Surface Tunability of Polymer Brushed Substrates

류두열 한국고분자학회 2012 한국고분자학회 학술대회 연구논문 초록집 Vol.2012 No.4

A new type of Phase behavior in Block copolymer

류두열,T. P. Russell,정운용,김진곤 한국고분자학회 2002 한국고분자학회 학술대회 연구논문 초록집 Vol.2002 No.10

Homopolymer/homopolymer blends with UCST and LCST

류두열,채승훈,박민수,김진곤 한국고분자학회 2002 한국고분자학회 학술대회 연구논문 초록집 Vol.2002 No.4

The Effect of Hydrogenated C-9 Hydrocarbon resin on the Viscoelastic behaviors and Pressure-Sensitive Adhesion in Block copolymers-based PSA

류두열,김진곤 한국고분자학회 1999 한국고분자학회 학술대회 연구논문 초록집 Vol.24 No.1

Numerical simulation on structural behavior of UHPFRC beams with steel and GFRP bars

류두열,Nemkumar Banthia 사단법인 한국계산역학회 2015 Computers and Concrete, An International Journal Vol.16 No.5

This study simulates the flexural behavior of ultra-high-performance fiber-reinforced concrete (UHPFRC) beams reinforced with steel and glass fiber-reinforced polymer (GFRP) rebars. For this, micromechanics-based modeling was first carried out on the basis of single fiber pullout models considering inclination angle. Two different tension-softening curves (TSCs) with the assumptions of 2-dimensional (2-D) and 3-dimensional (3-D) random fiber orientations were obtained from the micromechanics-based modeling, and linear elastic compressive and tensile models before the occurrence of cracks were obtained from the mechanical tests and rule of mixture. Finite element analysis incorporating smeared crack model was used due to the multiple cracking behaviors of structural UHPFRC beams, and the characteristic length of two times the element width (or two times the average crack spacing at the peak load) was suggested as a result of parametric study. Analytical results showed that the assumption of 2-D random fiber orientation is appropriate to a non-reinforced UHPFRC beam, whereas the assumption of 3-D random fiber orientation is suitable for UHPFRC beams reinforced with steel and GFRP rebars due to disorder of fiber alignment from the internal reinforcements. The micromechanics-based finite element analysis also well predicted the serviceability deflections of UHPFRC beams with GFRP rebars and hybrid reinforcements.

Transition behavior of Block Copolymer in Thin Film Geometry

류두열,신창학,안형주 한국고분자학회 2009 한국고분자학회 학술대회 연구논문 초록집 Vol.2009 No.4

초고성능 섬유보강 콘크리트(UHPFRC)의 재료 특성 및 예측모델 1 : 응결 및 수축 특성과 인장거동 평가

류두열,박정준,김성욱,윤영수 대한토목학회 2012 대한토목학회논문집 A Vol.32 No.5A

최근 국내에서도 압축강도 180 MPa, 인장강도 10 MPa 이상의 초고성능 섬유보강 콘크리트(Ultra High Performance Fiber Reinforced Concrete, UHPFRC)가 개발되었다. 그러나 UHPFRC는 물-결합재비가 낮고 다량의 고분말 혼화재료를 혼입하며, 굵은 골재를 사용하지 않기 때문에 초기 재령에서의 자기수축이 크로, 표면이 급격히 건조하는 등 기존의 일반 콘크리트(Normal Concrete, NC) 및 고성능 콘크리트(High Performance Concrete, HPC)와는 다른 재료적 특성을 보인다. 그러므로 본 연구에서는 UHPFRC에 적합한 재료 실험 방법과 규정을 제안하고 극 초기 재령에서의 강도 특성을 평가하기위하여 응결 및 수축, 인장 실험을 수행하였다. 응결 실험 결과 파라핀 오일을 UHPFRC의 모르타르 표면에 적용할 경우 표면에서의 급격한 건조현상을 효율적으로 억제할 수 있는 것으로 나타났으며, 시멘트와 배합수의 수화반응을 지연 또는 촉진시키지 않는 것으로 나타나 응결 실험 시 표면건조 방지제로 적합한 것으로 판단되었다. 또한, 링-테스트를 수행하여 내부 강재 링의 온도와 변형률의 경향이 달라지는 시점을 수축 응력 발현 시점으로 정의하였으며, 이를 응결실험과 비교하여 본 결과 응결침에 걸리는 관입 저항력이 약 1.5 MPa일 때 수축 응력이 발현되는 것으로 나타났다. 이는 초결 및 종결보다 약 0.6시간, 2.1시간 빠른 것이며, 상기 시점을 UHPFRC의 자기수축 측정 시점(time-zero)으로 규정하였다. 마지막으로, 본 연구에서는 극 초기 재령 인장강도 측정 장비를 제작하여 초결시점에서부터 UHPFRC의 인장강도와 탄서예수를 측정하였으며, 이를 고려한 UHPFRC의 인장강도 및 탄성계수 예측식을 제안하였다. Recently, ultra high performance fiber reinforced concrete (UHPFRC) having over 180 MPa compressive strength and 10MPa tensile strength has been developed in Korea. Howerver, UHPFRC represents different material properties with normal concrete (NC) and conventional high performance concrete (HPC) such as a high early autogenous shrinkage and a rapid dry on the surface, because it has a low water-binder ratio and high fineness admixtures without coarse aggregate. In this study, therefore, to propose suitable experimental methods and regulations, and to evaluate mechanical properties at a very early age for UHPFRC, setting, shrinkage and tensile tests were performed. From the setting test results, paraffin oil was an appropriate material to prevent drying effect on the surface, because if paraffin oil is applied on the surface, it can efficiently prevent the drying effect and does not disturb or catalyze the hydration of cement. From the ring-test results, it was defined that the shrinkage stress is generated at the time when the graph tendency of temperature and strain of inner steel ring is changed. By comparing with setting test result, the shrinkage stress was firstly occurred as the penetration resistance of 1.5 MPa was obtained, and it was about 0.6 and 2.1 hour faster than those of initial and final sets. So, the starting time of autogenous shrinkage measurement (time-zero) of UHPFRC was determined when the penetration resistance of 1.5 MPa was obtained. Finally, the thensile strength and elastic modulus of UHPFRC were measured from near initial setting time by using very early age tensile test apparatus, and the prediction models for tensile strength and elastic modulus were proposed.

초고성능 섬유보강 콘크리트(UHPFRC)의 재료 특성 및 예측모델 2 : 구속 수축 특성 평가 및 구속도 예측

류두열,박정준,김성욱,윤영수 대한토목학회 2012 대한토목학회논문집 A Vol.32 No.5A

본 연구에서는 초고성능 섬유보강 콘크리트(Ultra High Performance Fiber Reinforced Concrete, UHPFRC)의 구속 상태에서의 수축 거동을 평가하고자 국내·외에서 가장 보편적으로 사용되는 링-테스트(ring-test)를 이용하여 구속 수축 실험을 수행하였다. 특히, 다양한 구속도에서의 수축 거동을 평가하기 위하여 내부 강재 링의 두께와 내부 반경을 달리하여 실험을 수행하였으며, 자유 수축과 인장강도 실험을 수반하여 구속도 및 응력 이완, 수축 균열 가능성 등을 복합적으로 평가하였다. 실험 결과 내부 링의 두께가 증가할수록 내부 링의 평균 변형률과 잔류 인장응력 감소하였으며, 반면에 구속도는 증가하는 경향을 보였다. 내부 링의 반경에 따라서는 변형률 및 잔류 인장응력, 구속도의 차이가 거의 없는 것으로 나타났다. 모든 시험체에서 잔류 인장응력이 인장강도에 비해 작은 것으로 나타났으며, 수축 균열은 발생하지 않았다. 지속적으로 작용하는 계면 구속 하중에 의해 탄성 수축 응력의 약 39~65%가 이완되는 것으로 나타났으며, 최대 이완 응력은 내부 링의 두께가 두꺼울수록 증가하는 것으로 나타났다. 마지막으로 본 연구에서는 비선형 회귀분석을 수행하여 재령에 따라 변하는 구속도를 예측하였으며, 실험 결과와 잘 일치하는 것으로 나타났다. In this study, to evaluate the shrinkage behavior of ultra high performance fiber reinforced concrete UHPFRC under restrained condition, restrained shrinkage test was performed according to ring-test mostly used at home and abroad. Ring-test was performed with the various thicknesses and radii of inner steel ring to give different degree of restraint. Free shrinkage and tensile tests were carried out simultaneously to estimate the degree of restraint, stress relaxation, and shrinkage cracking potential. Test results indicated that the average steel strain and residual tensile stress were reduced as the thicker inner steel ring was used, whereas degree of restraint was increased. The steel strain, residual tensile stress and degree of restraint were hardly affected by the size of radius of inner ring. In the case of all ring specimens, shrinkage crack did not occur because the residual tensile stress was lower than the tensile strength. About 39~65% of the elastic shrinkage stress was relaxed by the sustained interface pressure, and the maximum relaxed stress was increased as the thicker inner ring was applied. Finally, the degree of restraint with age was predicted by performing non-linear regression, and it was in good agreement with the test results.

Effect of cover depth and rebar diameter on shrinkage behavior of ultra-high-performance fiber-reinforced concrete slabs

류두열,권기연,양준모,윤영수 국제구조공학회 2017 Structural Engineering and Mechanics, An Int'l Jou Vol.61 No.6

This study investigates the effects of reinforcing bar diameter and cover depth on the shrinkage behavior of restrained ultra-high-performance fiber-reinforced concrete (UHPFRC) slabs. For this, twelve large-sized UHPFRC slabs with three different rebar diameters (db=9.5, 15.9, and 22.2 mm) and four different cover depths (h=5, 10, 20, and 30 mm) were fabricated. In addition, a large-sized UHPFRC slab without steel rebar was fabricated for evaluating degree of restraint. Test results revealed that the uses of steel rebar with a large diameter, leading to a larger reinforcement ratio, and a low cover depth are unfavorable regarding the restrained shrinkage performance of UHPFRC slabs, since a larger rebar diameter and a lower cover depth result in a higher degree of restraint. The shrinkage strain near the exposed surface was high because of water evaporation. However, below a depth of 18 mm, the shrinkage strain was seldom influenced by the cover depth; this was because of the very dense microstructure of UHPFRC. Finally, owing to their superior tensile strength, all UHPFRC slabs with steel rebars tested in this study showed no shrinkage cracks until 30 days.

Directed Self-Assembly of High-Molecular-Weight Block Copolymer and Its Applicability

류두열,김영식,이우섭,조성준 한국고분자학회 2018 한국고분자학회 학술대회 연구논문 초록집 Vol.43 No.2