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Thermoelectric properties of Gd, Y co-doped Ca3Co4O9+δ
H.Q. Liu,X.B. Zhao,T.J. Zhu,Y. Song,F.P. Wang 한국물리학회 2009 Current Applied Physics Vol.9 No.3
The Ca3-x-yGdxYyCo4O9+δ precursor powders were synthesized by the polyacrylamide gel method. The powders were sintered by the spark plasma sintering (SPS). The DTA analysis showed that the synthesis temperature of Ca3Co4O9+δ was about 933 K, which is lower than that of the conventional citric acid method. The resistivities, the Seebeck coefficients and the thermal conductivities of the samples were measured from room temperature to 973 K. The Seebeck coefficients and the resistivities of the doped samples were remarkably enhanced due to the decrease of the carrier concentration, whereas the thermal conductivities of them were decreased due to the impurity scattering effect. The maximal ZT value of 0.26 was obtained at 973 K for Ca2.7 Gd0.15 Y0.15Co4O9+δ. The Ca3-x-yGdxYyCo4O9+δ precursor powders were synthesized by the polyacrylamide gel method. The powders were sintered by the spark plasma sintering (SPS). The DTA analysis showed that the synthesis temperature of Ca3Co4O9+δ was about 933 K, which is lower than that of the conventional citric acid method. The resistivities, the Seebeck coefficients and the thermal conductivities of the samples were measured from room temperature to 973 K. The Seebeck coefficients and the resistivities of the doped samples were remarkably enhanced due to the decrease of the carrier concentration, whereas the thermal conductivities of them were decreased due to the impurity scattering effect. The maximal ZT value of 0.26 was obtained at 973 K for Ca2.7 Gd0.15 Y0.15Co4O9+δ.
G. Shi,Z. Liu,H.Y. Ban,Y. Zhang,Y.J. Shi,Y.Q. Wang 국제구조공학회 2012 Steel and Composite Structures, An International J Vol.12 No.1
Local buckling can be ignored for hot-rolled ordinary strength steel equal angle compression members, because the width-to-thickness ratios of the leg don’t exceed the limit value. With the development of steel structures, Q420 high strength steel angles with the nominal yield strength of 420 MPa have begun to be widely used in China. Because of the high strength, the limit value of the width-to-thickness ratio becomes smaller than that of ordinary steel strength, which causes that the width-to-thickness ratios of some hot-rolled steel angle sections exceed the limit value. Consequently, local buckling must be considered for 420 MPa steel equal angles under axial compression. The existing research on the local buckling of high strength steel members under axial compression is briefly summarized, and it shows that there is lack of study on the local buckling of high strength steel equal angles under axial compression. Aiming at the local buckling of high strength steel angles, this paper conducts an axial compression experiment of 420MPa high strength steel equal angles, including 15 stub columns. The test results are compared with the corresponding design methods in ANSI/AISC 360-05 and Eurocode 3. Then a finite element model is developed to analyze the local buckling behavior of high strength steel equal angles under axial compression, and validated by the test results. Followingthe validation, a finite element parametric study is conducted to study the influences of a range of parameters, and the analysis results are compared with the design strengths by ANSI/AISC 360-05 and Eurocode 3.
Cyclic Oxidation Behavior of Thermal Barrier Coatings Irradiated by High-intensity Pulsed Ion Beam
J. I. Song(송정일),Y. Q. Wang(왕일기),Y. G. Kwun(권용구),W. K. JOO(주원경) 한국자동차공학회 2007 한국자동차공학회 춘 추계 학술대회 논문집 Vol.- No.-
High-temperature oxidation resistance of 7 wt. % Y₂O₃-ZrO₂ thermal barrier coatings (TBCs) irradiated by high-intensity pulsed ion beam (HIPIB) has been investigated in a cyclic oxidation condition at 1050 ℃×1 h. The characteristics of the columnar grains disappeared after HIPIB irradiation at the ion current densities of 100-200 A/㎠, and the irradiated surface presented a smoothed, densified feature after the remelting and ablation due to the HIPIB irradiation. The cross-sectional morphologies of HIPIB-irradiated TBCs show less oxidation of the NiCoCrAlY bonding layer, with a thinner thermally grown oxide (TGO) layer. The morphology observation is consistent with the results of cyclic oxidation test. It is found that the inward diffusion of oxygen through TBCs can be significantly impeded by the desified top layer by the HIPIB irradiation, thus limiting the oxidation of the bonding layer, improving the overall oxidation resistance of the irradiated TBCs.
( L. Wei ),( F. Wang ),( M. Zhang ),( J. Jia ),( A.A. Yakovlev ),( W. Xie ),( E.Z. Burnevich ),( J. Niu ),( Y.J. Jung ),( X. Jiang ),( M. Xu ),( X. Chen ),( Q. Xie ),( J. Li ),( J. Hou ),( H. Tang ),( 대한간학회 2017 춘·추계 학술대회 (KASL) Vol.2017 No.1
Background/Aims: Treatment-naive GT 1b-infected patients from mainland China, South Korea and Russia were assessed for SVR at follow-up week 12 (SVR12) after receiving daclatasvir (60 mg, QD) and asunaprevir (100 mg, BID) (DCV+ASV). Methods: Patients were randomized 3:1 to receive DCV+ASV (24 weeks; immediate treatment [IM]) or 12 weeks of placebo followed by DCV+ASV (24 weeks; placebo-deferred treatment [PD]). The primary endpoint was to evaluate SVR12 in the IM arm to the historical rate for peginterferon/ribavirin (70%). Secondary endpoints included overall safety and safety comparisons between the treatment arms during the first 12 weeks. Results: 207 patients were randomized to IM (n=155) or PD (n=52); Asian (86%), female (59%), IL28B CC genotype (68%) and median age 49 (range 18-73) years; cirrhosis (13%), HCV RNA ≥6x106 IU/mL (53%). SVR12 in the IM arm was 92% and broadly unaffected by most baseline factors assessed (Figure); SVR12 was higher in patients without (96%) baseline NS5A-L31M/V or Y93H polymorphisms. There were 6 virologic breakthroughs, 6 relapses and 1 detectable HCV RNA at end-of-treatment in the IM arm. Safety was mostly comparable between the two arms during the first 12 weeks. The most frequent adverse events (AEs; ≥5%) during DCV+ASV (24 weeks) treatment in both arms were aminotransferase, bilirubin and INR elevations, hypertension, fatigue and respiratory tract infections; the most frequent treatment-emergent grade 3/4 laboratory abnormalities were aminotransferase (≤4.5%) and hematologic, lipase and total bilirubin abnormalities (≤2%); one patient (IM) discontinued DCV+ASV for aminotransferase elevations, nausea and jaundice (all reversible); one patient PD) discontinued DCV+ASV for a fatal AE unrelated to treatment. Conclusions: These data demonstrate that DCV+ASV is a highly efficacious and well tolerated treatment for treatment-naive HCV GT 1b-infected patients. Those treated immediately with DCV+ASV achieved a 92% SVR12 rate which was unaffected by factors known to attenuate response to interferon.
The Synthesis and Spectral Properties of Some New Monomethine Cyanine Dyes for Live Cell Imaging
Y. L. Fu,Y. Z. Zhou,G. Zhang,Q. C. Yang,X. Zhai,L. Y. Wang 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.2
Four monomethine cyanine dyes were synthesized and their structures were confirmed by 1H NMR, IR, UV–Vis, and HRMS. Their spectral properties were studied. It could be found that the λmax of the dyes was shorter in the protonic solvents compared with that in the non-protonic solvents. Moreover, the λmax shows a hypsochromic shift with the increasing polarity of the solvents. The interactions of four dyes with DNA were also studied. The results showed that the fluorescence intensities of the dyes 3a and 3b took place a qualitative change in the presence of DNA compared with the free dyes. The dyes used as cellular imaging agents were researched. The results indicated that the dye 3b could penetrate the live cell membrane.
Wang, Y.,Jin, L.,Wen, Q.N.,Kopparapu, N.K.,Liu, J.,Liu, X.L.,Zhang, Y.G. Asian Australasian Association of Animal Productio 2016 Animal Bioscience Vol.29 No.2
The supplementation of livestock feed with animal protein is a present cause for public concern, and plant protein shortages have become increasingly prominent in China. This conflict may be resolved by fully utilizing currently available sources of plant protein. We estimated the rumen degradability and the small intestinal digestibility of the amino acids (AA) in rapeseed meal (RSM), soybean meal (SBM), sunflower seed meal (SFM) and sesame meal (SSM) using the mobile nylon bag method to determine the absorbable AA content of these protein supplements as a guide towards dietary formulations for the dairy industry. Overall, this study aimed to utilize protein supplements effectively to guide dietary formulations to increase milk yield and save plant protein resources. To this end, we studied four cows with a permanent rumen fistula and duodenal T-shape fistula in a $4{\times}4$ Latin square experimental design. The results showed that the total small intestine absorbable amino acids and small intestine absorbable essential amino acids were higher in the SBM (26.34% and 13.11% dry matter [DM], respectively) than in the SFM (13.97% and 6.89% DM, respectively). The small intestine absorbable Lys contents of the SFM, SSM, RSM and SBM were 0.86%, 0.88%, 1.43%, and 2.12% (DM basis), respectively, and the absorbable Met contents of these meals were 0.28%, 1.03%, 0.52%, and 0.47% (DM basis), respectively. Among the examined food sources, the milk protein score of the SBM (0.181) was highest followed by those of the RSM (0.136), SSM (0.108) and SFM (0.106). The absorbable amino acid contents of the protein supplements accurately reflected protein availability, which is an important indicator of the balance of feed formulation. Therefore, a database detailing the absorbable AA should be established.