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李永俊,李根鎬,金熙東,李元宰,姜道烈 弘益大學校 1988 弘大論叢 Vol.20 No.2
In this paper, Thermally stimulated current(TSC) spectrum was mearsured as a function of formation temperature, formation time, formation voltage and heating rate in a biaxially oriented polypropylene film of thickness 40[μm], which is better than polyethylene in the enduring characteristic against heat and dielectric characteristic, the variation of the TSC was observed by ozone oxidation. This measurment has been carried out in the temperature range from-40[℃] to 140[℃]. As results of the measurment, A,B,C,D peaks was made at 0[℃], 40[℃], 80[℃], 120[℃], respectively. B peak was made at the near second glass transition temperature is estimated the dipole polarization by microbrown motion, C peak is estimated to the polarization of ionic space charge. And, In according to the increase of oxidation time by ozone, B peak increased slowly and C peak increased rapidly after it increased slowly during first oxidation time of 15[Hr]. By initial rising method, activation energies of B,C peaks were calculated to about 0.57, 0.84eV, respectively. The hopping distance and mobility of C peak for pure specimen and ozone oxidated specimen 54A, 71A and 1.099×10??cm²/υ·s, 8. 55×10??cm²/υ·s, respectively.