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        Commutability Assessment of Candidate External Quality Assessment Materials for Aminotransferase Activity Measurements Based on Different Approaches in China

        Long Qichen,Qi Tianqi,Zhang Tianjiao,Wang Jing,Zeng Jie,Ying Yan,Meng Wang,Wei Huang,Haijian Zhao,Wenxiang Chen,Chuanbao Zhang 대한진단검사의학회 2021 Annals of Laboratory Medicine Vol.41 No.1

        Background: Using commutable external quality assessment (EQA) materials is important for monitoring successful harmonization efforts. We assessed the commutability of four human serum pool (HSP) preparations to identify candidate EQA materials for alanine aminotransferase (ALT) and aspartate aminotransferase (AST) activity measurement. Methods: One set each of 85 clinical samples (CSs) was collected for ALT and AST activity measurement. The 15 candidate EQA materials included four types of HSP preparations (A to D): materials A, C, and D contained human original recombinant (HOR) aminotransferases; materials B was mixed leftover samples. The CSs and 15 candidate EQA materials were analyzed using seven routine assays, and the ln-transformed results were analyzed in 21 assay pairs. Commutability was assessed using Deming regression, with a 95% prediction interval (CLSI approach) and the difference in bias with an error component model (International Federation of Clinical Chemistry and Laboratory Medicine [IFCC] approach). Results: For ALT, all materials were commutable for 14–21 assay pairs according to the CLSI and IFCC approaches. For AST, B01-03 showed commutability for 14-21 assay pairs, and C01-03 and D01-03 showed commutability for no less than 10 assay pairs according to the two approaches. A01-06 were commutable for 9-16 assay pairs according to the CLSI approach, but for 6-9 assay pairs according to the IFCC approach. Conclusions: Mixed leftover samples showed desirable commutability characteristics as candidate EQA materials for routine aminotransferase activity measurements. Human serum bases supplemented with HOR were commutable for most routine ALT activity measurements.

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        ZnO/TiO2 core–shell heterojunction for CdS and PbS quantum dot-cosensitized solar cells

        Fangfang Gao,Qian Chen,Xiaoshan Zhang,Huan Wang,Tianjiao Huang,Liya Zhou 한국물리학회 2018 Current Applied Physics Vol.18 No.5

        ZnO nanorods (NRs) with regular morphology were prepared through hydrothermal method, and the TiO2 shell was assembled onto the surface of ZnO NRs by spin coating to the ZnO/TiO2 core–shell heterojunction. CdS and PbS quantum dots (QDs) were used to cosensitize the ZnO/TiO2 nanostructure by direct adsorption (DA) and successive ionic layer adsorption and reaction, respectively. SEM, TEM, and HRTEM images show that the samples possessed a rough surface and four lattice fringes indicating the successful synthesis of the ZnO/TiO2/ CdS/PbS composite structure. The ZnO/TiO2(10T)/CdS/PbS sample showed a high absorption intensity at a broad range of wavelength to visible light region. The ZnO/TiO2(10T)/CdS/PbS photoelectrode with QDSSCs showed the highest IPCE of 36.04% and photoelectric efficiency (η) of 1.59%; these values increased by approximately 550% and 150% compared with those of unsensitized ZnO (0.29%) and ZnO/TiO2(10T) (1.04%) and about 146% and 120% compared with those of ZnO/TiO2(10T)/CdS and ZnO/TiO2(10T)/PbS, respectively. The fill factor was 0.36, and the photocurrent density (Jsc) and open circuit voltage (Voc) reached the maximum values of 9.73 mA cm−2 and 0.46 V, respectively.

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