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Daniel Kane 성균관대학교 동아시아학술원 2007 Sungkyun Journal of East Asian Studies Vol.7 No.1
Daniel Kane and Richard D. McBride II and Timothy C. Lim and Robert Bedeski and Remco E. Breuker
Photoluminescence and photo-redox reactions of poly(2-methoxyaniline-5-sulfonic acid)
L.A.P. Kane-Maguire,Kane-Maguire,J. A. Causley,G. G. Wallace 한국물리학회 2004 Current Applied Physics Vol.4 No.2-4
The water-soluble fully sulfonated polyaniline, poly(2-methoxyaniline-5-sulfonic acid) has been found to photoluminesce in itsemeraldine oxidation state, ES(PMAS). Excitation of aqueous solutions at 450530 nm, near its characteristic absorption band at473 nm, led to emission at ca. 600 nm (2.1 eV). Calculations incorporating cyclic voltammetric data for ground state PMAS suggestthat the photo-generated ES.(PMAS) excited state should be both a very powerful oxidising agent and a strong reducing agent (ca.2.7 and 1.1 V of oxidising and reducing power, respectively). This prediction has been conrmed from photolysis studies ofES(PMAS) in the presence of the potentially reducible cobalt(III) cations CoCl(NH3)2þ5 , Co(H2O)(NH3)3þ5 and Co(en)3þ3 . In water,photo-oxidation of the ES(PMAS) to its fully oxidised pernigraniline base PB(PMAS) form was conrmed by UVvisible spec-troscopy. In the case ofK-Co(en)3þ3 as the acceptor, strong support for the concomitant reduction of the Co(III) complex to thecorresponding Co(II) species was obtained from its observed racemisation. Relatively low quantum eciencies (<3%) wereestablished for these novel, photo-initiated redox reactions. These photo-redox reactions were preceded by a photo-initiated con-formational change in the ES(PMAS) polymer from an ‘‘extended coil’’ to a ‘‘compact coil’’ conformation. The presence of addedNaþ and NHþ4 ions had a marked inuence on the nature of the photo-reactions, with Naþ ions retarding the photo-assistedelectron transfer, while NHþ4 ions prevented the initial conformational change in the ES(PMAS).
War, Inhumane Acts and International Restorative Justice
Kane Timothy Michael,김보혁 인하대학교 법학연구소 2015 法學硏究 Vol.18 No.2
War often brings with it the most brutal and inhumane acts, at times on incredibly vast scales, often committed by governments of states. After the fighting stops, somehow justice must be served and scars healed. And somehow we have to find a way to reduce the likelihood of inhumane crimes from ever happening again. World War II ended in 1945 but nearly 7 decades later much is unhealed, for many justice has yet to be served and much resentment lingers. In international law there are multiple provisions for dealing with international wrongful acts committed by states and the after affects of war. UN ULC adopted "Draft Articles on the Responsibility of States for Internationally Wrongful Acts" in 2001. The article 37 states that the state responsible for an internationally wrongful act is under an obligation to give satisfaction for the injury caused by that act insofar as it cannot be made good by restitution or compensation. The satisfaction may consist in an acknowledgement of the breach, an expression of regret, a formal apology or another appropriate modality. Article 37 has its limit to heal emotive side of trust from the victim state because this process is not obligation sofaras the state wrongful act can be made by restitution or compensation. In the case of the after effects of World War II we have two almost parallel cases that had nearly opposite outcomes in regard to the process of restoration of trust, peace and healing in the international community: Germany and Japan. Germany has largely managed to restore its place in the international community while making amends with its victims. Japan has, to a considerable degree, fallen short of restoring trust with its neighbors and many victims still remained aggrieved. The question remains, is there a better way to restore international trust for countries which have committed inhumane actions by their government during a time of war and what would such a system look like? Tn the mean while, there is only one example of a large modern industrial democracy with a significantly declining domestic crime rate. That example is Japan. Japan does not achieve this through direct reliance upon its formal criminal law system. Instead Japan has achieved this through utilization of a quasi-formal system of restorative justice. In this paper, we analyze Japan’s quasi-formal system of restorative justice. What we find is that Germany followed a process that maps closely to Japan’s domestic system of restorative justice, while, ironically, Japan did not. We then take the process we extracted from analysis of Japan’s system of restorative justice and craft a proposed framework for a quasi-formal international restorative justice system. Perhaps this way we can arrive at our goals of restoration and reduction in inhumane act by state internationally.
Kane Timothy Michael,김보혁 서울시립대학교 서울시립대학교 법학연구소 2015 서울법학 Vol.23 No.2
The Supreme Court dominates America’s legal establishment. Predicting its decisions has, arguably, and for all practicality, become an industry. The traditions of the court have endowed it with a teleological approach which makes predicting the court’s decisions difficult. On important decisions, especially those with political overtones, the Justices on the court show a strong preference to vote along partisan lines, in harmony with the party that nominated them onto the court – but not always. In a review of the court’s history, in key decisions Justices have departed from their more predictable partisanship. Our analysis shows that when judges depart from their predictable partisanship, they do so for fairly consistent, if not predictable, reasons: institution building. This paper argues that the Supreme Court behaves in a manner consistent with Max Weber's social theory: that a bureaucracy will labor to perpetuate itself. The Supreme Court often makes decisions for the purpose of enhancing and perpetuating the institution of the Court itself. Because the Supreme Court is a national institution, at times “institution building”means nation building. This paper studies the tension of partisanship versus institution building in Supreme Court decisions: the dynamics of fission versus fusion, the tension that exist between these two poles and the mechanics of how this is worked out, creates arguably some of the greatest drama in the Court’s history as demonstrated in Marbury v. Madison and Bush v. Gore.
STELLAR VARIABILITY OF THE EXOPLANET HOSTING STAR HD 63454
Kane, Stephen R.,Dragomir, Diana,Ciardi, David R.,Lee, Jae-Woo,Lo Curto, Gaspare,Lovis, Christophe,Naef, Dominique,Mahadevan, Suvrath,Pilyavsky, Genady,Udry, Stephane,Wang, Xuesong,Wright, Jason IOP Publishing 2011 The Astrophysical journal Vol.737 No.2
<P>Of the hundreds of exoplanets discovered using the radial velocity ( RV) technique, many are orbiting close to their host stars with periods less than 10 days. One of these, HD 63454, is a young active K dwarf which hosts a Jovian planet in a 2.82 day period orbit. The planet has a 14% transit probability and a predicted transit depth of 1.2%. Here we provide a re-analysis of the RV data to produce an accurate transit ephemeris. We further analyze 8 nights of time series data to search for stellar activity both intrinsic to the star and induced by possible interactions of the exoplanet with the stellar magnetospheres. We establish the photometric stability of the star at the 3 mmag level despite strong Ca II emission in the spectrum. Finally, we rule out photometric signatures of both star-planet magnetosphere interactions and planetary transit signatures. From this we are able to place constraints on both the orbital and physical properties of the planet.</P>
Bipolar Orders, the Two Koreas since 1989
Kane, Daniel C. 성균관대학교 동아시아학술원 2009 Sungkyun Journal of East Asian Studies Vol.9 No.2
Bipolar Orders, the Two Koreas since 1989