Electronic structure, magnetic and structural properties of Ni doped ZnO nanoparticles

Kumar, S.,Vats, P.,Gautam, S.,Gupta, V.P.,Verma, K.D.,Chae, K.H.,Hashim, Mohd.,Choi, H.K. Pergamon Press 2014 Materials research bulletin Vol.59 No.-

We report structural, magnetic and electronic structural properties of Ni doped ZnO nanoparticles prepared by auto-combustion method. The prepared nanoparticles were characterized by using X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), near edge X-ray absorption fine structure (NEXAFS) spectroscopy, and dc magnetization measurements. The XRD and HR-TEM results indicate that Ni doped ZnO nanoparticles have single phase nature with wurtzite lattice and exclude the presence of secondary phase. NEXAFS measurements performed at Ni L<SUB>3,2</SUB>-edges indicates that Ni ions are in +2 valence state and exclude the presence of Ni metal clusters. O K-edge NEXAFS spectra indicate an increase in oxygen vacancies with Ni-doping, while Zn L<SUB>3,2</SUB>-edge show the absence of Zn-vacancies. The magnetization measurements performed at room temperature shows that pure and Ni doped ZnO exhibits ferromagnetic behavior.

Reduction of noxious Cr(VI) ion to Cr(III) ion in aqueous solutions using H2O2 and UV/H2O2 systems

M.H. Dehghani,B. Heibati,A. Asadi,I. Tyagi,S. Agarwal,V.K. Gupta 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.33 No.-

Conversion of the toxic Cr(VI) to the less toxic Cr(III) in aqueous solutions by chemical andphotochemical reduction was carried out using H2O2 and UV radiation. The whole mechanism was wellelucidated and investigated using potassium dichromate (K2Cr2O7) as a standard model compound. Theeffects of potential factors affecting the reduction efficiency were well studied and optimized, theoptimized parameters such as concentration of H2O2 (from 0.5 to 1.5 M), pH (from 5 to 9), irradiationtime (0 to 140 min) and reaction time (0 to 120 min). Initial concentration of Cr(VI) in the solution wasvaried from 0.1 to 15 mg/L plays a significant role in the mechanism involves for the reduction of noxiousCr(VI) to less toxic Cr(III).

Rate of simultaneous approximation for Baskakov-Szasz operators

V. Gupta,T. Kim,V. K. Singh,B. Lee 장전수학회 2011 Proceedings of the Jangjeon mathematical society Vol.14 No.3

In the present paper we consider an integral modification of the Baskakov operators,which have weight functions of Sz´asz basis functions. We study the rate of convergence for absolutely continuous functions having a derivative coinciding a.e. with a function of bounded variation. We also mention some of the improvements of the paper [1].

Photoluminescence, thermoluminescence and evaluation of some parameters of Dy³⁺ activated Sr₅(PO₄)₃F phosphor synthesized by sol-gel method

Gupta, K.K.,Kadam, R.M.,Dhoble, N.S.,Lochab, S.P.,Singh, V.,Dhoble, S.J. Elsevier Sequoia 2016 JOURNAL OF ALLOYS AND COMPOUNDS Vol.688 No.2

In this study, we have synthesized Dy<SUP>3+</SUP> activated Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F (S-FAP) phosphors by sol-gel synthesis method. The synthesized phosphors were characterized by X-ray diffraction pattern (XRD), scanning electron microscopic (SEM), photoluminescence (PL) and thermoluminescence (TL) for structural, morphological and luminescent properties. Dy<SUP>3+</SUP> activated Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F phosphor shows its characteristic PL emission at 481 nm and 574 nm due to <SUP>4</SUP>F<SUB>9/2</SUB> → <SUP>6</SUP>H<SUB>15/2</SUB> and <SUP>4</SUP>F<SUB>9/2</SUB> → <SUP>6</SUP>H<SUB>13/2</SUB> transitions, respectively. TL characteristics of Dy<SUP>3+</SUP> doped Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F phosphors were taken after irradiation by <SUP>60</SUP>Co gamma exposure. Two separate TL peaks at 126 <SUP>o</SUP>C and 279 <SUP>o</SUP>C were observed in case of Dy<SUP>3+</SUP> doped phosphor. Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F:Dy<SUP>3+</SUP> phosphor was irradiated within a wide range of exposure of 50 Gy to 7 kGy doses. Linearity was found up to 2 kGy and thereafter TL response saturates. Fading study was also carried out over the duration of six weeks for Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F phosphor. Trapping parameters were calculated using Chen's peak shape method, initial rise method and various heating rate method. Glow curve is deconvoluted using computerized glow curve deconvolution program. TL sensitivity of Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F:Dy<SUP>3+</SUP> phosphor is found to be less by a factor of 2.08 than commercially used CaSO<SUB>4</SUB>:Dy phosphor. In order to identify the defect centers formed upon γ-ray irradiation in Sr<SUB>5</SUB>(PO<SUB>4</SUB>)<SUB>3</SUB>F:Dy<SUP>3+</SUP> phosphor, EPR measurements were carried out on un-irradiated and irradiated phosphors.

IMPACT BEHAVIOR MODELING OF MOTORCYCLE FRONT WHEEL-TIRE ASSEMBLY

K. S. TAN,S. V. WONG,R. S. RADIN UMAR,N. K. GUPTA,A. M. S. HAMOUDA 한국자동차공학회 2009 International journal of automotive technology Vol.10 No.3

Experiments were conducted to investigate the influence of certain parameters that affect the impact response of the motorcycle front wheel-tire assembly under various impact conditions. Impact tests were conducted according to 2V 5–1 fractional factorial design using a pendulum impact test apparatus with impact speed, impact mass, tire inflation pressure level, striker geometry, and impact location as design factors. Significant factors influencing the response of the wheel-tire assembly were identified. Coefficients for each factor were also determined, and empirical models were then developed for each response. An analysis indicates that the developed models fit well within the experimental ranges of the respective factors. However, for several interaction effects, the models become unrealistic, whereby they give certain deformation values when approaching zero impact mass and/or zero impact velocity. This is not consistent with the mechanics of the physical world, as there should not be any significant deformation when delivered impact energy is small enough. Efforts have been made in developing better models to resolve the inconsistency and to include a wider range, especially considering the case of the lower limit of experimental factors, which are an impact mass of 51.18 kg and/or an impact velocity of 3 m s−1 (10.8 km/h) down to zero. The minimum amount of impact energy required to produce the onset of observable deformation on the wheel was incorporated in the development of new models. Finally, the present models have been developed not only to cover the lower regions but also to range up to the upper limits of the factors, which are an impact mass of 101.33 kg and an impact velocity of 6 m s−1 (21.6 km/h). Experiments were conducted to investigate the influence of certain parameters that affect the impact response of the motorcycle front wheel-tire assembly under various impact conditions. Impact tests were conducted according to 2V 5–1 fractional factorial design using a pendulum impact test apparatus with impact speed, impact mass, tire inflation pressure level, striker geometry, and impact location as design factors. Significant factors influencing the response of the wheel-tire assembly were identified. Coefficients for each factor were also determined, and empirical models were then developed for each response. An analysis indicates that the developed models fit well within the experimental ranges of the respective factors. However, for several interaction effects, the models become unrealistic, whereby they give certain deformation values when approaching zero impact mass and/or zero impact velocity. This is not consistent with the mechanics of the physical world, as there should not be any significant deformation when delivered impact energy is small enough. Efforts have been made in developing better models to resolve the inconsistency and to include a wider range, especially considering the case of the lower limit of experimental factors, which are an impact mass of 51.18 kg and/or an impact velocity of 3 m s−1 (10.8 km/h) down to zero. The minimum amount of impact energy required to produce the onset of observable deformation on the wheel was incorporated in the development of new models. Finally, the present models have been developed not only to cover the lower regions but also to range up to the upper limits of the factors, which are an impact mass of 101.33 kg and an impact velocity of 6 m s−1 (21.6 km/h).

Effect of tube area on the behavior of concrete filled tubular columns

P.K. Gupta,V.K. Verma,Heaven Singh,Ziyad A. Khaudhair 사단법인 한국계산역학회 2015 Computers and Concrete, An International Journal Vol.15 No.2

In the present study, a Finite Element Model has been developed and used to study the effect of diameter to wall thickness ratio (D/t) of steel tube filled with concrete under axial loading on its behavior and load carrying capacity. The model is verified by comparing its findings with available experimental results. Influence of thickness and area of steel tube on strength, ductility, confinement and failure mode shapes has been studied. Strength enhancement factors, load factor, confinement contribution, percentage of steel and ductility index are defined and introduced for the assessment. A parametric study by varying length and thickness of tube has been carried out. Diameter of tube kept constant and equals to 140 mm while thickness has been varied between 1 mm and 6 mm. Equations were developed to find out the ultimate load and confined concrete strength of concrete. Variation of lateral confining pressure along the length of concrete cylinder was obtained and found that it varies along the length. The increase in length of tubes has a minimal effect on strength of tube but it affects the failure mode shapes. The findings indicate that optimum use of materials can be achieved by deciding the thickness of steel tube. A better ductility index can be obtained with the use of higher thickness of tube.

X-ray/gamma radiation shielding properties of Aluminium-Barium Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

Sathish K.V.,Sridhar K.N.,Seenappa L.,Manjunatha H.C.,Vidya Y.S.,Chinnappa Reddy B.,Manjunatha S.,Santhosh A.N.,Munirathnam R.,Raj Alfred Cecil,Damodara Gupta P.S.,Sankarshan B.M. 한국원자력학회 2023 Nuclear Engineering and Technology Vol.55 No.5

For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (6000 C) to study the electromagnetic (EM) (X/g) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic BaðNO3Þ2, a and g phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc’s relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/g) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/g) radiation shielding

Biochemical characterization of sericin isolated from cocoons of tropical tasar silkworm Antheraea mylitta raised on three different host plants for its prospective utilization

Jena K.,Kumari Ruchi,Pandey J.P.,Kar P.K.,Akhtar J.,Singh A.K.,Gupta V.P.,A. K. Sinha 한국응용곤충학회 2021 Journal of Asia-Pacific Entomology Vol.24 No.3

Sericin were isolated and characterized from tasar cocoons raised in three different food plants i.e. Terminalia arjuna, T. tomentosa and Shorea robusta for its applications. Their molecular composition, structure and physical nature were determined by elemental analysis, amino acid analysis, Fourier Transform Infrared Spectroscopy (FTIR) and Differential Scanning Calorimetry (DSC) analysis. These results show that tasar food plants influence the physical and chemical properties of sericin. Further, sericin isolated from cocoons of S. robusta food plant shows better antioxidant potential and inhibition of tyrosinase, elastase and glutathione-S-transferase activity than other food plants. This may be attributed to its amino acid variations and associated phenolic content. The present study appears to be useful in utilizing tasar sericin as a potential bio-molecule for its prospective utili zation in pharmaceuticals and its associated fields.

Study on Suitable Semen Additives Incorporation into the Extender Stored at Refrigerated Temperature

Bhakat, M.,Mohanty, T.K.,Raina, V.S.,Gupta, A.K.,Pankaj, P.K.,Mahapatra, R.K.,Sarkar, M. Asian Australasian Association of Animal Productio 2011 Animal Bioscience Vol.24 No.10

The objective of this study was to compare the effect of Butylated Hydroxy Toluene (BHT), Pentoxifylline (PTX) and ${\alpha}$-tocopherol (Vit E) on semen quality parameters of Karan Fries bulls. The fortification of extender by various semen additives improves motility as well as fertility of spermatozoa. Split samples of 24 ejaculates of four Karan Fries bulls were extended in extender with or without various additives such as BHT, PTX and Vit E, and performance was evaluated at an interval of 0, 24, 48 and 72 h at refrigerated temperature (4-$7^{\circ}C$). Results of the present study revealed that addition of BHT, PTX and Vit E in extender improved sperm cell function, such as motility, viability, HOST, and acrosome integrity, as compared to the control during liquid storage up to 48 h of preservation at refrigerated temperature. There was no significant (p<0.05) difference between any of the additives up to 48 h of preservation. Overall, the results showed a significant (p<0.05) deterioration in motility after each storage interval. The results showed a significant deterioration in the acrosome integrity and plasma membrane integrity up to 48 h; subsequently, there was not much degradation of both the semen quality parameters. There was a significant increase in spermatozoal tail and total abnormality after each storage interval at refrigerator temperature (4 to $7^{\circ}C$); however, the head and mid-piece abnormalities were almost unaffected. Tail and total abnormality were least in extender fortified with BHT, PTX and Vit E at different hours of incubation as compared to the control. The addition of 1.5 mM BHT, 3.6 mM PTX and 1 mg/ml Vit E in the semen extender has more beneficial effect in terms of semen quality and preservability of spermatozoa.

Laser wakefield acceleration of electrons from a density-modulated plasma

Gupta, D.N.,Gopal, K.,Nam, I.H.,Kulagin, V.V.,Suk, H. Cambridge University Press 2014 Laser and particle beams Vol.32 No.3

<B>Abstract</B><P>This research reports the increased electron energy gain from laser wakefield acceleration in density-modulated plasma with an external magnetic field. Periodic plasma density- modulation can excite higher harmonics of different phase velocities of fundamental wakefield that can assist in improving the self-trapping of pre-accelerated electrons to accelerate them for higher energy. Furthermore, the applied magnetic field assisted self-injection can also contribute in electron energy enhancement during the acceleration. The physical mechanism is described with a theoretical formulation for this scheme. Results of two-dimensional particle-in-cell simulations are reported to understand the proposed idea.</P>