Enhanced proton conductivity of sulfonated poly(ether ether ketone) membranes at elevated temperature by incorporating (3-aminopropyl)triethoxysilane-grafted graphene oxide

Shuguo Qu,Chenchen Zhang,Minhui Li,Yan Zhang,Lunbo Chen,Yushuai Yang,Bo Kang,Yiwei Wang,Jihai Duan,Weiwen Wang 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.12

Making inexpensive proton exchange membrane with high proton conductivity for the proton exchange membrane fuel cell (PEMFC) is still a challenging problem. Graphene oxide (GO) nanoparticles grafted with (3-aminopropyl) triethoxy silane (APTES) were prepared and then incorporated into sulfonated poly(ether ether ketone) (SPEEK) matrix by solution casting to make the composite proton exchange membrane. The obtained nanoparticles and composite membranes were characterized by XRD, FT-IR, Raman, TGA, SEM, and UTM. GO treated with the silane coupling agent improved the dispersion stability and compatibility of GO in SPEEK, which decreased the agglomeration of GO nanoparticles in the SPEEK membrane. The prepared nanocomposite membranes exhibited better water retention properties and proton conductivity. The proton conductivity of the SPEEK membrane with 2wt% amine functionalized GO (AGO) reached 11.32mS/cm at 120oC, which was 2.45-times higher than that of the pristine SPEEK membrane. The reason was that AGO nanoparticles disperse uniformly in the SPEEK membranes, which provides new channels for proton transfer. The potential application of this composite membrane in the PEMFC was indicated.

The enhancement of humidity sensing performance based on Eu-doped ZnO

Shuguo Yu,Hongyan Zhang,Cunchong Lin,Mingjin Bian 한국물리학회 2019 Current Applied Physics Vol.19 No.2

In this work, a high performance impedance-type humidity sensor based on Europium-doped ZnO with abundant surface oxygen vacancy defects was synthesized by sol-gel method. Response of the Eu-doped ZnO with different molar ratio were investigated by exposing them to humidity environments in wide range of 11–95% RH at room temperature. The Eu-doped ZnO (2 mol%) exhibits a three orders impedance change, along with short response/ recovery time (5 s/19 s), low hysteresis and best linearity. Complex impedance spectra indicates that dopant Eu can enhance humidity sensing performance of ZnO, which is resulted from the introduction of Eu3+ ions into ZnO structure to produce more defects of surface oxygen vacancy and more active sites on the surface of ZnO. The results show that this is a feasible method to achieve high humidity sensing performance by Eu doped ZnO, which make it a promising candidate for humidity sensing materials and broaden the use of ZnO materials.

Analysis of three dimensional equivalent static wind loads of symmetric high-rise buildings based on wind tunnel tests

Shuguo Liang,Lianghao Zou,Dahai Wang,Guoqing Huang 한국풍공학회 2014 Wind and Structures, An International Journal (WAS Vol.19 No.5

Using synchronous surface pressures from the wind tunnel test, the three dimensional wind load models of high-rise buildings are established. Furthermore, the internal force responses of symmetric high-rise buildings in along-wind, across-wind and torsional directions are evaluated based on mode acceleration method, which expresses the restoring force as the summation of quasi-static force and inertia force components. Accordingly the calculation methods of equivalent static wind loads, in which the contributions of the higher modes can be considered, of symmetric high-rise buildings in along-wind, across-wind and torsional directions are deduced based on internal forces equivalence. Finally the equivalent static wind loads of an actual symmetric high-rise building are obtained by this method, and compared with the along-wind equivalent static wind loads obtained by China National Standard.

Computational fluid dynamics study on the anode feed solid polymer electrolyte water electrolysis

Shuguo Qu,Guanghui Chen,Jihai Duan,Weiwen Wang,Jianlong Li 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.6

A steady-state two-dimensional model for the anode feed solid polymer electrolyte water electrolysis (SPEWE) is proposed in this paper. Finite element procedure was employed to calculate the multicomponent transfer model coupled with fluid flow in flow channels and gas diffusion layers and electrochemical kinetics in catalyst reactive surface. The performance of the anode feed SPEWE predicted by this model was compared with the published experimental results and reasonable agreement was reached. The results show that oxygen mass fraction increases because of the water oxidation when water flows from the import to the export on the anode side. On the cathode side, hydrogen mass fraction varies little since hydrogen and water mix well. The flux of water across the electrolyte increased almost linearly with the increase of the applied current density. Since the ohmic overpotential loss increasing as the solid polymer electrolytes’ thickness increasing, the performance of the anode feed SPEWE with Nafion 112, 115, 117 decreases at the same applied current density.

Analysis of three dimensional equivalent static wind loads of symmetric high-rise buildings based on wind tunnel tests

Liang, Shuguo,Zou, Lianghao,Wang, Dahai,Huang, Guoqing Techno-Press 2014 Wind and Structures, An International Journal (WAS Vol.19 No.5

Using synchronous surface pressures from the wind tunnel test, the three dimensional wind load models of high-rise buildings are established. Furthermore, the internal force responses of symmetric high-rise buildings in along-wind, across-wind and torsional directions are evaluated based on mode acceleration method, which expresses the restoring force as the summation of quasi-static force and inertia force components. Accordingly the calculation methods of equivalent static wind loads, in which the contributions of the higher modes can be considered, of symmetric high-rise buildings in along-wind, across-wind and torsional directions are deduced based on internal forces equivalence. Finally the equivalent static wind loads of an actual symmetric high-rise building are obtained by this method, and compared with the along-wind equivalent static wind loads obtained by China National Standard.

Control of 3-D coupled responses of wind-excited tall buildings by a spatially placed TLCD system

Liang, Shuguo,Li, Qiusheng,Qu, Weilian Techno-Press 2000 Wind and Structures, An International Journal (WAS Vol.3 No.3

The possible application of a spatially placed passive tuned liquid column damper system for suppressing coupled lateral-torsional responses of tall buildings is investigated in this paper. The wind loads acting on rectangular tall buildings are analytically expressed as 3-D stochastic model. Meanwhile, the 3-D responses of tall buildings may be coupled due to eccentricities between the stiffness and mass centers of the buildings. In these cases, torsional responses of the buildings are rather larger, and a TLCD system composed of several TLCD located near the sides of the buildings is more effective than the same TLCD placed at the building center in reducing both translational and torsional responses of the buildings. In this paper, extensive analytical and numerical work has been done to present the calculation method and optimize the parameters of such TLCD systems. The numerical examples show that the spatially placed TLCD system can reduce coupled along-wind, across-wind and torsional responses significantly with a fairly small mass ratio.

Simplified formulas for evaluation of across-wind dynamic responses of rectangular tall buildings

Liang, Shuguo,Li, Q.S.,Zou, Lianghao,Wu, J.R. Techno-Press 2005 Wind and Structures, An International Journal (WAS Vol.8 No.3

Tall buildings under wind action usually oscillate simultaneously in the along-wind and across-wind directions as well as in torsional modes. While several procedures have been developed for predicting wind-induced loads and responses in along-wind direction, accurate analytical methods for estimating across-wind and torsional response have not been possible yet. Simplified empirical formulas for estimation of the across-wind dynamic responses of rectangular tall buildings are presented in this paper. Unlike established empirical formulas in codifications, the formulas proposed in this paper are developed based on simultaneous pressure measurements from a series of tall building models with various side and aspect ratios in a boundary layer wind tunnel. Comparisons of the across-wind responses determined by the proposed formulas and the results obtained from the wind tunnel tests as well as those estimated by two well-known wind loading codes are made to examine the applicability and accuracy of the proposed simplified formulas. It is shown through the comparisons that the proposed simplified formulas can be served as an alternative and useful tool for the design and analysis of wind effects on rectangular tall buildings.

Analysis of vortex induced vibration frequency of super tall building based on wind tunnel tests of MDOF aero-elastic model

Lei Wang,Shuguo Liang,Jie Song,Shuliang Wang 한국풍공학회 2015 Wind and Structures, An International Journal (WAS Vol.21 No.5

To study the vibration frequency of super high-rise buildings in the process of vortex induced vibration (VIV), wind tunnel tests of multi-degree-of-freedom (MDOF) aero-elastic models were carried out to measure the vibration frequency of the system directly. The effects of structural damping, wind field category, mass density, reduced wind velocity (Vr), as well as VIV displacement on the VIV frequency were investigated systematically. It was found that the frequency drift phenomenon cannot be ignored when the building is very high and flexible. When Vr is less than 8, the drift magnitude of the frequency is typically positive. When Vr is close to the critical wind velocity of resonance, the frequency drift magnitude becomes negative and reaches a minimum at the critical wind velocity. When Vr is larger than12, the frequency drift magnitude almost maintains a stable value that is slightly smaller than the fundamental frequency of the aero-elastic model. Furthermore, the vibration frequency does not lock in the vortex shedding frequency completely, and it can even be significantly modified by the vortex shedding frequency when the reduced wind velocity is close to 10.5.

Investigation of 3-D dynamic wind loads on lattice towers

Lianghao Zou,Shuguo Liang,Q. S. Li,Lin Zhao,Yaojun Ge 한국풍공학회 2008 Wind and Structures, An International Journal (WAS Vol.11 No.4

In this paper, the along-wind, across-wind as well as torsional dynamic wind loads on three kinds of lattice tower models are investigated using the base balance technique in a boundary layer wind tunnel. The models were specially designed, and their fundamental frequencies in the directions of the three principal axes are still in the frequency range of the spectra of wind loads on lattice towers. In order to clear contaminations to the spectra of wind loads induced by model resonance, the generalized force spectra of the first mode of the models in along-wind, across-wind and torsional directions were derived based on measured base moments of the models. The RMS generalized force coefficients are also obtained by removing the contributions of model resonance. Finally, the characteristics of the 3-D dynamic wind loads, especially those of the across-wind dynamic loads, on the three kinds of lattice towers are presented and discussed.

Simplified formulas for evaluation of across-wind dynamic responses of rectangular tall buildings

Lianghao Zou,Shuguo Liang,Q. S. Li,J. R. Wu 한국풍공학회 2005 Wind and Structures, An International Journal (WAS Vol.8 No.3