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      • Highly Ordered Mesoporous Crystalline MoSe<sub>2</sub> Material with Efficient Visible‐Light‐Driven Photocatalytic Activity and Enhanced Lithium Storage Performance

        Shi, Yifeng,Hua, Chunxiu,Li, Bin,Fang, Xiangpeng,Yao, Chaohua,Zhang, Yichi,Hu, Yong‐,Sheng,Wang, Zhaoxiang,Chen, Liquan,Zhao, Dongyuan,Stucky, Galen D. WILEY‐VCH Verlag 2013 Advanced functional materials Vol.23 No.14

        <P><B>Abstract</B></P><P>Highly ordered mesoporous crystalline MoSe<SUB>2</SUB> is synthesized using mesoporous silica SBA‐15 as a hard template via a nanocasting strategy. Selenium powder and phosphomolybdic acid (H<SUB>3</SUB>PMo<SUB>12</SUB>O<SUB>40</SUB>) are used as Se and Mo sources, respectively. The obtained products have a highly ordered hexagonal mesostructure and a rod‐like particle morphology, analogous to the mother template SBA‐15. The UV‐vis‐NIR spectrum of the material shows a strong light absorption throughout the entire visible wavelength region. The direct bandgap is estimated to be 1.37 eV. The high surface area MoSe<SUB>2</SUB> mesostructure shows remarkable photocatalytic activity for the degradation of rhodamine B, a model organic dye, in aqueous solution under visible light irradiation. In addition, the synthesized mesoporous MoSe<SUB>2</SUB> possess a reversible lithium storage capacity of 630 mAh g<SUP>−1</SUP> for at least 35 cycles without any notable decrease. The rate performance of mesoporous MoSe<SUB>2</SUB> is much better than that of analogously synthesized mesoporous MoS<SUB>2</SUB>, making it a promising anode for the lithium ion battery.</P>

      • Study on load distribution ratio of composite pre-tightened tooth joint by shear nonlinearity

        Yifeng Gao,Fei Li,Qilin Zhao,Jiangang Gao,Lin Shi,Zhiqin Zhao 국제구조공학회 2021 Steel and Composite Structures, An International J Vol.40 No.5

        Load distribution has a great influence on the mechanical properties of composite pre-tightened multi-tooth connection. To obtain the load distribution mechanism of composite pre-tightened multi-tooth joints, the multi-tooth joints were studied by experimental and theoretical methods. First, an experimental study was conducted on three-tooth specimens with different tooth depths and tooth lengths, and the failure mode, bearing capacity and load distribution mechanism of the specimens were obtained. Then, based on the nonlinear constitutive of interlaminar shear, an analytical model for load distribution of composite pre-tightened multi-tooth joint was proposed to research the multi-tooth load distribution mechanism. Finally, the theoretical and experimental results were compared. The research showed: (1) The theoretical results of the multi-tooth load distribution ratio were in good agreement with that of the experimental results, the maximum error between the theoretical value and the experimental value of the three-tooth joint was 17.44%, and the minimum error was only 2.35%; (2) The load distribution ratio of composite pre-tightened multi-tooth was uneven, for three-tooth joints, the values of load distribution ratio from large to small were: the first tooth, the third tooth and the second tooth.; (3) Multi-tooth load distribution ratio changed with the change of external load. The change of load distribution ratio was obvious in the early stage of loading, and tended to be gentle in the later stage of loading.

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        Exercise-induced FNDC5/irisin protects nucleus pulposus cells against senescence and apoptosis by activating autophagy

        Zhou Wenxian,Shi Yifeng,Wang Hui,Chen Linjie,Yu Caiyu,Zhang Xufei,Yang Lei,Zhang Xiaolei,Wu Aimin 생화학분자생물학회 2022 Experimental and molecular medicine Vol.54 No.-

        Intervertebral disc degeneration (IVDD) is a major cause of low back pain (LBP), and excessive senescence and apoptosis of nucleus pulposus (NP) cells are major pathological changes in IVDD. Physical exercise could effectively delay the process of intervertebral disc degeneration; however, its mechanism is still largely unknown. Irisin is an exercise-induced myokine released upon cleavage of the membrane-bound precursor protein fibronectin type III domain-containing protein 5 (FNDC5), and its levels increase after physical exercise. Here, we show that after physical exercise, FNDC5/irisin levels increase in the circulation and NP, senescence and apoptosis are reduced, autophagy is activated in NP tissue, and the progression of IVDD is delayed. Conversely, after knocking out FNDC5, the benefits of physical exercise are compromised. Moreover, the overexpression of FNDC5 in NP tissue effectively alleviated the degeneration of the intervertebral disc (IVD) in rats. By showing that FNDC5/irisin is an important mediator of the beneficial effects of physical exercise in the IVDD model, the study proposes FNDC5/irisin as a novel agent capable of activating autophagy and protecting NP from senescence and apoptosis.

      • Enhanced Li storage performance of ordered mesoporous MoO2 via tungsten doping.

        Fang, Xiangpeng,Guo, Bingkun,Shi, Yifeng,Li, Bin,Hua, Chunxiu,Yao, Chaohua,Zhang, Yichi,Hu, Yong-Sheng,Wang, Zhaoxiang,Stucky, Galen D,Chen, Liquan RSC Pub 2012 Nanoscale Vol.4 No.5

        <P>Ordered mesoporous tungsten-doped MoO(2) was synthesized by a nanocasting method. The Li storage performance of mesoporous MoO(2) is significantly improved by tungsten doping, which exhibits a reversible capacity of 700 mA h g(-1), better cycling and rate performance. This material combines the advantages of the high theoretical capacity of MoO(2) and the better electroactivity of WO(2).</P>

      • Morphology-selective synthesis of mesoporous SBA-15 particles over micrometer, submicrometer and nanometer scales

        Lee, Hyung Ik,Kim, Jin Hoe,Stucky, Galen D.,Shi, Yifeng,Pak, Chanho,Kim, Ji Man Royal Society of Chemistry 2010 Journal of materials chemistry Vol.20 No.39

        <P>Mesoporous silica structures are of increasing importance as supports for enzymes and molecular organometallic catalysts. For high-surface-area, porous 3-d catalytic supports, the relationship between the exterior particle morphology and the 3-d mesopore structure is of particular significance. This paper describes the designed synthesis of selected morphologies of mesoporous SBA-15, which can be chosen from micrometer sized spheres to hundreds or tens of nanometers sized monodispersed particles such as platelets, hexagonal columns, rice-shapes, rods with tunable aspect ratios, and donuts. These are directly synthesized <I>via</I> control of the fundamental synthesis factors, including initial temperature, stirring rate and micelle packing parameter, rather than by the use of additives that have been generally utilized for specific morphologies in previous reports. The relationship between these basic synthesis parameters and morphologies provides insights into the formation of mesostructured materials.The SBA materials with various morphologies are expected to be useful in applications that require anisotropic or path-length-controlled diffusion.</P> <P>Graphic Abstract</P><P>Control of fundamental synthesis factors such as initial temperature, stirring rate, and micelle-packing parameter enables morphological control of mesoporous SBA-15 silica over wide size range and improves its potential applications. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c0jm00820f'> </P>

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