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오염물질 확산방지를 위한 운영중 군 사격장 환경관리방안에 대한 고찰
정재웅,문희선,남경필,Jung, Jae-Woong,Moon, Hee Sun,Nam, Kyoungphile 한국지하수토양환경학회 2015 지하수토양환경 Vol.20 No.6
Pollutants such as heavy metals and explosives originating from the military operational ranges can be migrated to adjacent surface water body or offsite soil, and can affect to local residents and aquatic ecosystem. Therefore, Korea Ministry of the National Defense has established various guidelines for environmental management including the installation of pollutant migration prevention facilities (PMPFs) and monitoring methodologies for heavy metals in the operational range soil and effluent and sediment of PMPFs. However, current guidelines neither address the explosive compounds such as 2, 4, 6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) nor suggest detailed environmental investigation protocol. This paper introduces the new “Environmental Management Manual for Military Firing Ranges”, which includes the environmental criteria for explosives as well as the detailed investigation protocol for the affected environmental media including soil, effluent and sediment of PMPFs.
투수성 매질 내에서의 지하수위 상승에 따른 TCE 거동특성 및 오염물 이동량 변화 연구
이동근,문희선,이강근,Lee, Dong Geun,Moon, Hee Sun,Lee, Kang-Kun 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.2
In this study, three dimensional and two dimensional laboratory experiments were conducted to investigate the effect of water table rising on DNAPL migration, contaminants mass discharge ($M_d$), and residual NAPL distribution. The accumulation of TCE in unsaturated zone was observed in both two and three dimensional experiments. This implies DNAPL sources could exist in unsaturated zone at contaminated sites. It has been investigated that the TCE concentration is proportional to the areal ratio of residual TCE. This means the residual TCE obviously could affect the TCE concentration in aquifer system. The results of the two-dimensional experiment indicated that the contaminant sources in unsaturated zone could lead the $M_d$ increasing with water table rising and the source zone heterogeneity could also highly affect the $M_d$.
비소제거효율이 향상된 식물상 정화공법의 현장적용가능성 평가
정슬기,문희선,양우진,남경필,Jeong, Seulki,Moon, Hee Sun,Yang, Woojin,Nam, Kyoungphile 한국지하수토양환경학회 2016 지하수토양환경 Vol.21 No.1
A siderophore-producing bacterium (i.e., Pseudomonas aeruginosa) capable of chelating Fe<sup>3+</sup> from its mineral form (i.e., iron oxides) was used to enhance As uptake by plants. Since As in soil is mainly associated with iron oxides, siderophore can play an important role in As mobilization through the dissolution of As-bearing iron oxides. A series of pot experiment using Pteris cretica showed that As removal by P. cretica with siderophore-producing bacteria addition increased more than three times compared to that without bacteria addition. Competition between indigenous bacteria and introduced bacteria (i.e., P. aeruginosa) was also observed, but such competition seemed not to be significant. This study suggests that enhanced-phytoremediation by siderophore-producing bacteria addition could be a visible option for longterm As removal in the forest area at the former Janghang smelter site.
사고 누출 화학물질 중 강산의 생산, 사용 현황 및 사고 사례 분석
신도연,문희선,윤윤열,윤욱,이윤호,하규철,현성필,Shin, Doyun,Moon, Hee Sun,Yoon, Yoon Yeol,Yun, Uk,Lee, Yunho,Ha, Kyoochul,Hyun, Sung Pil 한국지하수토양환경학회 2014 지하수토양환경 Vol.19 No.6
We reviewed literature focusing on the amounts of domestic production, distribution, and consumption of strong acids and their spill cases. In particular, we investigated the chemistry and toxicity of four strong acids classified as "accident preparedness substances," including hydrochloric, nitric, sulfuric, and hydrofluoric acid. We recommend sulfuric and hydrofluoric acid as the chemicals of priority control based on the amounts used and toxicity. An advanced prevention/response system needs to be established along with an improved human and social infrastructure to prevent and efficiently respond to chemical accidents. Understanding the behavior and transport of spilled strong acids in the soil and groundwater environments requires a multi-disciplinary approach since they go through a variety of chemical and biogeochemical reactions with complex geomedia. However, no such research has been done in this area in Korea to the best of our knowledge. We expect the results of this study to contribute as basic data to future research.
잔류 불산에 의한 모델 지질토양시료의 광물 용해 및 비소 용출 특성
전필용,문희선,신도연,현성필,Jeon, Pilyong,Moon, Hee Sun,Shin, Doyun,Hyun, Sung Pil 한국지하수토양환경학회 2018 지하수토양환경 Vol.23 No.2
This study explored secondary effects of the residual hydrofluoric acid (HF) after a hypothetical acid spill accident by investigating the long-term dissolution of minerals and leaching of pre-existing arsenic (As) from two soil samples (i.e., KBS and KBM) through batch and column experiments. An increase in the HF concentration in both soil samples resulted in a dramatic increase in the release of major cations, especially Si. However, the amounts of mineral dissolved were dependent on the soil type and mineral characteristics. Compared to the KBM soil, relatively more Ca, Mg and Si were dissolved from the KBS soil. The column experiment showed that the long-term dissolution rates of the minerals are closely associated with the acid buffering capacity of the two soils. The KBM soil had relatively higher effluent pH values compared to the KBS soil. Also, more As was leached from the KBM soil, with a more amorphous hydrous oxide-bound As fraction. These results suggest that the potential of heavy metal leaching by the residual acid after an acid spill will be influenced by heavy metal speciation and mineral structure in the affected soil.