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박성빈,서중석,강대승,권선길,박성원,Park Sung-Bin,Seo Chung-seok,Kang Dae-Seung,Kwon Seon-Gil,Park Seong-Won Korean Radioactive Waste Society 2005 방사성폐기물학회지 Vol.3 No.2
The electrolytic reduction of uranium oxide in a LiCl-Li$_{2}$O molten salt system has been studied in a 10 g U$_{3}$O$_{8}$ /batch-scale experimental apparatus with an integrated cathode assembly at 650$^{\circ}C$. The integrated cathode assembly consists of an electric conductor, the uranium oxide to be reduced and the membrane for loading the uranium oxide. From the cyclic voltammograms for the LiCl-3 wt$\%$ Li$_{2}$O system and the U$_{3}$O$_{8}$-LiCl-3 wt$\%$ Li$_{2}$O system according to the materials of the membrane in the cathode assembly, the mechanisms of the predominant reduction reactions in the electrolytic reactor cell were to be understood; direct and indirect electrolytic reduction of uranium oxide. Direct and indirect electrolytic reductions have been performed with the integrated cathode assembly. Using the 325-mesh stainless steel screen the uranium oxide failed to be reduced to uranium metal by a direct and indirect electrolytic reduction because of a low current efficiency and with the porous magnesia membrane the uranium oxide was reduced successfully to uranium metal by an indirect electrolytic reduction because of a high current efficiency.
제올라이트 ( A , 13X , Y , Mordenite , Chabazite ) 의 이온교환특성 연구
안진수,서중석,이용래,전관식,박현수 ( Jin Soo An,Chung Seok Seo,Yong Rae Lee,Kwan Sik Chun,Hyun Soo Park ) 한국공업화학회 1994 공업화학 Vol.5 No.6
본 연구에서는 Cs, Sr, Co이온과 5가지 유형의 제올라이트(A, 13X, Y, Mordenite, Chabazite)를 대상으로 낮은 이온농도(0.01N과 0.005N)의 수용액 중에서 이온평형 isotherm과 총 이온교환용량을 측정하고, 그 결과를 이용하여 이온교환반응에 따르는 자유에너지변화(△G°)와 엔탈피변화(△H°)를 계산하였다. 또 이들 5종의 제올라이트 중 이온교환특성이 뛰어난 3종을 대상으로 3종의 이온이 공존할 경우의 이온교환평형을 측정하여 그 결과를 삼성분계 도표에 나타내었다. 실험결과, 이온선택도와 이온교환반응에 따르는 자유에너지변화(△G°)의 크기 순서가 일치하며, △G°크기의 차이가 선택도 크기의 차이와도 상관관계가 있다는 사실을 확인하였다. 그리고 Cs이온의 흡착에는 Chabazite가 적합하고, Sr과 Co이온의 흡착에는 제올라이트-A와 13X가 효과적인 것으로 나타났다. The objective of this study is to experimentally investigate the ion exchange characteristics of five types of Zeolite(Zeolite-A, 13X, Y, Mordenite, Chabazite)for effective removal of Cs, Sr and Co ions in water solution at low concentration(0.01 N and 0.005 N). Total ion exchange capacity and equilibrium isotherm are measured, and free-energy change(△G°) and enthalpy change(△H°) in ion exchange reaction are calculated from experimental results. In addition the ion exchange equilibrium in the three-component system for three types of zeolite showing better efficiency is measured and plotted in triangle coordinates. It is shown from experimental results that the magnitude of free-energy change increases with the increasing ion selectivity, and the difference of free energy change between ions correlates closely with that of ion selectivity. The results also shows that Chabazite is effective for the adsorption of Cs ion, and Zeolite-A and Zeolite-13X for that of Sr and Co ions.
고온 리튬용융염계 산화분위기에서 Inconel 합금의 부식거동
조수행,서중석,윤지섭,박성원,Cho, Soo-Hang,Seo, Chung-Seok,Yoon, Ji-Sup,Park, Seoung-Won 한국재료학회 2006 한국재료학회지 Vol.16 No.9
The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is too corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Inconel 713LC, MA 754, X-750 and 718 in the molten salt $LiCl-Li_2O$ under an oxidizing atmosphere was investigated at $650^{\circ}C$ for $72{\sim}216$ hours. Inconel 713LC alloy showed the highest corrosion resistance among the examined alloys. Corrosion products of Inconel 713LC were $Cr_2O_3,\;NiCr_2O_4$ and NiO, and those of Inconel MA 754 were $Cr_2O_3\;and\;Li_2Ni_8O_{10}$ while $Cr_2O_3,\;NiFe_2O_4\;and\;CrNbO_4$ were produced from Inconel 718. Also, corrosion products of Inconel X-750 were found to be $Cr_2O_3,\;NiFe_2O_4\;and\;(Cr,Nb,Ti)O_2$. Inconel 713LC showed local corrosion behavior and Inconel MA 754, 718, X-750 showed uniform corrosion behavior.
박병흥,강대승,서중석,박성원,Park ByungHeung,Kang Dae-Seung,Seo Chung-Seok,Park Seong-Won Korean Radioactive Waste Society 2005 방사성폐기물학회지 Vol.3 No.2
Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of Li$_{2}$O. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.
조수행,임종호,정준호,오승철,서중석,박성원,Cho Soo-Hang,Lim Jong-Ho,Chung Jun-Ho,Oh Seung-Chul,Seo Chung-Seok,Park Seoung-Won 한국재료학회 2004 한국재료학회지 Vol.14 No.11
The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which is a chemically aggressive environment that is very corrosive for typical structural materials. So, it is essential to choose the optimum material for the process equipment handling molten salt. In this study, corrosion behavior of Haynes 263, 75, and Inconel X-750, 718 in molten salt of $LiCl-Li_{2}O$ under oxidation atmosphere was investigated at $650^{\circ}C\;for\;72\sim360$ hours. At $3\;wt\%\;of\;Li_{2}O$, Haynes 263 alloy showed the highest corrosion resistance among the examined alloys, and up to $8\;wt\%\;of\;Li_{2}O$, Haynes 75 exhibited the highest corrosion resistance. Corrosion products were formed $Li(Ni,Co)O_2,\;LiNiO_2\;and\;LiTiO_2\;and\;Cr_{2}O_3$ on Haynes 263, $Cr_{2}O_3,\;NiFe_{2}O_4,\;LiNiO_2,\;Li_{2}NiFe_{2}O_4,\;Li_{2}Ni_{8}O_10$ and Ni on Haynes 75, $Cr_{2}O_3,\;(Al,Nb,Ti)O_2,\;NiFe_{2}O_4,\;and\;Li_{2}NiFe_{2}O_4$ on Inconel X-750 and $Cr_{2}O_3,\;NiFe_{2}O_4\;and\;CrNbO_4$ on Inconel 718, respectively. Haynes 263 showed local corrosion behavior and Haynes 75, Inconel X-750, 718 showed uniform corrosion behavior.
리튬용융염계 산화성분위기에서 Al-Y 코팅한 Haynes 263의 고온 부식거동
조수행,임종호,정준호,서중석,박성원,Cho Soo-Hang,Lim Jong-Ho,Chung Jun-Ho,Seo Chung-Seok,Park Seoung-Won 한국재료학회 2005 한국재료학회지 Vol.15 No.3
The electrolytic reduction of spent oxide fuel involves the liberation of oxygen in a molten LiCl electrolyte, which results in a chemically aggressive environment that is very corrosive fir typical structural materials. So, it is essential to choose the optimum material f3r the process equipment handling molten salt. In this study, the corrosion behavior of Al-Y coated Haynes 263 in a molten salt of $LiCl-Li_2O$ under oxidation atmosphere was investigated at $650^{\circ}C$ for $72\~168$ hours. The corrosion rate of Al-Y coated Haynes 263 was low while that of bare Haynes 263 was high in a molten salt of $LiCl-Li_2O$. Al-Y coated Haynes 263 improved the corrosion resistance better than bare Haynes 263 alloy. An Al oxide layer acts as a protective film which Prohibits Penetration of oxygen. Corrosion Products were formed $Li(Ni,Co)O_2$ and $LiTiO_2$ on bare Haynes 263, but $LiAlO_2,\;Li_5Fe_5O_8\;and\;LiTiO_2$ on Al-Y coated Haynes 263.
방경식(Bang, Kyoung-Sik),이주찬(Lee, Ju-Chan),서중석(Seo, Chung-Seok),서기석(Seo, Ki-Seog),김형진(Kim, Hyung-Jin) 한국화재소방학회 2012 한국화재소방학회 학술대회 논문집 Vol.2012 No.춘계
차량의 충돌에 따른 등유의 누출에 의한 화재와 항공기 충돌에 따른 항공유의 누출에 의한 화재 발생 시 격실의 개구부 크기에 따른 화염온도를 평가하기 위해 화원으로 등유와 Jet-A-1을 사용하고 개구부의 크기를 조절해 가며 격실화재시험을 수행하였으며, 가장 높게 측정된 시험결과의 조건으로 과도화재시험을 수행하여 금속저장용기가 화염온도에 미치는 영향을 평가하였다. 시험결과 등유보다 Jet-A-1의 열 방출속도 및 질량 연소유속이 크게 나타났으며, Jet-A-1에서의 화염온도가 높게 측정되었다. 연료 소모율은 개구부의 크기가 클 경우 작은 경우보다 크게 나타났으며, 개구부의 크기가 클 경우 화염온도가 높게 측정되었다. 격실 내에 금속저장용기가 저장되었을 때는 저장용기가 화염으로부터 받는 열량만큼 화염의 온도는 낮아지는 것으로 나타났다.