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        Polyglycerol modified polysiloxane surfactants: Their adsorption and aggregation behavior in aqueous solution

        Guoyong Wang,Yanyan Zhu,Yunhui Zhai,Wanxu Wang,Zhiping Du,Jieqiong Qin 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.47 No.-

        A simple process to synthesize polyglycerol modified polysiloxane surfactants has been carried outapplying a “grafting-to” approach. After formation of allyl polyglycerol ether (APGE) from diglycerol(DGY) and allyl glycidyl ether (AGE), polysiloxane modified by designed number of polyglycerol groups(PHMS-APGE) were obtained by connecting the APGE structure to different Si H functionalizedpolyhydromethyl siloxane (PHMS). The synthesized APGE-PHMS were characterized by IR and 1H NMR. Solubility measurements showed that the solubility of the as-prepared polymers increased in polarsolvents with the increasing of the amount of hydrophilic APGE groups. Furthermore, the surface activity,surface adsorption, aggregation and spreading behaviors of APGE-PHMS were investigated utilizingsurface tension measurements, dynamic light scattering (DLS), transmission electron microscopy (TEM)and contact angle measurements. The results showed that critical aggregation concentration (CAC) andthe time needed to reach adsorption equilibrium on water surface decrease systematically with theincrease in the number of APGE groups. These polymers in aqueous solutions could aggregate to formspherical assemblies. Moreover, the spreading behavior of these polymers on low energy surface wasfound to be influenced by the number of hydrophilic APGE groups.

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        Determination of Palladium in Water Samples Using Cloud Point Extraction Coupled with Laser Thermal Lens Spectrometry

        Han, Quan,Huo, Yanyan,Yang, Na,Yang, Xiaohui,Zhai, Yunhui,Zhang, Qianyun Korean Chemical Society 2015 대한화학회지 Vol.59 No.5

        A preconcentration procedure for determination of palladium by laser thermal lens spectrometry (TLS) is proposed. It is based on cloud point extraction of palladium(II) ions as 2-(3,5-dichloro-2-pyridylazo)-5-dimethylaminoaniline (3,5-diCl-PADMA) complexes using octylphenoxypolyethoxyethanol (Triton X-114) as surfactant. The effects of various experimental conditions such as pH, concentration of ligand and surfactant, equilibration temperature and time on cloud point extraction were studied. Under the optimized conditions, the calibration graph was linear in the range of 0.15~6 ng mL<sup>−1</sup>, and the detection limit was 0.04 ng mL<sup>−1</sup> with an enrichment factor of 22. The sensitivity was enhanced by 846 times when compared with the conventional spectrophotometric method. The recovery of palladium was in the range of 96.6%~104.0%. The proposed method was applied to the determination of palladium in water samples.

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