Effects of L-tryptophan, Fructan, and Casein on Reducing Ammonia, Hydrogen Sulfide, and Skatole in Fermented Swine Manure

Q.K. Sheng,Z.J. Yang,H.B. Zhao,X.L. Wang,J.F. Guo 아세아·태평양축산학회 2015 Animal Bioscience Vol.28 No.8

The effects of daily dietary Bacillus subtilis (Bs), and adding L-tryptophan, fructan, or casein to fecal fermentation broths were investigated as means to reduce the production of noxious gas during manure fermentation caused by ammonia, hydrogen sulfide (H2S), and 3-methylindole (skatole). Eighty swine (50.0±0.5 kg) were equally apportioned to an experimental group given Bs in daily feed, or a control group without Bs. After 6 weeks, fresh manure was collected from both groups for fermentation studies using a 3×3 orthogonal array, in which tryptophan, casein, and fructan were added at various concentrations. After fermentation, the ammonia, H2S, L-tryptophan, skatole, and microflora were measured. In both groups, L-tryptophan was the principle additive increasing skatole production, with significant correlation (r = 0.9992). L-tryptophan had no effect on the production of ammonia, H2S, or skatole in animals fed Bs. In both groups, fructan was the principle additive that reduced H2S production (r = 0.9981). Fructan and Bs significantly interacted in H2S production (p = 0.014). Casein was the principle additive affecting the concentration of ammonia, only in the control group. Casein and Bs significantly interacted in ammonia production (p = 0.039). The predominant bacteria were Bacillus spp. CWBI B1434 (26%) in the control group, and Streptococcus alactolyticus AF201899 (36%) in the experimental group. In summary, daily dietary Bs reduced ammonia production during fecal fermentation. Lessening L-tryptophan and increasing fructan in the fermentation broth reduced skatole and H2S.

Covalent attachment of chiral alkaloids onto silicon surfaces

H. Wang,H.L. Zhang,Y. Guo,F.Y. Qiao,Q.Y. Sun 한국물리학회 2007 Current Applied Physics Vol.7 No.s1

In this work, we report the covalent attachment of a chiral molecule onto a hydrogen-terminated Si(SiH) surface by using an extre-mely mild approach. Cinchonine, a chiral alkaloid was self-assembled onto a SiH surface via a photochemistry method at room tem-perature. The self-assembled monolayers (SAMs) obtained were characterized by means of ellipsometry, XPS and wettability studies.The lm formation kinetics was monitored by ellipsometry and XPS, which indicated that a full monolayer was formed within 15 h.

Boron adsorption mechanism of a hybrid gel derived from tetraethoxysilane and bis(trimethoxysilylpropyl)amine

Liu, H.,Qing, B.,Ye, X.,Guo, M.,Li, Q.,Wu, Z.,Lee, K.,Lee, D.,Lee, K. 한국물리학회 2009 Current Applied Physics Vol.9 No.4_SUP

An organic/inorganic hybrid gel was prepared with tetraethoxysilane (TEOS) and bis(trimethoxysilylpropyl)amine (TSPA) as precursors. The adsorption of boron on the hybrid gel in aqueous solutions was investigated comprehensively by varying the initial boron concentration, pH, ionic strength, and temperature. The equilibrium adsorption amount of boron increases with the increase in initial boron concentration and ionic strength, but decreases with the increase in temperature. The adsorption amount exhibits a maximum at initial pH of 4-10. Boron appears to be adsorbed in both H<SUB>3</SUB>BO<SUB>3</SUB> and B(OH)<SUB>4</SUB><SUP>-</SUP> forms through the hydrogen bonding, electrostatic and hydrophobic attractions.

Non-fragile H_~ filtering for nonlinear discrete-time delay systems with randomly occurring gain variations

Liu, Y.,Park, J.H.,Guo, B.Z. Instrument Society of America 2016 ISA transactions Vol.63 No.-

In this paper,the problem of H<SUB>~</SUB> filtering for a class of nonlinear discrete-time delay systems is investigated. The time delay is assumed to be belonging to a given interval, and the designed filter includes additive gain variations which are supposed to be random and satisfy the Bernoulli distribution. By the augmented Lyapunov functional approach, a sufficient condition is developed to ensure that the filtering error system is asymptotically mean-square stable with a prescribed H<SUB>~</SUB> performance. In addition, an improved result of H<SUB>~</SUB> filtering for linear system is also derived. The filter parameters are obtained by solving a set of linear matrix inequalities. For nonlinear systems, the applicability of the developed filtering result is confirmed by a longitudinal flight system, and an additional example for linear system is presented to demonstrate the less conservativeness of the proposed design method.

Preparation and characterization of glass-ceramics with α-cordierite as the main crystalline phase from bluestone tailings

C.H. Li,W. Zhao,J.L. Zhang,W. Lu,P. Li,B.J. Yan,H.W. Guo 한양대학교 세라믹연구소 2021 Journal of Ceramic Processing Research Vol.22 No.4

The bluestone tailings are quickly expanded in China with the continuous utilization and mining of bluestone resources. Theincremental recycling of bluestone tailings is important to solve the resources waste and environmental pollution. This studyaims to reuse the bluestone tailings as the main material to prepare α-cordierite glass-ceramics based on melting process. Theresults show that the nucleation temperature, crystallization peak temperature and the activation energy for crystallizationdecreased gradually with increasing the percentage of bluestone tailings. The complete preparation parameters of α-cordieriteglass-ceramics include a bluestone tailings percentage of 70%, a heating rate of 5 oC·min^-1, a crystallization duration of 1.5h, a crystallization temperature of 970 oC, a nucleation temperature of 830 oC, and a nucleation duration of 1.0 h. Theperformances analyses reveals that the α-cordierite glass-ceramics based on the optimized parameters exhibits high densityand Vickers hardness, low dielectric loss and water absorption, and strong chemical resistance.

Environmentally friendly and non-polluting solvent pretreatment of palm samples for polyphenol analysis using choline chloride deep eutectic solvents

Fu, N.,Lv, R.,Guo, Z.,Guo, Y.,You, X.,Tang, B.,Han, D.,Yan, H.,Row, K.H. Elsevier 2017 Journal of chromatography Vol.1492 No.-

<P>In this work, choline chloride (ChCI) deep eutectic solvents (DESs) were evaluated for the pretreatment of palm samples in the analysis of polyphenols, such as protocatechuic acid, catechins, epicatechin, and caffeic acid. During the enrichment step of the pretreatment, eight DESs comprising ChCI with ethylene glycol (EG), glycerol (Gly), xylitol (Xyl), phenol (Ph), formic acid (FA), citric acid (CiA), oxalic acid (OA), or malonic acid (MA), were prepared and applied to the reflux extraction of polyphenols from palm samples. All the DESs exhibited higher polyphenol extraction efficiency than methanol, and the highest extraction efficiency was obtained using ChCI-FA (1:1, mole ratio). For the purification step of the pretreatment, eight ChCI DES-modified adsorbents were prepared by hydrothermal polymerization and packed into solid phase extraction (SPE) cartridges, and ChCI-Urea, ChCI-Gly, ChCI-FA, and water, were used as eluents. The ChCI DES-modified adsorbents were characterized by Fourier transform infrared spectroscopy, thermal gravimetric analysis, scanning electron microscopy, and Brunauer-Emmett-Teller surface analysis, and the polyphenols were analyzed by mass spectrometry and high-performance liquid chromatographultraviolet detection. The highest purification efficiency was obtained using the ChCI-Ph DES-modified adsorbent as the SPE packing material and ChCI-Urea-H2O (1:1:5, mole ratio), ChCI-Gly (1:1, mole ratio), ChCI-FA-H2O (1:1:5, mole ratio), and H2O as the eluents. Compared to conventional purification processes that employ commercial C-18 or C-8 SPE columns with organic solvents as eluents, the ChCI DES-based SPE purification process successfully avoided the use of expensive commercial SPE columns and organic solvents. Furthermore, it isolated a larger amount of the target compounds under the same experimental conditions, and could be applied over five cycles with good reversibility. This work indicates that DESs as green solvents have great potential for the totally green pretreatment of samples during the enrichment and purification processes. (C) 2017 Elsevier B.V. All rights reserved.</P>

An ANPC based High-Power Medium-Voltage Triple Active Bridge (TAB) DC-DC Converter with Enhanced Modulations

Hui Cao,Feng Guo,Zhuxuan Ma,Liyang Du,Yue Zhao,H. Alan Mantooth 전력전자학회 2023 ICPE(ISPE)논문집 Vol.2023 No.-

A high-power medium-voltage isolated DC-DC converter is proposed aiming at onboard power distribution for the future electric aircraft. The proposed converter is designed using the triple-active-bridge architecture, which consists of an H-bridge on the low voltage side and two active neutral-point-clamped (ANPC) half-bridge in series on the high voltage side. With this configuration, a high voltage step-up ratio can be achieved while using cost-effective low voltage silicon carbide (SiC) devices. A full power prototype is developed to study the design feasibility, where the H-bridge takes an input voltage up to 1 kV and the converter output can reach up to 4 kV. An improved modulation strategy is presented to control the power flow with reduced voltage overshoot across transformer windings. Also, an algorithm is proposed to address the capacitor voltage imbalance. The feasibility of the proposed converter architecture and its modulation scheme are verified using both simulation and experimental studies.

Toward reciprocal feedback between computational design, engineering, and fabrication to co-design coreless filament-wound structures

Kannenberg Fabian,Zechmeister Christoph,Gil Pérez Marta,Guo Yanan,Yang Xiliu,Forster David,Hügle Sebastian,Mindermann Pascal,Abdelaal Moataz,Balangé Laura,Schwieger Volker,Weiskopf Daniel,Gresser Götz 한국CDE학회 2024 Journal of computational design and engineering Vol.11 No.3

Fiber-reinforced composites offer innovative solutions for architectural applications with high strength and low weight. Coreless filament winding extends industrial processes, reduces formwork, and allows for tailoring of fiber layups to specific requirements. A previously developed computational co-design framework for coreless filament winding is extended toward the integration of reciprocal design feedback to maximize design flexibility and inform design decisions throughout the process. A multi-scalar design representation is introduced, representing fiber structures at different levels of detail to generate feedback between computational design, engineering, and fabrication. Design methods for global, component, and material systems are outlined and feedback generation is explained. Structural and fabrication feedback are classified, and their integration is described in detail. This paper demonstrates how reciprocal feedback allows for co-evolution of domains of expertise and extends the existing co-design framework toward design problems. The developed methods are shown in two case studies at a global and component scale.

Data processing, analysis, and evaluation methods for co-design of coreless filament-wound building systems

Gil Pérez Marta,Mindermann Pascal,Zechmeister Christoph,Forster David,Guo Yanan,Hügle Sebastian,Kannenberg Fabian,Balangé Laura,Schwieger Volker,Middendorf Peter,Bischoff Manfred,Menges Achim,Gresser 한국CDE학회 2023 Journal of computational design and engineering Vol.10 No.4

The linear design workflow for structural systems, involving a multitude of iterative loops and specialists, obstructs disruptive innovations. During design iterations, vast amounts of data in different reference systems, origins, and significance are generated. This data is often not directly comparable or is not collected at all, which implies a great unused potential for advancements in the process. In this paper, a novel workflow to process and analyse the data sets in a unified reference frame is proposed. From this, differently sophisticated iteration loops can be derived. The developed methods are presented within a case study using coreless filament winding as an exemplary fabrication process within an architectural context. This additive manufacturing process, using fiber-reinforced plastics, exhibits great potential for efficient structures when its intrinsic parameter variations can be minimized. The presented method aims to make data sets comparable by identifying the steps each data set needs to undergo (acquisition, pre-processing, mapping, post-processing, analysis, and evaluation). These processes are imperative to provide the means to find domain interrelations, which in the future can provide quantitative results that will help to inform the design process, making it more reliable, and allowing for the reduction of safety factors. The results of the case study demonstrate the data set processes, proving the necessity of these methods for the comprehensive inter-domain data comparison.

Effects of L-tryptophan, Fructan, and Casein on Reducing Ammonia, Hydrogen Sulfide, and Skatole in Fermented Swine Manure

Sheng, Q.K.,Yang, Z.J.,Zhao, H.B.,Wang, X.L.,Guo, J.F. Asian Australasian Association of Animal Productio 2015 Animal Bioscience Vol.28 No.8

The effects of daily dietary Bacillus subtilis (Bs), and adding L-tryptophan, fructan, or casein to fecal fermentation broths were investigated as means to reduce the production of noxious gas during manure fermentation caused by ammonia, hydrogen sulfide ($H_2S$), and 3-methylindole (skatole). Eighty swine ($50.0{\pm}0.5kg$) were equally apportioned to an experimental group given Bs in daily feed, or a control group without Bs. After 6 weeks, fresh manure was collected from both groups for fermentation studies using a $3{\times}3$ orthogonal array, in which tryptophan, casein, and fructan were added at various concentrations. After fermentation, the ammonia, $H_2S$, L-tryptophan, skatole, and microflora were measured. In both groups, L-tryptophan was the principle additive increasing skatole production, with significant correlation (r = 0.9992). L-tryptophan had no effect on the production of ammonia, $H_2S$, or skatole in animals fed Bs. In both groups, fructan was the principle additive that reduced $H_2S$ production (r = 0.9981). Fructan and Bs significantly interacted in $H_2S$ production (p = 0.014). Casein was the principle additive affecting the concentration of ammonia, only in the control group. Casein and Bs significantly interacted in ammonia production (p = 0.039). The predominant bacteria were Bacillus spp. CWBI B1434 (26%) in the control group, and Streptococcus alactolyticus AF201899 (36%) in the experimental group. In summary, daily dietary Bs reduced ammonia production during fecal fermentation. Lessening L-tryptophan and increasing fructan in the fermentation broth reduced skatole and $H_2S$.