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        A long-term anti-corrosion and cathodic delamination resistant epoxy coating based on COF grafted GO nanofillers

        Tianxiang Sun,Kai Jin,Wei Wang,Wen Li,Tong Wang,Tengxun Yang,Jia Cheng,Zhipeng Zhao,Shougang Chen 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.128 No.-

        Here, a long-term anti-corrosive epoxy (EP) coating based on nano-hybrid filler was developed. The surfaceof graphene oxide (GO) was aminated with (3-aminopropyl) triethoxysilane (APTES), and then theporous covalent organic framework (COF) was in-situ grown on amino functionalized graphene oxide(FGO) nanosheets by Schiff-based reaction to prepare FGO-COF nanofillers. Different characterizationmethods proved the successful modification of GO nanosheets with COF particles. The excellent waterresistance of composite coatings was characterized through contact angle, adhesion, and water uptaketests. Transmission electron microscope (TEM) and molecular dynamics (MD) methods showed thatthe grafting of COF enhanced the dispersion and compatibility of GO in the coating. EIS measurements,salt spray analysis and cathodic delamination test indicated the significant improvements in the protectiveproperties of the composite coatings compared with pure EP coating. The low-frequency impedancemodulus of 1% FGO-COF composite coating reached higher than 6.8 109 Xcm2 after immersed in seawater for 60 days. In addition, the 1% FGO-COF composite coating performed only 34% delamination ratioafter 120 h cathodic delamination test.

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        Population Genetic Structure of Liza affinis (Eastern Keelback Mullet), Reveals High Gene Flow Inferred from Microsatellite Analysis

        Lu Liu,Xiumei Zhang,Dianrong Sun,Tianxiang Gao,Na Song 한국해양과학기술원 2019 Ocean science journal Vol.54 No.2

        The population genetic studies of marine fishes usually show complex patterns of genetic differentiation which were influenced by both historical process and contemporary gene flow. Genetic structure of eight different populations for eastern keelback mullet, Liza affinis, collected from the coast along eastern and southern China, was examined using six microsatellite loci. We found strong genetic similarities among most of the samples except the Dongguan population and most microsatellite variation was found within populations. All loci were characterized by high genetic variability with expected heterozygosities ranging from 0.871 to 0.928. The Bayesian cluster analysis of the microsatellite data detected four genetic groups with no relation to geographic areas. The bottleneck results also showed no significant values. Based on these data we postulated that complex marine currents and larval dispersal shaped the genetic structured of studied populations. The present study illustrated the importance of understanding the biological significance of genetic differentiation when using molecular data in identifying units for management and protection.

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