable salts inhibited the dissolution of the PTCDA. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Cho, Hyun Yong,Tarte, Naresh Hiraral,Cui, Liqiang,Hong, Dae Sik,Woo, Seong Ihl,Gong, Young-Dae WILEY-VCH Verlag 2006 Macromolecular chemistry and physics Vol.207 No.21
<P>Summary: A novel non-metallocene Zr(IV) complex bearing a bianionic form of the ligand 2,6-bis(2-benzimidazolyl)pyridine is synthesized. This Zr complex is an active catalyst for the polymerization of MA via coordination polymerization in the presence of methylaluminoxane MAO. The activity and MWD are increased as the polymerization temperature increases. The maximum activity is observed at Al/Zr molar ratio of 100 and the deactivation is shown above 100, resulting from an inactive bimetallic complex between catalyst and free TMA presented in MAO. Decrease in MWD is observed with higher MAO concentration due to its role in chain transfer during the chain propagation.</P><P> <img src='wiley_img/10221352-2006-207-21-MACP200600395-gra001.gif' alt='wiley_img/10221352-2006-207-21-MACP200600395-gra001'> Graphic The reaction of the ligand and catalyst synthesis. </P>