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Crystallization and melting behavior of polypropylene in b-PP/polyamide 6 blends containing PP-g-MA
Zhidan Lin,Zixian Guan,Baofeng Xu,Chao Chen,Guangheng Guo,Jiaxian Zhou,Jiaming Xian,Lin Cao,Yueliang Wang,Mingqing Li,Wei Li 한국공업화학회 2013 Journal of Industrial and Engineering Chemistry Vol.19 No.2
In this research, we used a twin-screw extruder to melt and blend PP-g-MA compatibilizer with bpolypropylene (PP)/polyamide 6 (PA6). The influences of the PA6 and PP-g-MA contents in PP/PA6 blends on crystallization and melting behavior of PP phase and morphology were investigated. The results showed that, when PP-g-MA copolymer was added to the b form of nucleated PP/PA6 blends, the anhydride groups in PP-g-MA and PA6 terminal amine groups react to form PP-g-PA graft copolymer in a two-phase interface. This reduces the interfacial tension, improves the interfacial adhesion, and reduces the size of PA6 domains in the blend. The generated PP-g-PA graft copolymer wrapped PA6 phase and buried the anhydride groups of PP-g-MA. When the proportion of PP-g-MA and PA6 was between 0.5 and 0.75, there was no longer interfering to the formation of b-crystals in the PP phase. The content of bcrystal of PP phase in blends was found to reach as large as 85.9%.