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        Identification of mountain-cultivated ginseng and cultivated ginseng using UPLC/oa-TOF MSE with a multivariate statistical sample-profiling strategy

        Xu, Xin-fang,Cheng, Xian-long,Lin, Qing-hua,Li, Sha-sha,Jia, Zhe,Han, Ting,Lin, Rui-chao,Wang, Dan,Wei, Feng,Li, Xiang-ri The Korean Society of Ginseng 2016 Journal of Ginseng Research Vol.40 No.4

        Background: Mountain-cultivated ginseng (MCG) and cultivated ginseng (CG) both belong to Panax ginseng and have similar ingredients. However, their pharmacological activities are different due to their significantly different growth environments. Methods: An ultra-performance liquid chromatography/quadrupole time-of-flight mass spectrometry (UPLC-QTOF-MS/MS)-based approach was developed to distinguish MCG and CG. Multivariate statistical methods, such as principal component analysis and supervised orthogonal partial-least-squares discrimination analysis were used to select the influential components. Results: Under optimized UPLC-QTOF-MS/MS conditions, 40 ginsenosides in both MCG and CG were unambiguously identified and tentatively assigned. The results showed that the characteristic components of CG and MCG included ginsenoside Ra3/isomer, gypenoside XVII, quinquenoside R1, ginsenoside Ra7, notoginsenoside Fe, ginsenoside Ra2, ginsenoside Rs6/Rs7, malonyl ginsenoside Rc, malonyl ginsenoside Rb1, malonyl ginsenoside Rb2, palmitoleic acid, and ethyl linoleate. The malony ginsenosides are abundant in CG, but higher levels of the minor ginsenosides were detected in MCG. Conclusion: This is the first time that the differences between CG and MCG have been observed systematically at the chemical level. Our results suggested that using the identified characteristic components as chemical markers to identify different ginseng products is effective and viable.

      • SCIESCOPUS

        Analytical solution for natural frequency of monopile supported wind turbine towers

        Rong, Xue-Ning,Xu, Ri-Qing,Wang, Heng-Yu,Feng, Su-Yang Techno-Press 2017 Wind and Structures, An International Journal (WAS Vol.25 No.5

        In this study an analytical expression is derived for the natural frequency of the wind turbine towers supported on flexible foundation. The derivation is based on a Euler-Bernoulli beam model where the foundation is represented by a stiffness matrix. Previously the natural frequency of such a model is obtained from numerical or empirical method. The new expression is based on pure physical parameters and thus can be used for a quick assessment of the natural frequencies of both the real turbines and the small-scale models. Furthermore, a relationship between the diagonal and non-diagonal element in the stiffness matrix is introduced, so that the foundation stiffness can be obtained from either the p-y analysis or the loading test. The results of the proposed expression are compared with the measured frequencies of six real or model turbines reported in the literature. The comparison shows that the proposed analytical expression predicts the natural frequency with reasonable accuracy. For two of the model turbines, some errors were observed which might be attributed to the difference between the dynamic and static modulus of saturated soils. The proposed analytical solution is quite simple to use, and it is shown to be more reasonable than the analytical and the empirical formulas available in the literature.

      • KCI등재

        Analytical solution for natural frequency of monopile supported wind turbine towers

        Xue-Ning Rong,Ri-Qing Xu,Heng-Yu Wang,Su-Yang Feng 한국풍공학회 2017 Wind and Structures, An International Journal (WAS Vol.25 No.5

        In this study an analytical expression is derived for the natural frequency of the wind turbine towers supported on flexible foundation. The derivation is based on a Euler-Bernoulli beam model where the foundation is represented by a stiffness matrix. Previously the natural frequency of such a model is obtained from numerical or empirical method. The new expression is based on pure physical parameters and thus can be used for a quick assessment of the natural frequencies of both the real turbines and the small-scale models. Furthermore, a relationship between the diagonal and non-diagonal element in the stiffness matrix is introduced, so that the foundation stiffness can be obtained from either the p-y analysis or the loading test. The results of the proposed expression are compared with the measured frequencies of six real or model turbines reported in the literature. The comparison shows that the proposed analytical expression predicts the natural frequency with reasonable accuracy. For two of the model turbines, some errors were observed which might be attributed to the difference between the dynamic and static modulus of saturated soils. The proposed analytical solution is quite simple to use, and it is shown to be more reasonable than the analytical and the empirical formulas available in the literature.

      • KCI등재

        An Egg-Shaped Elastic Viscoplastic Model for Clay: Experimental Investigation and Constitutive Modelling

        Pan Ding,Luying Ju,Ri-Qing Xu,Zihai Yan,Mingming Wu,Gangping Zhang 대한토목학회 2023 KSCE Journal of Civil Engineering Vol.27 No.5

        This paper presents the experimental investigation carried out for evaluation of the rheological behaviours of Hangzhou soft clay, and proposes a three-dimensional elastic viscoplastic model to describe the rheological characteristics under triaxial condition. Firstly, the time-dependent behaviours of Hangzhou soft clay, such as creep and strain rate effects, were observed and discussed based on the analysis of rheological tests. Subsequently, a constitutive model was formulated under the framework of Perzyna’s overstress theory and incorporates other developments, including: 1) A smooth and continuous egg-shaped yield surface, whose shape can change from an ellipse to a teardrop shape, thus providing greater flexibility for better modelling; 2) An equivalent time concept, which enables the model to describe the time-dependent behaviours under different loading paths. By varying the shape parameter, the newly established model can be degenerated into modified Cam-clay (MCC) model or Yin-Graham elastic viscoplastic model. Finally, the model was solved numerically using the fourth-order convergent iterative method combined with the Runge-Kutta method. Comparison of simulation results and experimental data shows that the newly proposed model has an ability to predict creep characteristics and strain rate effects of soft clay.

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