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Arima, N.,Kim, S.,Kojima, M. Springer Science + Business Media 2016 Journal of optimization theory and applications Vol.168 No.3
<P>We propose the moment cone relaxation for a class of polynomial optimization problems to extend the results on the completely positive cone programming relaxation for the quadratic optimization model by Arima, Kim and Kojima. The moment cone relaxation is constructed to take advantage of sparsity of the polynomial optimization problems, so that efficient numerical methods can be developed in the future. We establish the equivalence between the optimal value of the polynomial optimization problem and that of the moment cone relaxation under conditions similar to the ones assumed in the quadratic optimization model.</P>
Economic Evaluation of A CGS with Energy Storage Systems
Kojima, Yoshihide,Kato, Masakazu The Korean Institute of Electrical Engineers 2011 The Journal of International Council on Electrical Vol.1 No.1
Problems such as global warming and resource depletion are becoming more and more serious. End consumers are required to reduce CO2 emissions and to make effective use of energy. As measures, cogeneration systems (CGSs) and energy storage systems including heat storage and battery are considered. In this paper, optimum facility planning and economy evaluation has been performed by linear programming for a CGS with energy storage systems.
Kojima, Yuki,Inazu, Koji,Hisamatsu, Yoshiharu,Okochi, Hiroshi,Baba, Toshihide,Nagoya, Toshio Korean Society for Atmospheric Environment 2010 Asian Journal of Atmospheric Environment (AJAE) Vol.4 No.1
The effectiveness of the government regulation on tail-pipe emission for diesel vehicles issued in 2003 in Tokyo was evaluated in this study. Variations in annual average concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitro-PAHs associated with airborne particulate matter were investigated in connection with the variation in airborne elemental carbon (EC) concentration in downtown Tokyo, Japan in 2006-2007 and in 1997-1998. The annual average concentrations of EC, seven different PAHs, and 1-nitropyrene were found to have decreased significantly from 1997-1998 to 2006-2007. The most prominent decrease in atmospheric concentration was observed for 1-nitropyrene, which is a representative nitro-PAH originating from diesel vehicles. This indicated that the government control has worked to considerably reduce both atmospheric mutagens and airborne particulate matter. In contrast, the concentrations of two nitro-PAHs, 2-nitrofluoranthene and 2-nitropyrene, remained the same. These nitro-PAHs are known to be formed by atmospheric nitration of their parent PAHs, and this result suggested factors other than the concentration of parent PAHs and $NO_2$ affects the degree of atmospheric formation of nitro-PAHs.
Kojima Tomoki,Huang Chen-Yu,Yayou Ken-ichi 아세아·태평양축산학회 2024 Animal Bioscience Vol.37 No.5
Objective: Parturition is crucial for dams, their calves, and cow managers. The prediction of calving time, which assists cow managers to decide on the relocation of cows to maternity pens and necessity of human supervision, is a pivotal aspect of livestock farming. However, existing methods of predicting calving time in dairy cows based on hormonal changes and clinical symptoms are time-consuming and yield unreliable predictions. Accordingly, we investigated whether heart rate variability (HRV) which is a non-invasive assessment of autonomic nervous system (ANS) activity and behavior during the prepartum period would be useful for predicting calving time in dairy cows. Methods: Eight pregnant cows were surveilled under electrocardiogram and video recordings for HRV and behavioral analyses, respectively. HRV parameters in time and frequency domains were evaluated. A 24-h time budget was calculated for each of six types of behavior (standing and lying with or without rumination, sleeping, and eating). Results: Heart rate on calving day is considerably higher than those recorded on the days preceding calving. Low frequency power declined, whereas high frequency power escalated on the calving day compared to the period between 24 and 48 h before calving. The time budget for ruminating while lying decreased and that while standing increased markedly on the calving day compared to those allocated on the preceding days; nonetheless, the total time budget for ruminating did not differ during the prepartum period. Conclusion: We elucidated the ANS activity and behavioral profiles during prepartum period. Our results confirm that HRV parameters and behavior are useful for predicting calving time, and interestingly indicate that the time budget for ruminating while standing (or lying) may serve as a valuable predictor of calving. Collectively, our findings lay the foundation for future investigations to determine other potential predictors and formulate an algorithm for predicting calving time.
Kojima, Takahiko,Nakayama, Kazuya,Sakaguchi, Miyuki,Ogura, Takashi,Ohkubo, Kei,Fukuzumi, Shunichi American Chemical Society 2011 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.133 No.44
<P>Ruthenium(II)–acetonitrile complexes having η<SUP>3</SUP>-tris(2-pyridylmethyl)amine (TPA) with an uncoordinated pyridine ring and diimine such as 2,2′-bipyridine (bpy) and 2,2′-bipyrimidine (bpm), [Ru<SUP>II</SUP>(η<SUP>3</SUP>-TPA)(diimine)(CH<SUB>3</SUB>CN)]<SUP>2+</SUP>, reacted with <I>m</I>-chloroperbenzoic acid to afford corresponding Ru(II)–acetonitrile complexes having an uncoordinated pyridine-<I>N</I>-oxide arm, [Ru<SUP>II</SUP>(η<SUP>3</SUP>-TPA-O)(diimine)(CH<SUB>3</SUB>CN)]<SUP>2+</SUP>, with retention of the coordination environment. Photoirradiation of the acetonitrile complexes having diimine and the η<SUP>3</SUP>-TPA with the uncoordinated pyridine-<I>N</I>-oxide arm afforded a mixture of [Ru<SUP>II</SUP>(TPA)(diimine)]<SUP>2+</SUP>, intermediate-spin (<I>S</I> = 1) Ru(IV)–oxo complex with uncoordinated pyridine arm, and intermediate-spin Ru(IV)–oxo complex with uncoordinated pyridine-<I>N</I>-oxide arm. A Ru(II) complex bearing an oxygen-bound pyridine-<I>N</I>-oxide as a ligand and bpm as a diimine ligand was also obtained, and its crystal structure was determined by X-ray crystallography. Femtosecond laser flash photolysis of the isolated <I>O</I>-coordinated Ru(II)–pyridine-<I>N</I>-oxide complex has been investigated to reveal the photodynamics. The Ru(IV)–oxo complex with an uncoordinated pyridine moiety was alternatively prepared by reaction of the corresponding acetonitrile complex with 2,6-dichloropyridine-<I>N</I>-oxide (Cl<SUB>2</SUB>py-O) to identify the Ru(IV)–oxo species. The formation of Ru(IV)–oxo complexes was concluded to proceed via intermolecular oxygen atom transfer from the uncoordinated pyridine-<I>N</I>-oxide to a Ru(II) center on the basis of the results of the reaction with Cl<SUB>2</SUB>py-O and the concentration dependence of the consumption of the starting Ru(II) complexes having the uncoordinated pyridine-<I>N</I>-oxide moiety. Oxygenation reactions of organic substrates by [Ru<SUP>II</SUP>(η<SUP>3</SUP>-TPA-O)(diimine)(CH<SUB>3</SUB>CN)]<SUP>2+</SUP> were examined under irradiation (at 420 ± 5 nm) and showed selective allylic oxygenation of cyclohexene to give cyclohexen-1-ol and cyclohexen-1-one and cumene oxygenation to afford cumyl alcohol and acetophenone.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2011/jacsat.2011.133.issue-44/ja207572z/production/images/medium/ja-2011-07572z_0005.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja207572z'>ACS Electronic Supporting Info</A></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja207572z'>ACS Electronic Supporting Info</A></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja207572z'>ACS Electronic Supporting Info</A></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja207572z'>ACS Electronic Supporting Info</A></P>