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      • Resonance analysis of cantilever porous graphene platelet reinforced pipe under external load

        Qinghua Huang,Xinping Yu,Jun Lv,Jilie Zhou,Marischa Ray Elvenia 국제구조공학회 2022 Steel and Composite Structures, An International J Vol.45 No.3

        Nowadays, there is a high demand for great structural implementation and multifunctionality with excellent mechanical properties. The porous structures reinforced by graphene platelets (GPLs) having valuable properties, such as heat resistance, lightweight, and excellent energy absorption, have been considerably used in different engineering implementations. However, stiffness of porous structures reduces significantly, due to the internal cavities, by adding GPLs into porous medium, effective mechanical properties of the porous structure considerably enhance. This paper is relating to vibration analysis of fluidconveying cantilever porous graphene platelet reinforced (GPLR) pipe with fractional viscoelastic model resting on foundations. A dynamical model of cantilever porous GPLR pipes conveying fluid and resting on a foundation is proposed, and the vibration, natural frequencies and primary resonant of such a system are explored. The pipe body is considered to be composed of GPLR viscoelastic polymeric pipe with porosity in which Halpin-Tsai scheme in conjunction with the fractional viscoelastic model is used to govern the construction relation of nanocomposite pipe. Three different porosity distributions through the pipe thickness are introduced. The harmonic concentrated force is also applied to the pipe and the excitation frequency is close to the first natural frequency. The governing equation for transverse motions of the pipe is derived by the Hamilton principle and then discretized by the Galerkin procedure. In order to obtain the frequency-response equation, the differential equation is solved with the assumption of small displacement, damping coefficient, and excitation amplitude by the multiple scale method. A parametric sensitivity analysis is carried out to reveal the influence of different parameters, such as nanocomposite pipe properties, fluid velocity and nonlinear viscoelastic foundation coefficients, on the primary resonance and linear natural frequency. Results indicate that the GPLs weight fraction porosity coefficient, fractional derivative order and the retardation time have substantial influences on the dynamic response of the system.

      • KCI등재

        Thermally Healable Polyurethanes Based on Furfural-Derived Monomers via Baylis-Hillman Reaction

        Qinghua Huang,Fanghong Yang,Xingxing Cao,Zhongyu Hu,Chuanjie Cheng 한국고분자학회 2019 Macromolecular Research Vol.27 No.9

        Two novel acrylate monomers with diol group, 2-hydroxyethyl 2-(furan- 2-yl(hydroxy)methyl)acrylate and methyl 2-(hydroxy(5-(hydroxymethyl)furan-2- yl)methyl)acrylate, were synthesized via Baylis-Hillman reaction in moderate yields. The monomer 2-hydroxyethyl 2-(furan-2-yl(hydroxy)methyl)acrylate was obtained from furfural and 2-hydroxyethyl acrylate (HEA); methyl 2-(hydroxy(5-(hydroxymethyl)furan- 2-yl)methyl)acrylate was prepared from 5-hydroxymethl furfural (HMF) and methyl acrylate. The monomer 2-hydroxyethyl 2-(furan-2-yl(hydroxy)methyl)acrylate reacted with toluene diisocyanate (TDI)-derived or hexamethylene diisocyanate (HDI)-derived diisocyanate oligomers to obtain the corresponding linear polyurethane oligmers PU-1T and PU-1H. Similarly, the diol methyl 2-(hydroxy(5-(hydroxymethyl)furan- 2-yl)methyl)acrylate reacted with TDI- or HDI-derived diisocyanate oligomers to obtain the corresponding linear polyurethane oligmers PU-2T and PU-2H. The numberaverage molecular weights of the linear polyurethane oligomers are approximately 300-350 Da. There are furan groups in the linear polyurethane oligomers PU-1T, PU-1H, PU-2T and PU-2H, which makes them capable of undergoing reversible Diels-Alder reaction with 4,4'- bismaleimidodiphenylmethane (BMI) to form the corresponding crosslinked polyurethanes CPU-1T, CPU-1H, CPU-2T and CPU-2H. Pencil hardness of CPU-1T, CPU-1H, CPU-2T and CPU-2H are 3H, 2H, 2H and HB, respectively. Glass transition temperatures of CPU-1T, CPU- 1H, CPU-2T and CPU-2H are 104.8, 97.6, 5.1 and 1.2 oC, respectively. TGA analysis shows that Td90 values of the CPUs range from 180 to 250 oC. Furthermore, the reversible crosslinked polyurethanes CPU-1T and CPU-1H can be completely self-healed at 90 oC for 3 h, while CPU-2T and CPU-2H can self-heal at 80 oC for 3 h presumably due to their low glass transition temperatures.

      • KCI등재

        Cyclic Response and Constitutive Model Study of G20Mn5QT Cast Steel

        Qinghua Han,Qianwen Huang,Yan Lu 한국강구조학회 2020 International Journal of Steel Structures Vol.20 No.4

        A series of cyclic loading tests of G20Mn5QT cast steel are carried out at the strain ratio of − 1. The results of tests show that the G20Mn5QT cast steel has the similar tendency in cyclic softening with diff erent constant strain amplitude. A slight strain softening is observed, and then the stress states keep steady during the remaining cycles. A new damage variable is proposed considering the eff ects of strength degeneration within two inner variables which are the maximum equivalent plastic strain and the equivalent plastic strain increment. The damage variable provides better insight into the multiaxial cyclic loading and gives a reasonable prediction of failure under the loading history of constant strain amplitude. The proposed damage variable is further introduced in the cyclic constitutive model by the user subroutine interfaces VUMAT by the software ABAQUS. The relationships between the equivalent plastic strain and the damage variable, Young’s modulus and yield strength are fi nally put forward as it is expedient to get the equivalent plastic strain in the numerical analysis.

      • SCIESCOPUSKCI등재

        A simple electrospinning strategy to achieve the uniform distribution of ultra‑fine CoP nanocrystals on carbon nanofibers for efficient lithium storage

        Qinghua Wang,Wei Wang,Junlin Huang,Hong Yin,Yucan Zhu,Haitao Wang,Minjie Zhou,Binhong He,Zhaohui Hou,Wenyuan Xu 한국탄소학회 2023 Carbon Letters Vol.33 No.1

        Transition-metal phosphides (TMPs), a promising anode material for lithium-ion batteries (LIBs), are limited in application because of its serious volume effect in the cycle. In this work, a simple electrospinning strategy was proposed to restrict the grain size of CoP nanocrystals by nano-confined effect of carbon nanofibers with ligands. The addition of ligands not only could realize the uniform dispersion of CoP nanocrystals, but also strengthen the bond between the metals and carbon nanofibers. As a result, the CoP/CNF composite exhibits excellent lithium storage performance, and its reversible specific capacity could reach 1016.4 mAh g? 1 after 200 cycles at a current density of 200 mA g? 1. The research is anticipated to provide a new idea for the preparation of anode materials for lithium ion batteries.

      • KCI등재

        Receiver-centric Buffer Blocking-aware Multipath Data Distribution in MPTCP-based Heterogeneous Wireless Networks

        ( Yuanlong Cao ),( Qinghua Liu ),( Yi Zuo ),( Fenfen Ke ),( Hao Wang ),( Minghe Huang ) 한국인터넷정보학회 2016 KSII Transactions on Internet and Information Syst Vol.10 No.10

        One major concern of applying Multipath TCP (MPTCP) to data delivery in heterogeneous wireless networks is that the utilization of asymmetric paths with diverse networking-related parameters may cause severe packet reordering and receive buffer blocking (RB<sup>2</sup>LOC). Although many efforts are devoting to addressing MPTCP`s packet reordering problems, their sender-controlled solutions do not consider balancing overhead between an MPTCP sender and receiver, and their fully MPTCP mode cannot make MPTCP achieve a desired performance. This paper proposes a novel receiver-centric buffer blocking-aware data scheduling strategy for MPTCP (dubbed MPTCP-rec) necessitating the following aims: (1) alleviating MPTCP`s packet reordering and RB<sup>2</sup>LOC problems, (2) improving the MPTCP performance, and (3) balancing load between the MPTCP sender and receiver. Simulation results show that the proposed MPTCP-rec solution outperforms the existing MPTCP solutions in terms of data delivery performance in heterogeneous wireless networks.

      • KCI등재

        Receiver-driven Cooperation-based Concurrent Multipath Transfer over Heterogeneous Wireless Networks

        ( Yuanlong Cao ),( Qinghua Liu ),( Yi Zuo ),( Minghe Huang ) 한국인터넷정보학회 2015 KSII Transactions on Internet and Information Syst Vol.9 No.7

        The advantages of employing SCTP-based Concurrent Multipath Transfer (CMT) have been demonstrated to be very useful for data delivery over multi-homed wireless networks. However, there is still significant ongoing work addressing some remaining limitations and challenges. The most important concern when applying CMT to data delivery is related to handling packet reordering and buffer blocking. Another concern on this topic is that current sender-based CMT solutions seldom consider balancing the overhead and sharing the load between the sender and receiver. This paper proposes a novel Receiver-driven Cooperation-based Concurrent Multipath Transfer solution (CMT-Rev) with the following aims: (i) to balance overhead and share load between the sender and receiver, by moving some functions including congestion and flow control from the sender onto receiver; (ii) to mitigate the data reordering and buffer blocking problems, by using an adaptive receiver-cooperative path aggregation model, (iii) to adaptively transmit packets over multiple paths according to their receiver-inspired sending rate values, by employing a new receiver-aware data distribution scheduler. Simulation results show that CMT-Rev outperforms the existing CMT solutions in terms of data delivery performance.

      • KCI등재후보

        Preservation of Simmental bull sperm at 0°C in Tris dilution: effect of dilution ratio and long-distance transport

        Jiang Shouqing,Huang Fei,Niu Peng,Wang Jieru,He Xiaoxia,Han Chun-mei,Gao Qinghua 아세아·태평양축산학회 2024 Animal Bioscience Vol.37 No.2

        Objective: This study aimed to assess the impact of the dilution ratio of Tris diluent, storage at 0°C, and long-distance transportation on the spermatozoa of Simmental cattle. It also validated the feasibility of the regional distribution of fresh semen. Methods: In experiment 1, semen was diluted at four dilution ratios (1:6, 1:9, 1:12, and 1:15) to determine the optimal dilution ratio of Tris diluent. In experiment 2, we assessed sperm viability, progressive motility (objectively assessed by computer-assisted sperm analyzer), and acrosome intactness in Tris dilutions kept at constant 0°C for 1, 3, 6, 9, and 12 days. We compared them to Tianshan livestock dilutions (Commercial diluent). In experiment 3, semen was diluted using Tris diluent, and sperm quality was measured before and after long-distance transport. Artificial insemination of 177 Simmental heifers compared to 156 using Tianshan Livestock dilution. Results: The outcomes demonstrated that 1:9 was the ideal Tris diluent dilution ratio. The sperm viability, Progressive Motility, and acrosome integrity of both Tris and Tianshan dilutions preserved at 0°C gradually decreased over time. sperm viability was above 50% for both dilutions on d 9, with a flat rate of decline. The decrease in acrosome integrity rate was faster for Tianshan livestock dilutions than for Tris dilutions when stored at 0°C for 1 to 6 days. There was no significant difference (p>0.05) in sperm viability between semen preserved in Tris diluent after long-distance transportation and semen preserved in resting condition. The conception rates for Tris dilution and Tianshan livestock dilution were 49.15% and 46.15% respectively, with no significant difference (p>0.05). Conclusion: This shows that Tris diluent is a good long-term protectant. It has been observed that fresh semen can be successfully preserved for long-distance transport when stored under 0°C conditions. Additionally, it is feasible to distribute semen regionally.

      • KCI등재

        Structure and Properties of Aromatic Polyimide Fibers Fabricated by a Novel “Reaction-Spinning” Method

        Zhentao Li,Jie Dong,Jian Huang,Tao Guo,Shihua Wang,Xin Zhao,Qinghua Zhang 한국고분자학회 2020 Macromolecular Research Vol.28 No.1

        In this work, two sets of high performance polyimide (PI) fibers fabricated by a more environmentally-friendly and highly efficient “reaction-spinning” method were firstly reported. The relationship between the spinning rate, chemical structure and the imidization degree of the PI precursor fibers were investigated, and the results indicated a moderate low spinning speed and relatively flexible molecular chains are both favorable for the partial imidization reaction in the spinning process. 2D WAXD results demonstrate that the rigid PDA-based PI fibers possess a higher alignment of polymer chains along the fiber axis during the spinning compared to the flexible ODA-based PIs, resulting in enhanced mechanical properties, with the tensile strength of 1.2-2.8 GPa and modulus of 53.6-111.2 GPa, respectively. Meanwhile, ODA sets of PI fibers exhibit a higher loop strength and knot strength than the commercial Aramid and PBO fibers. The process used in this study has a significant potential for realizing industrial level production of high strength and high modulus PI fibers.

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