Long-lived spin states of Fe atomic chains on Cu₂N via Hamiltonian engineering

J. Oh,R.J.G. Elbertse,D. Borodin,T. Ahn,J. Hwang,J. Rietveld,F. Delgado,A.J. Heinrich,S.F. Otte,Y. Bae 한국자기학회 2023 한국자기학회 학술연구발표회 논문개요집 Vol.33 No.1

Mapping Orbital-Resolved Magnetism in Single Lanthanide Atoms

A. Singha,D. Sostina,C. Wolf,S. L. Ahmed,D. Krylov,L. Colazzo,P. Gargiani,S. Agrestini,W.-S. Noh,J.-H. Park,M. Pivetta,S. Rusponi,H. Brune,A. J. Heinrich,A. Barla,F. Donati 한국자기학회 2023 한국자기학회 학술연구발표회 논문개요집 Vol.33 No.1

Charge carrier mobility study of a mesogenic thienothiophene derivative in bulk and thin films

Mazur, L.,Castiglione, A.,Ocytko, K.,Kameche, F.,Macabies, R.,Ainsebaa, A.,Kreher, D.,Heinrich, B.,Donnio, B.,Sanaur, S.,Lacaze, E.,Fave, J.L.,Matczyszyn, K.,Samoc, M.,Wu, J.W.,Attias, A.J.,Ribierre, Elsevier Science 2014 Organic electronics Vol.15 No.4

A novel mesogenic 2,5-bis-(5-octylthiophene)-thieno[3,2b]thiophene (TT) derivative has been synthesized. The fused-ring thiophene, end-capped with two octylthiophenes, exhibits ordered lamellar mesophases which were characterized by polarizing optical microscopy, differential scanning calorimetry and small-angle X-ray diffraction at various temperatures. The charge transport properties were investigated by time-of-flight technique as a function of temperature. On cooling from isotropic phase, a maximum hole mobility value of 0.07cm<SUP>2</SUP>V<SUP>-1</SUP>s<SUP>-1</SUP> was measured in the highly ordered mesophase of the bulk films. Field-effect transistor experiments on both solution and vacuum deposited thin films have also been performed. The solution-processed films exhibit charge carrier mobilities several orders of magnitude lower than values extracted from bulk time-of-flight curves and from vacuum deposited thin film transistors. This work provides evidence that the melt-processing route is an efficient alternative to commonly used solution-processing for fabrication of charge transporting layers from liquid crystalline semiconductors, with performances comparable to evaporation techniques.

Evidence for Hand-Size Constancy : The Dominant Hand as a Natural Perceptual Metric

Linkenauger, Sally A.,Geuss, Michael N.,Stefanucci, Jeanine K.,Leyrer, Markus,Richardson, Beth H.,Proffitt, Dennis R.,Bü,lthoff, Heinrich H.,Mohler, Betty J. SAGE Publications 2014 PSYCHOLOGICAL SCIENCE Vol.25 No.11

<P>The hand is a reliable and ecologically useful perceptual ruler that can be used to scale the sizes of close, manipulatable objects in the world in a manner similar to the way in which eye height is used to scale the heights of objects on the ground plane. Certain objects are perceived proportionally to the size of the hand, and as a result, changes in the relationship between the sizes of objects in the world and the size of the hand are attributed to changes in object size rather than hand size. To illustrate this notion, we provide evidence from several experiments showing that people perceive their dominant hand as less magnified than other body parts or objects when these items are subjected to the same degree of magnification. These findings suggest that the hand is perceived as having a more constant size and, consequently, can serve as a reliable metric with which to measure objects of commensurate size.</P>

Magnetism in Single Metalloorganic Complexes Formed by Atom Manipulation

Choi, T.,Badal, M.,Loth, S.,Yoo, J.-W.,Lutz, C. P.,Heinrich, A. J.,Epstein, A. J.,Stroud, D. G.,Gupta, J. A. American Chemical Society 2014 NANO LETTERS Vol.14 No.3

<P>The magnetic properties of molecular structures can be tailored by chemical synthesis or bottom-up assembly at the atomic scale. We used scanning tunneling microscopy to study charge and spin transfer in individual complexes of transition metals with the charge acceptor, tetracyanoethylene (TCNE). The complexes were formed on a thin insulator, Cu<SUB>2</SUB>N on Cu(100), by manipulation of individual atoms and molecules. The Cu<SUB>2</SUB>N layer decouples the complexes from Cu electron density, enabling direct imaging of the TCNE molecular orbitals as well as spin-flip inelastic electron tunneling spectroscopy. Results were obtained at low temperature down to 1 K and in magnetic fields up to 7 T in order to resolve splitting of spin states in the complexes. We also performed spin-polarized density functional theory calculations to compare with the experimental data. Our results indicate that charge transfer to TCNE leads to a change in spin magnitude, Kondo resonance, and magnetic anisotropy for the metal atoms.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/nalefd/2014/nalefd.2014.14.issue-3/nl404054v/production/images/medium/nl-2013-04054v_0007.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/nl404054v'>ACS Electronic Supporting Info</A></P>

멸구類(벼멸구 및 흰등멸구)와 水稻病害의 複合發生 被害에 關한 硏究

S.C. LEE,D.M. MATIAS,T.W. MEW,J.S. SORINO,E.A. HEINRICHS 한국응용곤충학회 1985 한국응용곤충학회지 Vol.24 No.2

수도(水稻) 병해충(病害蟲)의 동시발생(同時發生) 피해(被害)에 관한 연구(硏究)를 위한 기초시험(基礎試驗)으로 벼멸구와 흰등멸구의 복합발생(複合發生)에 따른 서식처선호성(棲息處選好性)을 확인(確認)코저 감수성(感受性) 품종(品種)인 IR22와 저항성(抵抗性)인 IR36(분벽최성기(分蘗最盛期)부터 흰등멸구에도 저항성(抵抗性)임)을 공시(供試)하여 조사(調査)한 결과(結果) 벼품종별(品種別), 생육시기별(生育時期別) 및 발생밀도(發生密度)에 따라 다소(多少) 차이(差異)는 있으나 일반적(一般的)으로 흰등멸구는 대부분(大部分) 벼 윗부분(部分)에 서식(棲息)하였고 벼멸구는 아래부분(部分)에 서식(棲息)함을 알 수 있었다. 두 종(種)의 복합발생시(複合發生時)의 서식선호성(棲息選好性)은 상대종(相對種)의 발생(發生)에 영향(影響)을 받지 않았고 각각 일정(一定)한 서식처(棲息處)를 선호(選好)하는 경향(傾向)이었다. 벼멸구의 생태형(生態型) 2에 대(對)하여 반응(反應)이 다른 다섯가지 품종(品種)(IR22 및 TN1: 감수성(感受性), Triveni 및 ASD7: 중정도저항성(中程度抵抗性), IR42: 抵抗性)을 공시(供試)하여 문고병(紋枯病)과 벼멸구의 동시발생(同時發生)에 의한 피해(被害)를 조사(調査)한 결과(結果) 병해충(病害蟲)의 동시발생(同時發生) 피해(被害)는 병원균(病原菌)이 단독발생(單獨發生)했을 때 보다 문고병(紋枯病)의 발병(發病)을 현저(顯著)히 조장(助長)시켰으며 병증(病症)의 발현속도(發現速度)도 빨랐고 균계생장(菌系生長)도 왕성(旺盛)하여 감염기(感染器)(infection structure)의 형성(形成)도 풍부(豊富)하였다. 벼멸구의 생태형(生態型) 2에 대(對)한 품종(品種) 반응(反應)과는 상관없이 벼멸구와 문고병(紋枯病)과의 동시발생(同時發生)은 벼멸구 단독발생(單獨發生)에 비(比)하여 더 심한 고사현상(枯死現象)(hopperburn)을 일으켰다. 즉 문고병(紋枯病) 병원균(病原菌)과 벼멸구의 동시발생(同時發生)은 상승적(相乘的) 피해(被害)가 나타남을 확인(確認)하였다. The locational preference of the brown planthopper (BPH) Nilaparvata lugens () and the whitebacked plant hopper (WBPH) Sogatella furcifera(Horvath) was studied on rice cultivars IR22 and IR36 as an integral part of subsequent research on insect-fungal pathogen relationships. The BPH was observed to stay consistently on the basal portion while the WBPH showed a general preference for the upper portion regardless of varieties, rice growth stages and insect population density levels. The habitat preference of both species (BPH and WBPH) was found not to be affected by the presence of the other species when both species are present on the same host plant Five rice cultivars with different reactions to BPH biotype 2 were used in the study on BPH-Rhizoctonia solani relationship: IR22 and TN1 (susceptible), Triveni and ASD7 (moderately resistant), and IR42 (resistant). Test plants were inoculated with R. solani (Kuhn) days after insect infestation. Sheath blight disease severity/incidence was significantly higher in the treatment where BPH+R. solani were together than in the treatment with only the pathogen. Symptom expression of the disease in the BPH-pathogen combination was faster and mycelial growth was more profuse inducing the formation of more infection structures. Regardless of varietal reaction to BPH biotype 2, the degree of hopperburn was significantly higher in the combination of the two pests as compared with that of BPH alone. There could be a synergistic relationship between the insect pest and the pathogen indicated by a positive interaction between the two species.

Photophysical, amplified spontaneous emission and charge transport properties of oligofluorene derivatives in thin films

Choi, E. Y.,Mazur, L.,Mager, L.,Gwon, M.,Pitrat, D.,Mulatier, J. C.,Monnereau, C.,Fort, A.,Attias, A. J.,Dorkenoo, K.,Kwon, J. E.,Xiao, Y.,Matczyszyn, K.,Samoc, M.,Kim, D.-W.,Nakao, A.,Heinrich, B.,Ha The Royal Society of Chemistry 2014 Physical chemistry chemical physics Vol.16 No.32

<P>We investigate the photophysical and amplified spontaneous emission properties of a series of monodisperse solution-processable oligofluorenes functionalized with hexyl chains at the C9 position of each fluorene unit. Thin films of these oligofluorenes are then used in organic field-effect transistors and their charge transport properties are examined. We have particularly focused our attention on the influence of oligofluorene length on the absorption and steady-state fluorescence spectra, on the HOMO/LUMO energy levels, on the photoluminescence lifetime and quantum yield as well as on the amplified spontaneous emission properties and the charge carrier mobilities. Differential scanning calorimetry and X-ray diffraction measurements demonstrate that, among all oligofluorene derivatives used in this study, only the structure and morphology of the pentafluorene film is significantly modified by a thermal treatment above the glass transition temperature, resulting in a 9 nm blue-shift of the fluorescence spectrum without significant changes in the photoluminescence quantum yield and in the amplified spontaneous emission threshold. In parallel, hole field-effect mobility is significantly increased from 8.6 × 10<SUP>−7</SUP> to 3.8 × 10<SUP>−5</SUP> cm<SUP>2</SUP> V<SUP>−1</SUP> s<SUP>−1</SUP> upon thermal treatment, due to an increase of crystallinity. This study provides useful insights into the morphological control of oligofluorene thin films and how it affects their photophysical and charge transport properties. Moreover, we provide evidence that, because of the low threshold, the tunability of the amplified spontaneous emission and the photostability of the films, these oligofluorenes are promising candidates for organic solid-state laser applications.</P> <P>Graphic Abstract</P><P>We investigate the charge transport, photophysical and amplified spontaneous emission properties of a series of monodisperse solution-processable oligofluorenes functionalized with hexyl chains at the C9 position of each fluorene unit. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4cp01134a'> </P>

The perceptual homunculus: The perception of the relative proportions of the human body.

Linkenauger, Sally A.,Wong, Hong Yu,Geuss, Michael,Stefanucci, Jeanine K.,McCulloch, Kathleen C.,Bü,lthoff, Heinrich H.,Mohler, Betty J.,Proffitt, Dennis R. American Psychological Association 2015 Journal of experimental psychology: general Vol.144 No.1

病害虫과 變色米 發生과의 關係에 관한 硏究

LEE S.C.,M.E. ALVENDA,J.M. BONMAN,E.A. HEINRICHS 한국응용곤충학회 1986 한국응용곤충학회지 Vol.25 No.2

변색미(變色米) 발생(發生)에 관여(關與)하는 병원균(病原菌)과 해충을 분류동정(分類同定)한 결과(結果) 해충으로는 허리노린재과(科)에 속하는 Leptocorisa oratorius가 우점종(優占種)이었고 노린재과(科)인 Menida varipennis. Stollia ventralis 및 Nezara viridula 등이 관여(關與)하였으며 병원균(病原菌)으로는 Drechslera oryzae. Curvularia lunata, Trichoniella padwickii, Sarocladium oryzae, Alternaria tenuis 및 Fusarium solani 등이 관여(關與)하였다. 병원균(病原菌)과 해충의 복합발생시(複合發生時)에 변색미발생(變色米發生)이 더 심하였고 병원균(病原菌)만의 발생시(發生時)는 변색미(變色米) 발생(發生)에 주로 영향(影響)을 미쳤으며 노린재류만의 발생시(發生時)는 수량감수(收量減收)에 더 큰 영향(影響)을 주었다. 그리고 노린재류에 의한 벼 유숙기간(乳熟期間)의 흡즙(吸汁)은 병원균침입(病原菌侵入)을 조장(助長)하여 벼의 질적(質的) 변화(變化)와 양적(量的) 감소(滅少)에 크게 영향(影響)하였다. Species of pathogens and insects associated with grain discoloration in the Philippines were indentified. Leptocorisa oratorios was the most dominant insect species causing discoloration. Pathogenicity tests of fungal organisms isolated from discolored grains showed that Drechslera oryzae, Curvularia lunata, Trichoconiella padwickii, Sarocladium oryzae, Alternaria tenuis, and Fusarium solani were the common pathogens responsible for 'dirty panicle' disease of rice. Discoloration incidence was higher on treatment when both pests were present than when they occurred singly. The discoloration severity was attributed to the pathogens whereas rice bug caused a high decrease in grain weight and unfilled grains. Rice bug feeding on grains enhances the infection caused by the pathogen. Due to this, the quantity and quality of grains produced were affected, resulting in yield reduction.