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Shahzad, Asif,Rasool, Kashif,Nawaz, Mohsin,Miran, Waheed,Jang, Jiseon,Moztahida, Mokrema,Mahmoud, Khaled A.,Lee, Dae Sung Elsevier 2018 CHEMICAL ENGINEERING JOURNAL -LAUSANNE- Vol.349 No.-
<P><B>Abstract</B></P> <P>A simple hydrothermal treatment process was used for the fabrication of a Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> (MXene) nanosheet-based hybrid photocatalyst. The chemical composition of the MXene and its derivatives (nanosize {0 0 1} facets of TiO<SUB>2</SUB> in Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> (001-T/MX)), as well as the structural properties and morphology of the as-prepared photocatalyst, were well characterised. The heterostructure of the as-prepared photocatalyst was obtained by controlled oxidation action via the Schottky junction formed between TiO<SUB>2</SUB>-MXene interfaces. The adsorption/photocatalytic degradation abilities of the pristine MXene and the as-synthesised 001-T/MX nanocomposite for carbamazepine (CBZ) were investigated. The determined <I>K<SUB>app</SUB> </I> value of CBZ under ultraviolet light was 0.0304 min<SUP>−1</SUP>, higher than that under natural solar light, and the degradation capacity was strongly controlled under acidic conditions (pH 3.0–5.0). During the photocatalytic degradation, <SUP> </SUP>OH and <SUP> </SUP>O<SUB>2</SUB> attacked the CBZ molecule; detailed degradation pathways were proposed accordingly. The novel heterojunction 001-T/MX exhibited excellent applicability for CBZ decomposition.</P> <P><B>Highlights</B></P> <P> <UL> <LI> A simple hydrothermal process is used for the fabrication of Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> (MXene) nanosheets. </LI> <LI> Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> MXene-based heterojunction (001-T/MX) can be used as a photocatalyst. </LI> <LI> Carbamazepine (CBZ) degradation under direct sunlight and ultraviolet light is studied. </LI> <LI> T/MX photocatalyst degrades 98.67% CBZ under UV light irradiation. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Mercuric ion capturing by recoverable titanium carbide magnetic nanocomposite
Shahzad, Asif,Rasool, Kashif,Miran, Waheed,Nawaz, Mohsin,Jang, Jiseon,Mahmoud, Khaled A.,Lee, Dae Sung Elsevier 2018 Journal of hazardous materials Vol.344 No.-
<P><B>Abstract</B></P> <P>Two-dimensional metal carbides and nitrides (MXenes) have attracted increasing attention for application in water/wastewater treatment. The functionalization of MXenes to increase their stability while demonstrating high pollutant removal can facilitate sustainable water/wastewater treatment processes. In this study, the highly stable magnetic titanium carbide (<I>Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB>)</I> MXene nanocomposite (<I>MGMX</I> nanocomposite) was successfully synthesized through a facile hydrothermal approach and was tested for aqueous-phase adsorptive removal of mercuric ions. The synthesized <I>MGMX</I> nanocomposite was studied using characteristic analyses, showing high stability as revealed by zeta-potential analysis and dynamic light-scattering technique. The <I>MGMX</I> nanocomposite presented excellent Hg(II) removal in a wide range of pH conditions, and an exceptional maximum experimental Hg(II) uptake capacity of 1128.41mgg<SUP>−1</SUP> was observed. The adsorption behavior was investigated using the Redlich-Peterson adsorption isotherm, pseudo second-order kinetics, and thermodynamics models. In the adsorption/desorption investigation, the <I>MGMX</I> nanocomposite was reusable for up to five cycles of adsorption/desorption. The stability, hydrophilic nature, available adsorptive surfaces, and easy separation after reaction make the <I>MGMX</I> nanocomposite an efficient sorbent for the removal of toxic Hg(II) for water purification.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Hybrid nanocomposites were synthesized using <I>Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> </I> MXene and Fe<SUB>2</SUB>O<SUB>3</SUB> nanoparticles. </LI> <LI> <I>MGMX</I> presented the highest removal capacity for Hg(II) among other 2D materials. </LI> <LI> <I>MGMX</I> adsorbed ∼99.9% Hg(II) in the existence of background metal ions. </LI> <LI> Fe<SUB>2</SUB>O<SUB>3</SUB> nanoparticles in <I>MGMX</I> played a significant role in Hg(II) adsorption. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Shahzad, Asif,Nawaz, Mohsin,Moztahida, Mokrema,Jang, Jiseon,Tahir, Khurram,Kim, Jiho,Lim, Youngsu,Vassiliadis, Vassilios S.,Woo, Seung Han,Lee, Dae Sung Elsevier 2019 CHEMICAL ENGINEERING JOURNAL -LAUSANNE- Vol.368 No.-
<P><B>Abstract</B></P> <P>Two-dimensional (2-D) titanium carbide MXene core (Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB>) shell aerogel spheres (MX-SA) for mercuric ion removal were designed and fabricated with varying concentrations of Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> MXene and sodium alginate (SA) using a facile method. Owing to their unique inside structures, high porosities, large specific surface areas, oxygenated functional groups of MXene nanosheets, and available active binding sites, the synthesized microspheres constitute a unique adsorbent for heavy metals removal in water. The MX-SA<SUB>4:20</SUB> spheres exhibit an exceptional adsorption capacity of 932.84 mg/g for Hg<SUP>2+</SUP>, which is among the highest value reported for adsorbents. The adsorbent exhibits high single- and multi-component removal efficiencies, with 100% efficiency for Hg<SUP>2+</SUP> and >90% efficiency for five heavy metal ions. The synthesized materials are highly efficient for Hg<SUP>2+</SUP> removal under extreme pH conditions (0.5–1.0 M HNO<SUB>3</SUB>) and have additional excellent reproducible properties. The micro-size and spherical shape of MX-SA<SUB>4:20</SUB> also allow it to be used in column-packed devices.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Ti<SUB>3</SUB>C<SUB>2</SUB>T<SUB>x</SUB> nanosheets were synthesized using a low-toxicity etching agent (NH<SUB>4</SUB>F). </LI> <LI> Core-shell of MX-SA<SUB>4:20</SUB> spheres was capable of very effectively removing heavy metals. </LI> <LI> MX-SA<SUB>4:20</SUB> spheres exhibited exceptional Hg<SUP>2+</SUP> adsorption capacity of 932.84 mg g<SUP>−1</SUP>. </LI> <LI> MX-SA<SUB>4:20</SUB> performed excellently in extreme acidic conditions. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>Fabrication of MX-SA<SUB>4:20</SUB> spheres through MXene-Alginate networking and their application in Hg<SUP>2+</SUP> uptake.</P> <P>[DISPLAY OMISSION]</P>
Parametric Investigation of Metals (Au, Ag, Pt and Cu) Using Analytical Hierarchy Process
Muhammad Asif,Faiz Rasool,Zubair Butt,Muhammad Shahzad,Nouman Ahmad,Abdul Rehman Chishti 한국전기전자재료학회 2019 Transactions on Electrical and Electronic Material Vol.20 No.2
Metals especially gold, silver, platinum and copper are getting more attention for application in electronics fi eld due to their versatile properties. In this paper, we selected the materials after comparison on the basis of their signifi cant properties. Those properties are conductivity, physical properties, reactivity, cost and demand and supply. We investigate the conductivity of metals at various temperature values, their historically monthly prices along with their worldwide demand and supply. First, we compare their conductivity and resistivity for various values of temperature as well as by adding impurity into them. Secondly, we examined their responses when they are in contact with the atmosphere, their historically monthly prices, availability in the earth crust, and a brief discussion on the structure of these metals. These metals are widely used in electronics and jewelry because of their good conductivity, chemical stability and long lasting. We implemented the analytical hierarchy process for the parametric investigation of these metals which is a general theory of measurement. It has been used to derive ratio scales from both continuous and discrete paired comparison. This comparison is taken from actual measurement which refl ects the relative strength of preferences. The metals are also useful to design electrical stimulator with low-frequency current to regulate the blood of the human body. By using the stimulator at acupuncture points to pass through small electrical signal is useful to control blood fl ow in the human body as well as provides relief in pain.
Naveed Shahzad Ali,Abdul Ghaffar,Asif Ali Qaiser,Muhammad Ahmad,Khurram 한국고분자학회 2021 폴리머 Vol.45 No.1
The recovery of solvents from the extracted oils using conventional thermal separation processes i.e. distillation or evaporation is often an energy-intensive process. To provide an energy-efficient alternative, an organic solvent nanofiltration thin-film composite membrane was prepared by depositing a thin layer of polyaniline (PANI), a selective layer, via interfacial polymerization on a crosslinked polyimide (XPI), a base ultrafiltration support membrane, to provide selective transport of constituents of a miscella. The membrane was characterized by microscopic, spectroscopic, and thermal analysis. The evaluation of the separation performance was carried out by a dead-end stirred cell using three vegetable oils. For sunflower, corn, and castor oil/n-hexane mixtures, the membrane resulted in a % rejection of 50, 56, and -44, respectively. A comparison of mass flux and rejection of corn and castor oils suggests that the PANI/XPI membranes showed a strong ion-exchange behavior significantly recognizing charge macromolecules due to the presence of charged emeraldine PANI.
Probabilistic Analysis To Analyze Uncertainty Incorporating Copula Theory
Li Bin,Shahzad Muhammad,Munir Hafiz Mudassir,Nawaz Asif,Fahal Nabeel Abdelhadi Mohamed,Khan Muhammad Yousaf Ali,Ahmed Sheeraz 대한전기학회 2022 Journal of Electrical Engineering & Technology Vol.17 No.1
The emerging trend of distribution generation with existing power system network leads uncertainty factor. To handle this uncertainty, it is a provocation for the power system control, planning, and operation engineers. Although there are numerous techniques to model and evaluate these uncertainties, but in this paper the integration of Copula theory with Improved Latin-hypercube Sampling (ILHS) are incorporated for Probabilistic load Flow (PLF) evaluation. In probabilistic research approaches, the dominant interest is to achieve appropriate modelling of input random variables and reduce the computational burden. To address the said problem, Copula theory is applied to execute the modelling and interaction among input random variables of the active power system network. Considering the real discrete data, the ILHS is adopted. The load fl ow accessibility of the power system is carefully modeled by considering the dependence and uncertainty factors. Modifi ed IEEE 14-bus system is employed to analyze the effi ciency and performance of the proposed model using active power system network. Output power of two wind energy farms situated in New Jersey are obtained for accuracy comparison. The proposed technique shows the superiority in PLF evaluation.
Partial fetotomy: technique to resolve wry neck dystocia in mare
Hassan, Mubbashar,Shahid, Sana,Asif, Akhtar Rasool,Naveed, Muhammad Ilyas,Shahzad, Abid Hussain,Khan, Mumtaz Ali The Korean Society of Animal Reproduction and Biot 2020 한국동물생명공학회지 Vol.35 No.4
Foaling is a process of giving birth to foal which is prompt and forceful event in equine breeding. Dystocia is declared when 2nd stage of parturition exceeds from 20 min without fetal movements in mare. Dystocia is very challenging situation for both mare and veterinarian. Survivability of mare and foal, and subsequent fertility of mare depends on efficient management. Therefore, the current report described a rare case of wry neck (torticollis or unilateral bent neck) resulted in dystocia, that was efficiently resolved by partial fetotomy and repulsion technique in mare under field conditions. Intensive post operative care was performed to avoid infection and to achieve fertility subsequently.