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M.Z.A. Rafiquee,Masoom R. Siddiqui,H.N. Haque,M. Shamsul Ola,Hamad A. Al-Lohedan,Z.A. ALOthman,Saikh M. Wabaidur 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.34 No.-
Reduction of molecular oxygen by 2-mercaptoethanol in the presence of cobalt(II)histidine is described. Cobalt(II)histidine complex forms dinuclear 2:1 (Co:O2) complex with molecular oxygen (m-dioxyte-trakis(histidinato)dicobalt(II)). The molecular oxygen did not directly react with 2-mercaptoethanol, but,reacted in the form of an adduct with cobalt(II)histidine complex. During the course of the reaction themolecular oxygen is reduced to hydroxide ion while the cobalt(II)histidine complex was oxidized tocobalt(III)histidine while 2-mercaptoethanol is reduced into 2,20-dithiodiethanol. The decrease inabsorbance for the dioxygen complex was monitored spectrophotometrically and was observed that thevalues of rate constant increased with the increase in [2-mercaptoethanol]. The values of kobs also increasedwith increasing [NaOH]. Thus, from the results of these studies, mechanism of the reaction has beenproposed. In addition, the values of various equilibrium constants and rate constants were also determinedusing nonlinear least square techniques.
Groundwater Dynamics and Balance in the Western Part of Greater Kushtia District of Bangladesh
M. Nozibul Haque,Mumnunul Keramat,Shamsuddin Shahid,Morteza Mohsenipour,Xiao-Jun Wang 대한토목학회 2017 KSCE JOURNAL OF CIVIL ENGINEERING Vol.21 No.5
Groundwater dynamics and balance have been studied for the assessment of groundwater abstraction status in the western part of grater Kushtia district, Bangladesh using data from 28 groundwater level monitoring wells, 180 lithologs, and one rainfall station for the period 2001-2007. The groundwater levels in the study area were found to vary at a depth between 0.0 m and 9.34 m. During peak season of groundwater abstraction (pre-monsoon), the maximum and minimum groundwater level with respect to mean sea level (MSL) were found to vary from 9.36 to 11.3 m and 2.3 to 4.9 m, respectively, whereas in post-monsoon these values were found to vary from 13.2 to 15.6 m and 7.6 to 9.6 m, respectively. The groundwater flow in the area was driven by topography, directed from the northwest to the southeast. This study revealed a declining trend in groundwater table both in pre- and post-monsoon seasons in the area. It has also been noticed that the rate of declination is increasing with time. The volumetric analysis of groundwater also showed a net negative balance, which indicates overexploitation of groundwater. The study concluded that the unsustainable utilization of groundwater resources in the study area has caused depletion in groundwater table.
Fabrication of Bismuth Vanadate (BiVO4)Nanoparticles by a Facile Route
M. F. Rahman,M. S. Haque,M. Hasan,M. A. Hakim 한국전기전자재료학회 2019 Transactions on Electrical and Electronic Material Vol.20 No.6
Monoclinic bismuth vanadate (m-BiVO4 ) has attracted many researchers as an advanced photocatalyst for hydrogen production via water splitting and degradation of organic contaminants. In this study, pure m-BiVO4 nanoparticles were fabricated by an easy reproducible solid state route at different temperatures (500 °C, 550 °C, 600 °C, 650 °C and 700 °C) for 2 h. The synthesized materials were characterized by X-ray Diff ractometer where all the diff raction patterns reveal characteristic peaks corresponding to m-BiVO 4 with space group C2/c. Obtained m-BiVO4 particles have the lattice parameters: a = 7.2477 Å, b = 11.6970 Å, c = 5.0900 Å and the volume of the unit cell is 309.23 (106 pm 3 ). Fourier Transform Infrared spectroscopy exhibits formation of Bi–O bond in the prepared nano powders. Ultraviolet–Visible diff use refl ectance spectroscopy suggests that nanostructured BiVO4 particles possess strong energy absorption properties both in visible and ultraviolet region. The particles show red shift of band gap as the calcination temperature rises and possible reasons have been discussed. Energydispersive X-ray spectroscopy confi rms presence of Bi, V, and O without any contaminant, while particle’s morphology was investigated using Field Emission Scanning Electron Microscope.
Hossen Quazi Md. Mosaddeque,Rahman S. M. Badier,Rahman Md. Nazibur,Sarker Muhammad Delwar Hossain,Moniruzzaman Md.,Tareq Md. Zablul,Sadat Md. Abu,Arafat Kazi Md. Yasin,Jahan Md. Sarwar,Haque Md. Samiu 한국작물학회 2022 Journal of crop science and biotechnology Vol.25 No.4
Polyethene is a global environmental threat, whereas jute (Corchorus spp.) fber is biodegradable, eco-friendly and can be used as a substitute for polyethene. Jute is a short-day plant and cultivated in March to July in Indian subcontinent for bast fber production. This season-bound cultivation nature hampers continuous supply of bast fber in the industry. In addition, its long cultivation period creates difculties to accommodate other high-value crops. To address these issues, a short life span (early fowering) jute genotype is extremely felt in jute growing areas of the world. But, unfortunately such variety has not been developed yet through both conventional and biotechnological approach. Accordingly, we adopted chemical mutagenesis by establishing LD50 (Lethal Dose) of EMS (Ethyl Methane Sulfonate) at 150 mM with 4h’ incubation for Capsularis jute seed. A novel mutant was found named—Komola, which showed a shorter lifespan than its ancestor by fowering at 70 days instead of 120 days. In addition, the mutant's stem and petiole was coppery-red instead of green. Molecular analysis revealed four SNPs in PMIR1 (Plastid Movement Impaired 1 Related 1) and two clade deletions in ELF3 (Early Flowering 3) genes from stable M4 generation. Histochemical and biochemical analyses explained this genotype’s lower content of lignin. This mutant could be used as future breeding material for the development of year-round cultivable jute genotype along with ofer up accommodation of other high-value agricultural crops in cropping pattern with a good source of year-round supply of bast fber to the industry
Soil Properties in Two Forest Sites in Cox's Bazar, Bangladesh
Akhtaruzzaman, Md.,Osman, K.T.,Sirajul Haque, S.M. Institute of Forest Science 2015 Journal of Forest Science Vol.31 No.4
Soil samples were collected from three depths (0-10 cm, 10-40 cm and 40-80 cm) of two forest sites including one plantation dominated by teak with some other minor species and another degraded natural forest in Cox's Bazar, Bangladesh to compare their soil properties. Some vegetation parameters were also studied. For this study $10{\times}10\;m$ and $2{\times}2\;m$ quadrats were used for the tree and undergrowth parameters, respectively. Soil samples were also collected from these quadrats. Between the two forest types, the highest levels of organic carbon, total nitrogen, available phosphorus, exchangeable bases and cation exchange capacity (CEC) were found in soils of the plantation. The soils were acidic in nature and exchangeable Al concentrations were low. Teak dominated forest plantation had higher soil fertility index (SFI) than the degraded natural forest site. Steps for reforestation and appropriate protection are needed to improve the situation.
Mayeen Uddin KHANDAKER,Guinyun Kim,A.K.M. Moinul Haque Meaze,Dongchul Son,Kwangsoo Kim,Young Seok Lee 한국물리학회 2006 THE JOURNAL OF THE KOREAN PHYSICAL SOCIETY Vol.48 No.4
We measured the production cross-sections of 99mTc, 96(m+g)Tc, 95mTc, and 95gTc radioisotopes for proton-induced reactions on molybdenum by using a stacked-foil activation technique in the energy range of 10 . 30 MeV at the MC50 cyclotron of the Korea Institute of Radiological and Medical Sciences. Reactions induced on the aluminum and copper foils were used to monitor the parameters of the proton beam. The present measurements are in generally good agreement with the earlier reported data in the investigated energy region. reg_id_no
Study of Euglenophytes Bloom and it’s Impact onFish Growth in Bangladesh
M.M. Rahman,M.M. Haque,S. Khan,M.A.S. Jewel 한국조류학회I 2007 ALGAE Vol.22 No.3
A study was carried out in nine fertilized fish ponds under three treatments (T-I, T-II and T-III) at Bangladesh Agricultural University, Mymensingh to see the bloom of euglenophytes with the intention of observing its impact on the growth of fish in culture condition. Some water quality parameters viz., temperature, dissolved oxygen, pH, PO4-P and NO3-N concentration and some biological parameters viz., phytoplankton population and growth of fish were monitored at fixed intervals. Euglenophytes showed a heavy bloom in late August in the ponds of T-II. The bloom was occurred by the genera, Euglena, Phacus and Trachelomonas of which Euglena was the most dominant genus. In relation of water quality parameters with euglenophytes bloom, it was hypothesized that euglenophytes prefers higher temperature and acidic environment with higher nutrient concentrations. Acidic environment and nutrient enrichment enhanced the bloom of euglenophytes which hampered the growth of other beneficial algal groups (chlorophytes and bacillariophytes) and fish. Due to heavy bloom, the fishes breathed with difficulty at the surface. The fishes in the heavy bloom ponds presented the weight values were lower than verified for those in the ponds where the bloom did not occur. Total production (calculated) of fish in different treatments ranged from 1355.89 to1760.63 kg ha–1 with significantly (p < 0.05) lowest in the ponds of T-II.