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- 저자 : Xin Tang (검색결과 161 건)
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Xin Tang,Shenhua Song,Ravi Muchakayala,Zhongyi Zhang,Anji Reddy Polu 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.37 No.-
New magnesium ion conducting polymer electrolyte films are developed and their experimentalinvestigations are reported. The polymer electrolyte films are composed of various poly(vinylidenefluoride-co-hexafluoropropylene):magnesium trifluoromethanesulfonate compositions (PVdF-HFP:Mg(Tf)2 in weight ratio) with different quantities of 1-ethyl-3-methylimidazolium trifluoromethane-sulfonate ionic liquid (EMITf). X-ray diffraction reveals that the pristine PVdF-HFP polymer filmpossesses a semi-crystalline structure and its amorphicity increases with increasing Mg(Tf)2 and EMITfconcentrations. From thermal analysis, the melting temperature (Tm), relative crystallinity (xc) andthermal stability of the 90PVdF-HFP:10Mg(Tf)2 gel polymer electrolyte film doped with 40 wt.% EMITfare obtained as 112 8C, 21.8% and 355 8C, respectively. The room-temperature ionic conductivity of thegel polymer electrolyte film increases with increasing EMITf concentration and reaches a high value ofapproximately 4.63 10 3 S cm 1 at 40 wt.% EMITf due to its amorphicity increase and interconnectedpore structure. For the 40 wt.% EMITf electrolyte film, the temperature dependence of ionic conductivityfollows the Arrhenius relation with an activation energy of 0.35 eV. The electrochemical stabilitywindow of the 40 wt.% EMITf electrolyte film is determined as 4.8 V. The findings from this study arepromising and have great potential for practical ionic device applications, particularly in rechargeablemagnesium ion batteries.
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Tang, Xin,Zhan, Ruoshui,Xi, Yanhui,Xu, Xianyong The Korean Institute of Power Electronics 2019 JOURNAL OF POWER ELECTRONICS Vol.19 No.6
Grid unbalanced faults can cause core saturation of power transformer and produce lower-order harmonics. These issues increase the electrical stress of power electronic devices and can cause a tripping of an entire HVDC system. In this paper, based on the positive-sequence and negative-sequence impedance model of a VSC-HVDC system as seen from the point of common connection (PCC), the resonance problem is analyzed and the factors determining the resonant frequency are obtained. Furthermore, to suppress over-voltage and over-current during resonance, a novel method using a virtual harmonic resistor is proposed. The virtual harmonic resistor emulates the role of a resistor connected in series with the commutating inductor without influencing the active and reactive power control. Simulation results in PSCAD/EMTDC show that the proposed control strategy can suppress resonant over-voltage and over-current. In addition, it can be seen that the proposed strategy improves the safety of the VSC-HVDC system under unbalanced faults.
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Tang, Lijun,Wu, Di,Hou, Shuhua,Wen, Xin,Dai, Xin Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.8
A carbazole-based Schiff base CB2 was synthesized and applied as a highly selective and sensitive fluorescent probe for $Cu^{2+}$ in $H_2O$-DMSO (8/2, v/v, pH = 7.4) solution. CB2 exhibits an excellent selectivity to $Cu^{2+}$ over other examined metal ions with a prominent fluorescence "turn-on" at 475 nm. CB2 and $Cu^{2+}$ forms a 1:2 binding ratio complex with detection limit of $9.5{\mu}M$. In addition, the $Cu^{2+}$ recognition process is hardly interfered by other examined metal ions.
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Tang, Lijun,Wen, Xin,Dai, Xin,Wu, Di,Huang, Zhenlong Korean Chemical Society 2014 Bulletin of the Korean Chemical Society Vol.35 No.11
A quinoline-thiooxorhodamine conjugate fluorescent sensor (1) has been synthesized. Sensor 1 exhibits high selectivity and sensitivity to $Hg^{2+}$ in $H_2O$/DMSO (95/5, v/v, HEPES 20 mM, pH = 7.4) solution with fluorescence detection. Other tested metal ions do not induce any significant fluorescence intensity changes. Sensor 1 interacts with $Hg^{2+}$ through a 1:1 binding stoichiometry with a good anti-inference ability. In addition, fluorescent imaging of $Hg^{2+}$ in Hela cells is also successfully demonstrated.
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Tang, Yan-Hui,Hu, Min,He, Xiao-Peng,Fahnbulleh, Sando,Li, Cui,Gao, Li-Xin,Sheng, Li,Tang, Yun,Li, Jia,Chen, Guo-Rong Korean Chemical Society 2011 Bulletin of the Korean Chemical Society Vol.32 No.3
The discovery of carbohydrate-based bioactive compounds has recently received considerable interest in the drug development. This paper stresses on the application of 1-methoxy-O-glucoside as the central scaffold, whereas salicylic pharmacophores were introduced with diverse spatial orientations probing into the structural preference of an enzymatic target, i.e. protein tyrosine phosphatase 1B (PTP1B). By employing regioselective protection and deprotection strategy, 2,6-, 3,4-, 4,6- and 2,3-di-O-propynyl 1-methoxy-O-glucosides were previously synthesized and then coupled with azido salicylate via click chemistry in forming the desired bidentate salicylic glucosides with high yields. The inhibitory assay of the obtained triazolyl derivatives leads to the identification of the 2,3-disubstituted salicylic 1-methoxy-O-glucoside as the structurally privileged PTP1B inhibitor among this bidentate compound series with micromole-ranged $IC_{50}$ value and reasonable selectivity over other homologous PTPs tested. In addition, docking simulation was conducted to propose a plausible binding mode of this authorized inhibitor with PTP1B. This research might furnish new insight toward the construction of structurally different bioactive compounds based on the monosaccharide scaffold.
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Interface Study of the Intermediate Connectors in Tandem Organic Devices
Tang, Jian-Xin,Fung, Man-Keung,Lee, Chun-Sing,Lee, Shuit-Tong The Korean Infomation Display Society 2010 Journal of information display Vol.11 No.1
The intermediate connectors play crucial roles in the performance of tandem organic light-emitting diodes (OLEDs) because they are required to facilitate charge carrier transport and to guarantee transparency for light transmission and deposition compatibility. Understanding the physical properties of the intermediate connector is not only fundamentally important but is also crucial to developing high-efficiency organic devices with a tandem structure. In this study, several effective intermediate connectors in tandem OLEDs using a doped or non-doped organic p-n heterojunction were systematically investigated by studying their interfacial electronic structures and corresponding device characteristics. The working mechanisms of the intermediate connectors are discussed herein by referring to their relevant energy levels with respect to those of the neighboring organic layers. The factors affecting the operation of the intermediate connectors in tandem OLEDs, as demonstrated herein, provide guidance for the identification of new materials and device architectures for high-performance devices.
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Xin Tang,Zhen Li,Yang He,Liyang Wang,Yufei Yue,Wen Wang 전력전자학회 2023 JOURNAL OF POWER ELECTRONICS Vol.23 No.2
In the stability analysis of DC (direct-current) power grids, AC (alternating current)/DC converters are usually treated as linear proportional amplifiers or inertial links. However, this approximation will have a considerable effect on the DC-side impedance model of a constant active power control converter and then affect the accuracy of the stability analysis of DC grids. In this paper, in view of the DC-side of the voltage fluctuations, the DC-side admittance model is established after the nonlinear relationship between the port voltage and the modulation signal function is determined. A comparison is made between the traditional modeling method and the proposed modeling method in the analysis of the phase–frequency characteristics and amplitude–frequency characteristics of the admittance. Results show that the proposed small-signal model can better fit the measured admittance in the low-frequency bands. The proposed admittance model in this paper is further applied to assess the small-signal stability of a DC grid. Finally, PSCAD/EMTDC simulation and lab-scaled prototype experiment are used to verify the correctness and effectiveness of the established admittance model. Results show that the small-signal model deduced in this paper can better fit and measure the admittance in the low-frequency band, and can more accurately judge the stability of the DC system.
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Xin Tang,Ruoshui Zhan,Yanhui Xi,Xianyong Xu 전력전자학회 2019 JOURNAL OF POWER ELECTRONICS Vol.19 No.6
Grid unbalanced faults can cause core saturation of power transformer and produce lower-order harmonics. These issues increase the electrical stress of power electronic devices and can cause a tripping of an entire HVDC system. In this paper, based on the positive-sequence and negative-sequence impedance model of a VSC-HVDC system as seen from the point of common connection (PCC), the resonance problem is analyzed and the factors determining the resonant frequency are obtained. Furthermore, to suppress over-voltage and over-current during resonance, a novel method using a virtual harmonic resistor is proposed. The virtual harmonic resistor emulates the role of a resistor connected in series with the commutating inductor without influencing the active and reactive power control. Simulation results in PSCAD/EMTDC show that the proposed control strategy can suppress resonant over-voltage and over-current. In addition, it can be seen that the proposed strategy improves the safety of the VSC-HVDC system under unbalanced faults.
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Active Power Filter Using Nonlinear Repetitive Controller
Xin Tang,Kai Ming Tsang,Wai Lok Chan 제어·로봇·시스템학회 2011 International Journal of Control, Automation, and Vol.9 No.1
Active power filters as solutions to power quality problems have become more and more important nowadays. A nonlinear repetitive controller for current control of active power filters is proposed. The proposed method is composed of a repetitive controller and a deadband relay. Whenever the input error is above the threshold, the current control loop is driven dominantly by the deadband relay to obtain fast dynamic response. After the input error is below the threshold, the deadband relay automatically turns off and the repetitive control alone governs the current control to eliminate the steady-state error. Discussions on the design of the current and voltage control loops are also given. Simulation and experimental results verified the feasibility of the proposed method.
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Interface Study of the Intermediate Connectors in Tandem Organic Devices
Jian-Xin Tang,Man-Keung Fung,Chun-Sing Lee,Shuit-Tong Lee 한국정보디스플레이학회 2010 Journal of information display Vol.11 No.1
The intermediate connectors play crucial roles in the performance of tandem organic light-emitting diodes (OLEDs) because they are required to facilitate charge carrier transport and to guarantee transparency for light transmission and deposition compatibility. Understanding the physical properties of the intermediate connector is not only fundamentally important but is also crucial to developing high-efficiency organic devices with a tandem structure. In this study, several effective intermediate connectors in tandem OLEDs using a doped or non-doped organic p-n heterojunction were systematically investigated by studying their interfacial electronic structures and corresponding device characteristics. The working mechanisms of the intermediate connectors are discussed herein by referring to their relevant energy levels with respect to those of the neighboring organic layers. The factors affecting the operation of the intermediate connectors in tandem OLEDs, as demonstrated herein, provide guidance for the identification of new materials and device architectures for high-performance devices.
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