나림광산 수계의 토양과 퇴적물에 관한 지구화학적 특성: 중금속 원소의 분산, 부화 및 기원

이찬희,이현구,이종창,Lee, Chan Hee,Lee, Hyun Koo,Lee, Jong Chang 대한자원환경지질학회 1998 자원환경지질 Vol.31 No.4

Geochemical characteristics of environmental toxic elements at the Narim mine area were investigated on the basis of major, minor, rare earth element geochemistry and mineralogy. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in soils and sediments range from 11.57 to 22.21 and from 1.86 to 3.93, and are partly negative and positive correlation against $SiO_2/Al_2O_3$ (3.41 to 4.78), respectively. These suggested that sediment source of host granitic gneiss could be due to rocks of high grade metamorphism originated by sedimentary rocks. Characteristics of some trace and rare earth elements of V/Ni (0.33 to 1.95), Ni/Co (2.00 to 6.50), Zr/Hf (11.27 to 53.10), La/Ce (0.44 to 0.55), Th/Yb (4.07 to 7.14), La/Th (2.35 to 3.93), $La_N/Yb_N$ (6.58 to 13.67), Co/Th (0.63 to 2.68), La/Sc (3.29 to 5.94) and Sc/Th (0.49 to 1.00) are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. Major elements in all samples are enriched $Al_2O_3$, MgO, $TiO_2$ and LOI, especially $Fe_2O_3$ (mean=7.36 wt.%) in sediments than the composition of host granitic gneiss. The average enrichment indices of major and rare earth elements from the mining drainage are 2.05 and 2.91 of the sediments and are 2.02 and 2.60 of the soils, normalizing by composition of host granitic gneiss, respectively. Average composition (ppm) of minor and/or environmental toxic elements in sediments and soils are Ag=14 and 1, As=199 and 14, Cd=22 and 1, Cu=215 and 42, Pb=1770 and 65, Sb=18 and 3, Zn=3333 and 170, respectively, and extremely high concentrations are found in the subsurface sediments near the ore dump. Environmental toxic elements were strongly enriched in all samples, especially As, Cd, Cu, Pb, Sb and Zn. The level of enrichment was very severe in mining drainage sediments, while it was not so great in the soils. Based on the EPA value, enrichment index of toxic elements is 8.63 of mining drainage sediments and 0.54 of soils on the mining drainage. Mineral composition of soils and sediments near the mining area were partly variable being composed of quartz, mica, feldspar, amphibole, chlorite and clay minerals. From the gravity separated mineralogy, soils and sediments are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various hydroxide minerals.

남동 - 황해 대륙붕의 준표층 니질퇴적물에서 산출되는 그레자이트

이찬희,진재화,장세원,이성록,이치원 ( Chan Hee Lee,Jae Hwa Jin,Se Won Chang,Sung Rock Lee,Chi Won Lee ) 한국광물학회 1995 광물과 암석 (J.Miner.Soc.Korea) Vol.8 No.1

Geochemical Variation of Authigenic Glauconite from Continental Shelf of the Yellow Sea, off the SW Korea

이찬희,이성록,이치원,최석원,Lee, Chan Hee,Lee, Sung-Rock,Lee, Chi-Won,Choi, Suck-Won The Korean Society of Economic and Environmental G 1997 자원환경지질 Vol.30 No.4

황해 대륙붕의 준고화된 표층퇴적물에서 자생하는 해록석들을 산출상태와 외부조직에 따라 괴상형, 균열형 및 다공질형으로 분류하였다. 이 해록석은 현세의 해침에 의하여 퇴적된 표층의 사질퇴적물내에 산포상으로 산출되며, 보통 0.1~1 mm 크기의 직경을 갖는다. x-선 회절분석 결과로 계산된, 해록석의 단위포와 크기는 $a=5.242{\AA}$, $b=9.059{\AA}$, $c=10.163{\AA}$, ${\beta}=100.5^{\circ}$, $V=474.53{\AA}^3$ 이고, 화학조성과 단위포의 크기로 계산된 밀도는 $2.60{\pm}0.45gm/cc$ 이다. 이 광물은 가열실험시 $10{\AA}$의 회절선이 증가하는 것으로 볼때 일정한 팽윤층을 갖는 것으로 보인다. $O_{10}(OH)_2$를 기준으로 평균조성을 구하면, 팔면체 자리의 Fe 함량은 1.19~2.06 이고, Al 함량은 0.18~0.76 이다. Fe와 Al은 서로 치환관계를 보이며 다공질형에서 괴상형으로 갈수록 Fe의 함량은 증가하고 Al은 감소한다. Mg의 함량은 0.35~0.54로서 Al이 높을수록 Mg의 양도 증가한다. K의 함량은 0.34~0.71의 범위를 보이며 다공질형에서 괴상형으로 갈수록 증가한다. 괴상형 또는 균열형 해록석은 질서/무질서의 혼합층 운모이며, 다공질형의 해록석은 혼합층 일라이트/스멕타이트로서 7~27%의 팽윤층을 포함한다. 이 광물은 표층 퇴적물이 퇴적된후에 극미립의 퇴적입자를 핵으로, 환원환경하에서 발생하는 퇴적물의 분해 및 생물체 파편과의 반응에 따라 자생한 것으로 추정된다. The massive, fractured and porous-type of glauconite, which is subdivided by surface morphology, occur in subtidal sand and semiconsolidated intertidal sand/mud from continental shelf of the southeastern Yellow Sea. This area is presumed to be a part of Holocene transgressive tidal systems tract. The glauconite, pellet-like grains with diameter of 0.1 to 1 mm, is scattered in surface sand sediments. Results of X-ray diffraction data of the minerals are monoclinic with $a=5.242{\AA}$, $b=9.059{\AA}$, $c=10.163{\AA}$, ${\beta}=100.5^{\circ}$, $V=474.53{\AA}^3$. Thermal treatments on the oriented glauconite increase the X-ray diffraction intensity near $10{\AA}$ (001), suggesting the presence of some expandable layers. Specific gravity of the glauconite is $2.60{\pm}0.45gm/cc$ on the basis of chemical composition and unit-cell dimensions. Based on $O_{10}(OH)_2$, chemical composition of glauconites, octahedral Fe content ranges from 1.19 to 2.06 atoms, corresponding octahedral AI is 0.18 to 0.76 atoms, which progressively substitute Fe for AI with increasing from porous to massive-type. The Mg content ranges from 0.35 to 0.54 atoms, and shows higher with increasing Al contents. A systematic increase of interlayer K from 0.34 to 0.71 is also observed with apparent increases from porous to massive-type, and related to a proportion of expandable layers. The clay preserved in glauconite, which is recognized as ordered/disordered (massive to fractured-type). The interstratified illite/smectite (porous-type), contains 7 to 27 % expandable layers. The glauconite seems to originate from post depositional authigenic growth in reducing environments promoted by the dissolution of clay minerals and biogenic debris.

구조방정식모형을 이용한 개인연금 가입의향의 결정요인 분석

이찬희,정홍주,Lee, Chanhee,Jung, Hongjoo 한국통계학회 2016 응용통계연구 Vol.29 No.3

본 연구는 노후대비를 위한 재무수단 중에서 중요성이 커지고 있는 개인연금의 가입의향에 영향을 주는 심리요인과 금융요인 간의 인과관계를 종합적으로분석하고자 하였다. 이를 위해 전국 7대도시에 거주하는 928명의 일반인을 대상으로 실시한 설문자료를 토대로 구조방정식모형(SEM)을 이용하여 실증분석하였다. 구조방정식에 의한 실증분석결과, 개인연금 미가입자의 신규가입의향에 있어 장수에 대한 가능성과 대처효용성은 장수에 대한 정서인 두려움과 걱정을 완전매개로 하여 개인연금의 신규가입의향에 영향을 주는 것으로 나타났다. 그리고 보험사 신뢰와 위험감수성향은 직접적으로 개인연금의 신규가입의향에 영향을 주며, 특히 개인연금 가입의향에 대하여 보험사 신뢰가 가장 중요한 요인임을 보여주었다. 또한 개인연금 기가입자의 추가가입의향에 있어서는 보험사 신뢰만이 개인연금 추가가입의향에 직접적으로 영향을 주는 것으로 나타났다. 본 연구를 통하여 장수 관련 정서적 측면이 개인연금 미가입 고객을 대상으로 한 마케팅 활동에 도움이 될 것으로 기대된다. 아울러 보험사 신뢰가 미래의 개인연금 신규가입뿐만 아니라 추가가입의향에 가장 큰 영향을 미치므로 보험사의 신뢰도를 높이기 위한 노력이 긴요함을 시사한다. This study analyzed the causal relationship among factors that influence the purchase intensions for individual pensions which have a growing importance as a financial means after retirement. For this purpose, structural equation modeling based on the survey data (N = 928) was conducted to analyze psychological factors and financial factors comprehensively. According to empirical results of the structural equation, in the case of non-subscribers of individual pensions, potential longevity and coping efficacy influenced the purchase intensions for individual pensions fully mediated by fear and worry about longevity. Trust in insurers and risk tolerance directly influenced the purchase intensions for individual pensions. These show that trust in insurers is the most important factor in purchase intensions for individual pensions. Also, only trust in insurers give a direct impact on individual pensions in the case of individual pension subscribers. Longevity-related emotional side is expected to help in marketing activities that target potential customers signing individual pensions. In addition, trust in insurers has the greatest impact on new and additional subscriptions that represent critical efforts to improve trust in insurers.

탄산염암 층준교대형 백전광상의 천열수 금-은 광화작용과 생성환경

이찬희,박희인,Lee, Chan Hee,Park, Hee-In 대한자원환경지질학회 1996 자원환경지질 Vol.29 No.2

The Baegjeon Au-Ag and Sb deposits, small of disseminated-type gold deposits are formed as a result of epithermal processes associated a shallow-seated Cretaceous Yeogdun granitoids intrusion. The orebodies are formed by the replacement of carbonate minerals in thin-bedded oolitic limestone beds favorable for mineralization within the upper-most Cambrian Pungchon Limestone Formation. The mineralization can be recognized one stage, ore minerals composed of base metal sulfides, electrum, AgSb-S, Ag-Cu-S, and Sb-S minerals. Gold-bearing minerals consist of electrum and submicroscopic invisible gold in pyrite and arsenopyrite. The composition of electrums ranges from 33.58 to 63.48 atomic % Ag. Fluid inclusion studies reveal that ore fluids were low saline $NaCl-CO_2-H_2O$ system. Temporary fluid mixing and boiling occured in later stage. Fluid inclusion data indicates the homogenization temperatures and salinities of NaCl eqivalent wt% were 176 to $246^{\circ}C$ and from 0.0 to 4.8 wt%, respectively. And $-logfs_2$, of mineralization obtained by thermodynamic considerations as 12.4 to 13.8 atm. The ${\delta}^{34}S_{H_2S}$, values of hydrothermal sulfides were calculated to be 6.8 to 10.2‰ which was of sedimentary origin. The ${\delta}^{18}O_{H_2O}$ and ${\delta}^{13}C_{CO_2}$, range from -3.9 to 9.6‰, from -1.1 to -2.2‰, and ${\delta}D$ range from -89 to -118‰, respectively. The Au deposition during mineralization seems to have occurred as a result of decrease of temperature, $fs_2$, $fo_2$, and pH probably due to oxidation by meteoric water mixing, which destabilized original $Au(HS)^-{_2}$. The mineralization of the Baegjeon deposits is similar to the Carlin-type deposits characterized by sediments-hosted epithermal bedding replacement disseminated gold deposits.

충남탄전, 대동누층군의 셰일과 탄질암에 관한 암석화학 및 환경지구화학적 특성

이찬희,이현구,김경웅,Lee, Chan Hee,Lee, Hyun Koo,Kim, Kyoung-Woong 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.5

Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

하수도 업무추진체계 개선

이찬희,Lee, Chan-Hui 한국상하수도협회 1997 水道 Vol.24 No.5

This year the Ministry of Environment(MOE) made a fifth amendment to the Sewerage Act, which was enacted in August 1966. The first objective of this amendment is to introduce small public sewerage system that is designed to treat wastewater produced in rural areas. Before small public sewerage system was introduced to the Act through this amendment, only urban areas were covered by public sewerage system. Because small sewerage system was introduced, wastewater generated in urban areas as well as rural areas can now be treated by public sewage treatment plants. In addition to this, some authorities on sewerage affairs were moved from the MOE to local governments by this amendment in order to enhance the power and responsibility of local governments in relation to sewerage affairs. Also, this amendment enabled local governments to entrust the authority to establish and manage sewage treatment plants to private companies, and enabled the MOE to organize an advisory committee on sewerage to review economic and technical aspects ofsewage treatment plants. This amendment went into effect September 8, 1997.

'97 상하수도 정책 방향

이찬희,Lee, Chan-Hui 한국상하수도협회 1997 水道 Vol.24 No.1

덕평지역(德平地域)의 옥천누층군(沃川累層群)에 분포(分布)하는 변성이질암(變成泥質岩)과 바륨-바나듐 백운모(白雲母)의 지구화학적(地球化學的) 및 광물학적(鑛物學的) 특성(特性)

이찬희,이현구,Lee, Chan Hee,Lee, Hyun Koo 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.1

The coal formation of the Deokpyeong area are interbedded along metapelites of the Ogcheon Supergroup, which are composed mainly of graphite, quartz, muscovite and associated with small amounts of biotite, chlorite, pyrite and barite. The ratios of $SiO_2/Al_2O_3$, $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ of the coaly metapelite are variable and wide range from 1.80 to 10.21, from 27.8 to 388.8 and from 7.6 to 61.8, respectively. These coal formation were deposited in basin of marine environments, and the REE of these rocks are not influenced with metamorphism and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, the ratios of La/Ce (0.19 to 0.99) and Th/U (0.02 to 4.75). These rocks also show much variation in $La_N/Yb_N$ (1.19 to 22.89), Th/Yb (0.14 to 21.43) and La/Th (0.44 to 13.67), and their origin is explained by derivation from a mixture of sedimentary and igneous rocks. The wide range in trace and REE element characteristics as Co/Th (0.12 to 2.78), La/Sc (0.33 to 10.18), Sc/Th (0.57 to 5.73), V/Ni (8 to 2347), Cr/V (0.02 to 0.67) and Ni/Co (1.56 to 32.95) of these coaly metapelites argues for inefficient mixing of the various source lithologies during sedimentation. Deep to pale green barium-vanadium muscovites (vanadium-oellacherite) have been found in this coal formations. Modes of occurrence and grain size of muscovite are heterogeneous, but most of the barium and vanadium-bearing muscovites occur along the boundaries between graphite and quartz grains, ranging from 200 to $350{\mu}m$ in length and from 40 to $60{\mu}m$ in width. Results of X-ray diffraction data of the minerals characterized to be monoclinic system with $a=5.249{\AA}$, $b=8.939{\AA}$, $c=20.924{\AA}$ and ${\beta}=95.894^{\circ}$. Representative chemical formula of the muscovite was $(Na_{0.09}K_{1.44}Ba_{0.46})(Al_{2.75}Ti_{0.07}V_{0.56}Fe_{0.08}Mg_{0.50})(Si_{6.12}Al_{1.88})O_{22}$. The V possibly substitute octahedral Al, and the Ba is coupled substitution of $K^+Si^{4+}=Ba^{2+}Na^+Ca^{2+}$, which compositional ranges of V and Ba are from 0.42 to 0.69 and from 0.34 to 0.56 based on $O_{22}$, respectively. Formation mechanism of the barium-vanadium muscovites in the coaly metapelite is shown that the formed by high pressure and temperature from regional metamorphism origanated during diagenesis at the interface between a basinal brine and organic matter.

개선된 SOG 기반 고속 세선화 알고리즘($SOG^*$)

이찬희,정순호,Lee, Chan-Hui,Jeong, Sun-Ho 한국정보처리학회 2001 정보처리학회논문지B Vol.8 No.6

본 논문은 기존의 신경망을 이용한 세선화 방법 중에서 자기 구성 그래프(Self-Organized Graph:SOG) 세선화 기법의 우수한 세선화 결과를 유지하면서, 수행 속도를 향상시키기 위하여 Kohonen Features Map의 새로운 점증 기법을 변형된 SOG에 적용한 개선된 SOG(Improved SOG:$SOG^*$) 세선화 기법을 제안한다. 실험 결과로써 숫자와 문자 모두 기존의 SOG와 같은 우수한 세선화 결과를 나타내며, O((logM)3)의 시간 복잡도를 가지는 속도 향상을 이루었다. 따라서 본 논문에서 제안한 방법은 숫자 또는 문자 인식에 있어 특징 추출의 빠른 전처리 과정으로 사용할 수 있다. In this paper, we propose Improved Self-Organized Graph(Improved SOG:$SOG^*$)thinning method, which maintains the excellent thinning results of Self-organized graph(SOG) built from Self-Organizing features map and improves the performance of modified SOG using a new incremental learning method of Kohonen features map. In the experiments, this method shows the thinning results equal to those of SOG and the time complexity O((logM)3) superior to it. Therefore, the proposed method is useful for the feature extraction from digits and characters in the preprocessing step.