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암모니아 가스 중화에 의한 폐산내 Mo 회수에 관한 연구
차우열,태순재,유진태,박융호,박종진 한국자원리싸이클링학회 2003 資源 리싸이클링 Vol.12 No.2
전구용 필라멘트 제조 공정에서 발생되는 Mo함유 폐산 내에 암모니아 가스를 취입하여 유가금속인 Mo를 암모늄테트라몰리브데이트($_3$.2NH$4MoO_3$.$H_2$O) 형태로 침전 회수하고, 여과 후 발생되는 중화 여액을 활용하기 위한 연구를 수행하였다. 암모니아 중화법을 이용한 Mo 회수공정에 있어 다양한 공정 변수들에 의한 제품의 회수율, 순도, 입도 등 특성을 평가하였으며, 그 결과로부터 Mo 염의 회수율 99.5% 이상, 순도 99.5% 이상을 확보하기 위한 최적 조업조건을 도출하였다. Bench 및 Pilot규모의 실험을 통하여 상업화 가능성을 확인하였으며, 폐산의 중화반응 후 발생된 여액은 엽면시비용 액상 복합비료의 원료로 사용 가능함을 확인하였다. The present work relates to the recovery of dissolved Mo from spent mandrel dissolving acid solution by injecting ammonia gas. In order to optimize the process parameters for high yield and high purity of recovered Mo products, a bench scale and a pilot scale experiments were carried out. As a result, more than 99.5% of Mo in spent acid was recovered in the form of ammonium molybdate(4MoO$_3$.$2NH_3$.$H_2$O). The purity of Mo products recovered was higher than 99.5%. In addition, the mother liquor, residual solution after precipitation and filtration of ammonium molybdate solid particles, could be utilized as fertilizers.
복합산화물이 형성된 API X80 라인파이프강의 용접열영향부 샤르피 흡수에너지
성효경 ( Hyo Kyung Sung ),신상용 ( Sang Yong Shin ),차우열 ( Woo Yeol Cha ),오경식 ( Kyung Shik Oh ),이성학 ( Sung Hak Lee ),김낙준 ( Nack J. Kim ) 대한금속재료학회 ( 구 대한금속학회 ) 2010 대한금속·재료학회지 Vol.48 No.10
This study assessed the Charpy impact properties of the heat-affected zones (HAZs) of API X80 linepipe steels containing complex oxides. Three types of steel were fabricated by adding Mg and O2 to form complex oxides and their microstructures and Charpy impact properties were investigated. The number of complex oxides increased with the amount of excess Mg and O2 that was included in the steels. Simulated HAZs containing a number of oxides showed a high volume fraction of acicular ferrite (AF) because the oxides acted as nucleation sites for AF, thereby leading to an improvement in the Charpy impact properties. According to a correlation study between the heat input, the volume fraction of the AF, and the Charpy impact properties, ductile fractures occurred predominantly when the fraction of the AF was 20% or higher; moreover, the Charpy absorbed energy was excellent at more than 100 J. These findings suggest that the improvement of the Charpy impact properties of the HAZs was associated with the active nucleation of AF in the oxide-containing steel HAZs.