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      • KCI등재

        방향족 무수물 기반의 에폭시 변성 아크릴레이트 바인더 합성 및 SiO₂ 레지스트 제조에 관한 연구

        김하림(Ha-Rim Kim),김도현(Do-Hyun Kim),김영운(Young-Woon Kim),이운영(Woon-Young Lee),배진영(Jin-Young Bae) 한국고분자학회 2018 폴리머 Vol.42 No.4

        본 연구에서는 유기 절연막에 적용 가능한 새로운 광경화 에폭시 변성 아크릴레이트의 합성 및 그 특성에 대해 살펴보았다. 우선 다양한 에폭시 변성 아크릴레이트를 합성하기 위하여 산 무수물과 하이드록시 아크릴 단량체의 조합에 의해 diesteric acid(DA) 유도체를 반응시켰다. 합성된 diesteric acid(DA)에 에폭시 화합물인 글리시딜 메타아크릴레이트(glycidyl methacrylate)를 반응시켜 광경화 타입의 에폭시 변성 아크릴레이트를 합성하였다. 그리고 실리카 분산액인 NANOBYK-3650과의 호환성을 살펴보았다. 사용한 단량체의 구조에 기인하여 실리카와 최적의 바인더를 선정하고 이를 고투과율·저유전 실리카 레지스트에 적용시키고자 배합을 하여 유기 절연막을 제조하였다. 실리카 함량에 따른 투과율, 패턴성, 열 안정성 그리고 전기적 특성(유전 상수)을 확인하였다. In this study noble UV-curable epoxy modified acrylates binder was designed and synthesized to apply an organic insulating film. Firstly, diesteric acid (DA) derivatives were prepared from anhydrides and hydroxy acrylates to synthesize epoxy modified acrylates. UV-curable epoxy modified acrylates were prepared from synthesized diesteric acid (DA) and epoxy chemicals, glycidyl methacrylate (GMA). The miscibility with silica millbase ‘NANOBYK-3650’ was investigated. Appropriate binder with silica was chosen by considering the monomer chemical structure. To obtain an organic insulating film with high transmittance and low k silica resist, optimum composition of UV-curable epoxy modified acrylates was also formulated. Transmittance, patternability, and electrical properties (dielectric constant) was measured.

      • KCI등재

        ‘통제경제(統制經濟)’와 ‘계획경제(計劃經濟)’의 교차와 길항 -1930년대 중국 통제경제론(統制經濟論)의 개념화-

        金河林 ( Kim Ha Rim ) 중국사학회 2020 中國史硏究 Vol.0 No.125

        The discourse on controlled economy in China was formulated in the 1930s when the fall of capitalism was intersected with the rise of socialism. Its formulation was closely connected with the Chinese perception on planned economy as an alternative to free economy in that its conceptualization process was largely influenced by the existing terminology of the planned economy. This study takes a multifaceted analysis on the dynamics of the conceptualization of the controlled economy. It pays attention to the fact that the theory on the controlled economy in China was developed along with a resonance of planned economy caused by a contemporary change, namely the transition of capitalism. The study first examines the political and intellectual context of the terminology “controlled economy” centering on the discourses by contemporary Chinese intellectuals. Then, it analyzes the practice of conceptualization of the theory of controlled economy in consideration with its relationships with the concept of planned economy. Finally, the study suggests the implication of the intellectual movement of conceptualizing controlled economy in grasping the contemporary practice of 1930s. In conceptualizing controlled economy, we can observe that it was often merged with the concept of planned economy. Its terminological usage, denotations and categories varied between disputants. It was basically because of the disagreements on commonness and disparities of the two theory, for instance, about the evaluation of socialistic modernization or the chances of its realization in China, etc. And yet, disputants largely consented in the conceptualization of controlled economy that they were commonly in favor of socialism; they regarded controlled economy as a harmonizing but temporarily adoptable model in minimizing the vice of capitalism and maximizing the virtue of planned economy. It requires to pay our attention as to understand the intellectual implication that the conceptualization of the theory of controlled economy was carried out as a critical reorganization of planned economy which had been suggested as an alternative to free economy, and as an independent interpretation of Chinese intellectuals which was lively attached to the semi-colonial circumstance of China.

      • KCI등재후보

        1930년대 중국 지식인들의 ‘변강(邊疆)’ 인식과 아시아주의

        김하림 ( Kim Ha Rim ) 국민대학교 중국지식네트워크 2017 중국지식네트워크 Vol.10 No.-

        1930년대 전반기 만주사변으로 가시화된 영토/주권의 분할을 마주하며 민족 생존의 위기감에 휩싸인 중국에서는 역사학, 민속학, 민족학 등 다양한 근대학문의 방법론을 동원한 ‘변강’ 연구가 봇물 터지듯 쏟아져 나오게 된다. 점차 가중되는 대내외적 위기 속에서 공통의 국민국가 의식을 창출하고 근대적 주체인 국민을 만들기 위한 일단의 노력이 이른바 내부의 ‘타자’로서의 ‘소수민족’을 국민의 영역 안으로 포섭하기 위한 민족 담론의 지속적 개발로 나타났던 것이다. 그런데 그 과정에서 재구성된 민족 담론은 단순히 일국 차원의 민족주의의 범주에서만 문제가 되었던 것은 아니었다. 근대적 주권국가로서의 국권 내지 변계(邊界)의 상실 문제는 변강 지역뿐 아니라 아시아 주변 국가들을 포함한 문제로 인식되기 일쑤였다. 요컨대, 이 시기 변강 문제는 쑨원(孫文)의 대아시아주의를 정치사상적 자원으로 삼아 전개되고 있던 아시아 담론과의 관계 속에서 민족주의의 발현 양식을 매개로 긴밀하게 연동되었다. 본 논문은 1930년대 중국 지식인들의 ‘변강’ 인식을 민족주의, 아시아주의와의 관계성 속에서 살펴보고자 한다. 1930년 같은 해에 아시아주의를 표방하면서 창간된 『신아세아(新亞細亞)』, 『신동방(新東方)』 두 월간잡지의 사례를 통해, 민족국가의 영토보존과 국민국가의 창출이라는 목표를 달성하기 위해 문명화 담론이 어떻게 전용되고 있는지를 살펴보고 그 안에 드리워진 식민주의적 시선을 지적해보고자 한다. 이 과정에서 ‘민족’의 내용성을 구성하거나 그에 영향을 미쳤던 매개적 요소들이 아시아에 대한 인식과의 길항 속에서 어떻게 재배치되는지 살펴본다. 또한 두 잡지의 정치 사상적 지향 차이에 따라 변강 인식에 어떤 편차가 나타나는지를 지적하고 이를 통해 민족주의와 초민족주의 간의 상호관계를 사고해볼 것이다. In the early 1930s’ Republic of China, studies on ‘border area’ came to burst out in various modern fields like history, folklore, and ethnology. It particularly came after by the Manchurian Incident which significantly threatened the territory and sovereignty of China. In midst of internal and external crises, Chinese scholars were required to make efforts to develop a consistent discourse on Chinese ethnicity in order to create one common perception of modern nation-state and its people, subsuming the so-called ‘minor ethnic groups’ as ‘the others’ inside. In fact, contemporary discussions on Chinese ethnicity were inherently developed beyond a matter of nationalism in one nation-state. It was because the issue of losing frontiers of the sovereign nation-state of China often comes with the question of territories and relationships between nearby Asian countries. In particular, the contemporary discourse on border area was closely catalyzed by the framework of realizing nationalism in relation to the discourse on Asia which had been developing under the political and intellectual resource of Pan-Asianism by Sun Wen. The article aims to investigate the Chinese intellectuals’ perception on ‘border area’ during 1930s in relation to contemporary Asianism, focusing on analyzing two monthly journals of New Asia and the New Eastern Journal which were commonly issued first in 1930. By analyzing discussions in the two journals, it is expected to point out how Chinese intellectuals took advantage of discussions of the theory of civilization in accomplishing the goals of perserving territories and building nation-state of China, and how their discussions in the process were overshadowed by colonialistic connotations. The article evidences the intervention of Asianism in that process, its affecting in redistributing certain components or certain catalystic elements of the contemporary Chinese nationalism. In addition, it pays attention to the differences in political and intellectual orientation between the two journals, which may allow to ponder the relationship between nationalism and transnationalism.

      • KCI등재
      • KCI등재
      • KCI등재
      • KCI등재

        Artemisia princeps Pampanini의 complete freund"s adjuvant 유발 관절염에 대한 개선 효과

        김하림(Ha-Rim Kim),김솔(Sol Kim),김선영(Seon-Young Kim) 한국생명과학회 2021 생명과학회지 Vol.31 No.8

        강화사자발쑥(Artemisia princeps Pampanini)은 항산화, 항염증 및 항균제와 같은 면역 기능 관련 질병에 널리 사용되는 약초이다. 이 연구에서 우리는 RAW 264.7 세포에서 AP 추출물의 항염증 효과를 조사하고 관련 메커니즘을 평가하였다. AP 추출물의 효과는 complete Freund’s adjuvant (CFA) 유도 관절염 및 lipopolysaccharide(LPS) 유도 마우스 모델에서도 평가되었다. RAW 264.7 세포에서 AP 추출물은 LPS에 의해 유도 된 산화질소(NO) 생성과 inducible NO synthase 및 cyclooxygenase-2 단백질 발현을 현저하게 억제했다. RAW 264.7 세포에서 LPS로 유도된 mitogen-activated protein kinase 와 nuclear factor-κB의 인산화 또한 AP 추출물에 의해 유의하게 억제되었다. AP 추출물의 경구 투여는 CFA 처리 마우스 그룹에 비해 발의 부종 및 비장 지수 증가를 억제하였다. 조직학적으로 CFA 처리 마우스 군에서는 cartilage와 synovium에서 염증 세포의 침윤이 증가한 반면 AP 추출물 투여군에서는 억제되었다. 더욱이, AP 추출물은 염증성 사이토카인으로 알려진 tumor necrosis factor-α 수준을 CFA 및 LPS 처리 마우스 모델에서 현저하게 감소시켰다. 결론적으로, AP 추출물의 항염증 및 항 관절염 효과는 in vitro 및 in vivo 모델 모두에서 확인되었으며, 이는 Artemisia princeps Pampanini가 관절염 치료의 후보 물질이 될 수 있음을 시사한다. Artemisia princeps Pampanini is an herbal medicine widely used to immune function-related diseases, such as anti-oxidative, anti-inflammatory, and antibacterial agents. In this study, we investigated the anti-inflammatory effects of AP extract and underlying mechanisms were evaluated in RAW 264.7 cells. The effects of AP extract were also studied in a complete Freund’s adjuvant (CFA)-induced arthritis and lipopolysaccharide (LPS)-induced inflammation mouse model. In RAW 264.7 cells, AP extracts significantly inhibited the LPS-induced nitric oxide (NO) production and inducible NO synthase and cyclooxygenase-2 protein expression. The LPS-induced phosphorylation of mitogen-activated protein kinases and nuclear factor-κB was also significantly blocked by AP extract in RAW 264.7 cells. Oral administration of AP extract suppressed the increase in mouse paw edema and spleen index compared to CFA-treated mice group. Histologically, the infiltration of inflammatory cells was increased in cartilage and synovium in the CFA-treated mouse group, whereas it was suppressed in the AP extract-administered group. Furthermore, AP extract treatment significantly reduced the inflammatory cytokine, tumor necrosis factor-α, levels in CFA and LPS-treated mouse. In conclusion, the anti-inflammatory and anti-arthritis effect of AP extract was confirmed in both in vitro and in vivo models, suggesting that Artemisia princeps Pampanini may be a candidate material for arthritis treatment.

      • KCI등재
      • KCI우수등재

        ‘民族經濟’와 ‘割據經濟’ ― 남경국민정부 시기 省統制經濟의 문제화 ―

        金河林(Kim, Ha Rim) 동양사학회 2021 東洋史學硏究 Vol.157 No.-

        This article pays attention to the debate on the controlled economy by provincial governments, which aims to analyze the contents of the debates and to clarify their contemporary context of 1930s. Intellectuals of the time basically derived the debate from the theoretical and practical ground of the theory of controlled economy in the same period, but the aftermath of the two came to be developed in a distinctive way. The distinction lay in the difference between the geopolitical level of the nation-state and that of the provinces when discussing the obligation of the time, particularly anti-Imperialism and anti-Feudalism. Whereas general discourse of the controlled economy presupposed the central government of the nation-state as a proper unit for administrative agency, the discourse on the controlled economy by provincial governments necessarily and significantly distant from the strong attachment to the nation-state. For provincial governments claiming the controlled economy was considered a good opportunity for possessing a leading authority to the construction of nation-state, and the pursuits also worked for the strengthening of provincial identity. Such composition of discourse brought about the trait of rivalry between centralization and decentralization. Either intended or not, it was attached in the discourse of controlled economy the context of locality versus center and that of rule-by-government versus rule-by-governments. The narrative of centralization defined the provincial governments’ claim of controlled economy as feudalistic separatist economy, in other words, disrupting the foundation of national economy and the true unification of China of overcoming semi-colonial condition and integrating the nation. However, the province-centered narrative claimed that the realization of controlled economy by provincial government would complement the central government, expand the authority and autonomy of provinces, and eventually contribute to the national economy. The trait or limitation of the debates on the controlled economy by provincial government lay in the fact that the issue of provincial autonomy was barely treated to the extent of reformation of political system or expansion of democracy and autonomy from the bottom. Intellectuals mostly did not took advantage of the legacy despite the recognition of the history in 1920s when the movements for inter-provincial autonomy stimulated the pursuit of decentralization. It primarily reveals the still-powerful entity of warlords, but it also tells the predominant narrative of nation-building in the 1930s so much so to dwarf the significance of the slogan, anti-Imperialism and anti-Feudalism. However, as seen in the lively construction of economy in Shanxi and Guangdong provinces in 1930s there existed some space for the provincial government more proper as the agency of the controlled economy, and there also existed some practical results that could be assessed for the realization of the anti-Imperialism and anti-Feudalism. It is likely to be the significant case of showing the aporia of the task of nation-building in the 1930s, the crossing and rivalry between centralization and decentralization of authority circumscribing the discourse of controlled economy by provincial government. Nevertheless of the overwhelming narrative of centralization, it is still worthwhile to rethink the meaning of the controlled economy of provincial government. We need to shed enough lights on the current of pursuing decentralization that had competed against it.

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