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Agglomerated film model 을 이용한 용융탄산염 연료전지용 perovskite 음극의 성능예측
임준혁,이병선,정하철,김윤성,위정호,전해수 ( Jun Heok Lim,Byung Sun Lee,Ha Chull Chung,Yun Sung Kim,Jung Ho Wee,Hai Soo Chun ) 한국공업화학회 1997 응용화학 Vol.1 No.1
A dual-porosity filmed agglomerate model for the porous cathode of the molten carbonate fuel has been investigated to predict the perovskite type cathode performance. The model predicts steady-state cell performance, given the above conditions that characterize the state of the perovskite electrode. Also, the effective surface area of electrode pore was obtained by mercury porosimeter. The results of the investigation are presented in the form of plots of overpotential vs. current density with varied the electrode material, gas composition and mechanism. The predicted polarization curves are compared with the empirical data from 1 ㎠ cell.