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Xun Gao,Qingde Li,Wanli Cheng,Guangping Han,Lihui Xuan 한국고분자학회 2017 Macromolecular Research Vol.25 No.2
Poplar fibers were pretreated under high temperature and pressurized steam at different temperatures and pressures; they were further modified using different amounts of silane coupling agent. The obtained modified fibers were used to prepare wood fiber/high-density polyethylene (HDPE) composites by an extrusion-molding process. The effects of high temperature and pressurized steaming/silane coupling co-modification on the properties of wood fiber/HDPE composites were investigated. The results show that after the high temperature and pressurized steaming treatment, the amount of hydroxyl groups on the surface of the fibers and surface polarity of the fibers decreased, whereas the crystallinity and thermal stability significantly increased. The storage modulus and mechanical properties of the composites improved as well. The addition of silane to the steam-treated fibers further enhanced the storage modulus, loss modulus, and the mechanical properties of the composites. Moreover, when the wood fibers were only modified by adding silane and the silane content was 5%, the prepared composites showed better mechanical properties than the high temperature and pressurized steaming treatment. However, the addition of a small amount of silane to the wood fibers exposed to steam at 170 °C and 0.8 MPa provided even better results; when 2% silane was added, the composites showed the best mechanical properties.
Agglomeration of particles during coal combustion in multistage spouted fluidized tower
Jia-Xun Liu,Jian-Min Gao,Xiao-Feng Wang,Shao-Hua Wu,Ji-Hui Gao 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.3
An experimental platform of spray agglomeration has been designed and built for removing small fly ash particles (PM10) from coal combustion. Systematic experiments were conducted in a multistage spouted tower using kinds of agglomerant solutions. The particle concentration increases greatly from the first stage to the second stage of the tower. With the increase of flue gas flow rate the oscillation of impulse signal response curves increases and the internal circulation of the tower intensifies. The influencing factors such as the surfactant, PH value, flow rate of the agglomerant solutions and inlet flue gas temperature were analyzed. SEM was used to analyze the microstructure of the particles. Final results indicate that the special shape of a multistage spouted fluidized tower has significant influences on the effect of agglomeration. The findings from this work will be helpful to form the basis, and provide guidance for, further studies on the control of fine particles such as PM2.5 or even smaller.
Development and characterization of a fully functional small anti-HER2 antibody
( Jie Gao ),( Bo Hua Le ),( Hui Mei Li ),( Xun Min Zhang ),( Da Peng Zhang ),( Lei Zhao ),( Chong Wang ),( Chen Fang ),( Wei Zhu Qian ),( Sheng Hou ),( Geng Kou ),( Hua Feng Wei ),( Shu Shi ),( Hao Wa 생화학분자생물학회 2009 BMB Reports Vol.42 No.10
Cui Xun,Gao Likun,Lu Cheng-Hsin,Ma Rui,Yang Yingkui,Lin Zhiqun 나노기술연구협의회 2022 Nano Convergence Vol.9 No.34
Single-metal-atom catalysts (SMACs) have garnered extensive attention for various electrocatalytic applications, owing to their maximum atom-utilization efficiency, tunable electronic structure, and remarkable catalytic performance. In particular, carbon-based SMACs exhibit optimal electrocatalytic activity for the oxygen reduction reaction (ORR) which is of paramount importance for several sustainable energy conversion and generation technologies, such as fuel cells and metal-air batteries. Despite continuous endeavors in developing various advanced carbon-based SMACs for electrocatalytic ORR, the rational regulation of coordination structure and thus the electronic structure of carbon-based SMACs remains challenging. In this review, we critically examine the role of coordination structure, including local coordination structure (i.e., metal atomic centers and the first coordination shell) and extended local coordination structure (i.e., the second and higher coordination shells), on the rational design of carbon-based SMACs for high-efficiency electrocatalytic ORR. Insights into the relevance between coordination structures and their intrinsic ORR activities are emphatically exemplified and discussed. Finally, we also propose the major challenges and future perspectives in the rational design of advanced carbon-based SMACs for electrocatalytic ORR. This review aims to emphasize the significance of coordination structure and deepen the insightful understanding of structure-performance relationships.
Cat fertilization by mouse sperm injection
Jin, Yong-Xun,Cui, Xiang-Shun,Yu, Xian-Feng,Lee, Sung-Hyun,Wang, Qing-Ling,Gao, Wei-Wei,Xu, Yong-Nan,Sun, Shao-Chen,Kong, IL-Keun,Kim, Nam-Hyung Cambridge University Press 2012 Zygote Vol.20 No.4
<B>Summary</B><P>Interspecies intracytoplasmic sperm injection has been carried out to understand species-specific differences in oocyte environments and sperm components during fertilization. While sperm aster organization during cat fertilization requires a paternally derived centriole, mouse and hamster fertilization occur within the maternal centrosomal components. To address the questions of where sperm aster assembly occurs and whether complete fertilization is achieved in cat oocytes by interspecies sperm, we studied the fertilization processes of cat oocytes following the injection of cat, mouse, or hamster sperm. Male and female pronuclear formations were not different in the cat oocytes at 6 h following cat, mouse or hamster sperm injection. Microtubule asters were seen in all oocytes following intracytoplasmic injection of cat, mouse or hamster sperm. Immunocytochemical staining with a histone H3-m2K9 antibody revealed that mouse sperm chromatin is incorporated normally with cat egg chromatin, and that the cat eggs fertilized with mouse sperm enter metaphase and become normal 2-cell stage embryos. These results suggest that sperm aster formation is maternally dependent, and that fertilization processes and cleavage occur in a non-species specific manner in cat oocytes.</P>
Wenjing Zhang,Li Gao,Xun Jiao,Jun Yu,Xiaosi Su,Shanghai Du 한국지질과학협의회 2014 Geosciences Journal Vol.18 No.4
Earth fissures in Su-Xi-Chang land subsidence areahave induced massive damages to the area. The non-linear characteristicassociated with the process of earth fissure formation requiresnon-linear method for evaluating the occurrence of the hazard. Based on quantification of influence factors on breeding the hazard,GA-ANN method, which integrates artificial neural networks(ANN) with genetic algorithms (GA), is developed for evaluating theoccurrence of earth fissure hazard. Six indicators, that include thedepth of bedrock burial (DBB), the degree of bedrock relief (DBR),water level (WL) (the II confined aquifer), the gradient of landsubsidence (GLS), transmissivity (T) (the II confined aquifer) andthe thickness of clay soil (TCS), are selected as the input patternsof the integrated approach, and danger index (DI) as the outputpattern. A multilayer back-propagation neural network is trainedwith 30 sets of data samples including 15 sets of earth fissure samplesand 15 sets of safety samples for defining the architecture ofANN. Subsequently, GA is employed by optimizing the initial weightsof trained ANN by minimizing the deviation of output. The efficacy ofthe integrated approach is demonstrated by comparing the deviationof output from ANN and GA-ANN for 5 testing samples andthe result shows that the GA-ANN method is more accurate thanANN in identifying the occurrence of earth fissure. The integratedmethod is applied to the assessment of earth fissure hazard in typicalregions of earth fissure. According to the classification of DI, theregions are divided into four zones ‒ danger zone, sub-danger zone,sub-safe zone and safe zone.
Zhang, Xiang-Han,Wang, Lan-Ying,Zhai, Gao-Hong,Wen, Zhen-Yi,Zhang, Zu-Xun Korean Chemical Society 2007 Bulletin of the Korean Chemical Society Vol.28 No.12
A series of dimethine cyanine dyes were synthesized in a fast, efficient and high yield by the condensation of quaternary salts with 1H-indole-3-carbaldehyde in the presence of piperidine under solvent-free microwave irradiation. The products were identified by 1H NMR, IR, UV-Vis spectra and elemental analysis. The absorption and fluorescence properties of these dyes were investigated both experimentally and theoretically. Calculations performed at a combination of time-dependent density functional theory (TD-DFT) and the polarizable continuum model (PCM) reproduced the π-π* type absorption bands of the dyes. Regression analysis was used for studying theoretical results of the absorption maxima in different solvents. Compared with experimental counterparts, estimated overall uncertainties in the absorption maxima were about ±2%.
Ruyuan Jiang,Niantao Liu,Yuhong Su,Sanshuang Gao,Xamxikamar Mamat,Thomas Wågberg,Yongtao Li,Xun Hu,Guangzhi Hu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.08
An integrative electroanalytical method was developed for detecting Cd2+ and Pb2+ ions in aqueous solutions. Polysulfide/graphene (RGO-S) nanocomposites were prepared and their performance as electrochemical sensors for Cd2+ and Pb2+ was evaluated. The RGO-S nanocomposite was carefully characterized by scanning electron microscopy with energy-dispersive X-ray spectrometry, transmission electron microscopy, and X-ray photoelectron spectroscopy. The as-prepared RGO-S was incorporated into a pyrolytic graphite electrode (RGO-S/PGE) and used for detecting trace amount of Cd2+ and Pb2+ by differential pulse anodic stripping voltammetry. Under optimal conditions, the stripping peak current of RGO-S/PGE varies linearly with heavy metal ion concentration in the ranges 2.0–300 μg L -1 for Cd2+ and 1.0–300 μg L -1 for Pb2+. The limits of detection for Cd2+ and Pb2+ were estimated to be about 0.67 μg L -1 and 0.17 μg L -1, respectively. The prepared electrochemical heavy-metal-detecting electrode provides good repeatability and reproducibility with high sensitivity, making it a suitable candidate for monitoring Cd2+ and Pb2+ concentrations in aqueous environmental samples.