콘크리트의 탄산화 관점에서 CO₂ 배출량-흡수량 평가에 관한 연구

이상현,이성복,이한승,Lee, Sang-Hyun,Lee, Sung-Bok,Lee, Han-Seung 한국콘크리트학회 2009 콘크리트학회논문집 Vol.21 No.1

콘크리트는 생산과정에서 다량의 이산화탄소를 배출하는 시멘트를 사용하기 때문에 반친환경적 재료로 인식되고 있다. 하지만 콘크리트는 사용기간 중 탄산화 과정을 통하여 대기중의 이산화탄소를 흡수한다. 이에 본 연구에서는 기존문헌 고찰을 통하여 1) 콘크리트 내 탄산화 가능한 물질의 농도, 2) 탄산화된 콘크리트의 체적, 3) 이산화탄소 분자량을 이용, 탄산화를 통한 콘크리트의 이산화탄소 흡수량의 정량적 산출 방법을 제시하였다. 또한 콘크리트 생산에 사용되는 재료들의 이산화탄소 배출량 자료를 이용하여 단위 콘크리트 생산에 따른 이산화탄소 배출량을 정량적으로 산출하였다. 이러한 콘크리트의 이산화탄소 흡수량 및 배출량의 정량적 산출방법을 이용하여 실제 사용중인 아파트 건축물 1동을 대상으로 하여 콘크리트의 생산에 따른 배출량과 사용기간에 따른 이산화탄소 흡수량을 정량적으로 산출하여 이산화탄소의 배출량-흡수량 평가를 실시하였다. 그 결과 건축물을 40, 60, 80년 사용시, 사용된 콘크리트의 이산화탄소 배출량 대 흡수량의 비율이 3.65, 4.47, 5.18%로 나타났다. 본 연구는 콘크리트 생산 및 사용에 따른 이산화탄소 배출량-흡수량의 정량적 산정방법에 연구의 목적을 두었으며 이산화탄소 배출량-흡수량 평가 결과 구조물을 80년 사용할 시 약 5.18%로 그 값이 미비하였으나 시멘트의 혼화재 치환율 증가를 통한 배출량 저감과 탄산화 체적 증가를 통한 이산화탄소 흡수량 증가를 통해 배출량-흡수량을 향상시킬 수 있으며, 향후 콘크리트의 이산화탄소 배출량-흡수량 평가에 본 연구의 방법이 유용하게 활용될 수 있을 것으로 판단된다. A concrete is considered unfriendly-environmental material because it uses cement which emits much $CO_2$ during producing process. However, a concrete absorbs $CO_2$ through carbonation process during service life. In this paper how much concrete absorbs $CO_2$ through carbonation was calculated using 1) concentration of carbonatable substances in concrete, 2) carbonated volume of concrete, 3) molecular weight of $CO_2$ based on references and the method was proposed. $CO_2$ emission from producing $1m^3$ concrete was calculated based on $CO_2$ emission datum of materials used in concrete. From using these methods that calculate $CO_2$ emission and absorption of concrete, assessment of $CO_2$ emission-absorption against a real apartment was conducted by subtracting absorption $CO_2$ according to service life from $CO_2$ emission in the process of making concrete. As a result, a ratio of absorption over emission of $CO_2$ through concrete carbonation according to service life 40, 60, 80 years was assessed about 3.65, 4.47, 5.18%. An objective of this study is to propose how to calculate emission - absorption of $CO_2$ from producing and using concrete. Although the result value, emission - absorption of $CO_2$, is 5.18% very low when the service life of an apartment is 80years, the value can be improved by reducing emission from using blended cement such as blast furnace slag or increasing replacement ratio of cement and increasing carbonated volume of concrete from expanding service life of a building. This study may be useful when $CO_2$ emission - absorption of concrete is evaluated in the further study.

반원형 리블렛 상부 난류경계층의 유동 구조 연구

이상현,이상준,Lee, Sang Hyun,Lee, Sang Joon 대한기계학회 1999 大韓機械學會論文集B Vol.23 No.7

The near-wall flow structures of turbulent boundary layer over riblets having semi-circular grooves were investigated experimentally for the drag decreasing ($s^+=25.2$) and drag increasing ($s^+=40.6$) cases. The field of view used for tho velocity field measurement was $6.75{\times}6.75mm^2$ in physical dimension, containing two grooves. One thousand instantaneous velocity fields over the riblets were extracted for each case of drag increase and decrease. For comparison, five hundreds instantaneous velocity fields over a smooth flat plate were also obtained under the same flow conditions. To see the global flow structure qualitatively, the flow visualization was also performed using the synchronized smoke-wire technique. For the drag decreasing case ($s^+=25.2$), most of the streamwise vortices stay above the riblets, interacting with the riblet tips. The high-speed in-rush flow toward the riblet surface rarely influences the flow inside tho riblet valleys submerged in the viscous sublayer. The riblet tips seem to impede the spanwise movement of the longitudinal vortices and induce secondary vortices. The turbulent kinetic energy in the riblet valley is sufficiently small to compensate the increased wetted area of the riblets. In addition, in the logarithmic region, the turbulent kinetic energy are small or almost equal to that of a smooth flat plato. For the drag increasing case ($s^+=40.6$), however, the streamwise vortices move into the riblet valley freely, interacting directly with the riblet inner surface. The penetration of the high-speed in-rush flow on the riblets increases tho skin-friction. The turbulent kinetic energy is increased in the riblet valleys and even in the outer region compared to that over a flat plate.

입력전류 파형 개선형 단상 정류기의 토폴로지

이상현(Sang-Hyun Lee),박진민(Jin-Min Park),문상필(Sang-Pil Mun),서기영(Ki-Young Suh) 한국조명·전기설비학회 2003 한국조명·전기설비학회 학술대회논문집 Vol.2003 No.-

For small capacity rectifier circuits such as these for consumer electronics and appliances, capacitor input type rectifier circuits are generally used. Consequently, various harmonics generated within the power system become a serious problem. Various studies of this effect have been presented previously. However, most of these employ switching devices, such as FETs and the like. The absence of switching devices makes systems more tolerant to over-load, and brings low radio noise benefits. We propose a power factor correction scheme using a LC resonant in commercial frequency without switching devices. In this method, it makes a sinusoidal wave by widening conduction period using the current resonance in commercial frequency, Hence the harmonic characteristics can be significantly improved, where the lower order harmonics, such as the fifth and seventh order are much reduced. The result are confirmed by the theoretical and experiment implementations.

추황배(Pyrus pyrifolia Nakai cv. Chuhwangbae) 과피로부터 1종의 Sterol과 3종의 배당체 화합물의 단리·동정

이유건(Yu Geon Lee1),조정용(Jeong-Yong Cho),이현주(Hyun Joo Lee),이용현(Yong Hyun Lee),이상현(Sang-Hyun Lee),한태호(Tae-Ho Han),김월수(Wol-Soo Kim),박근형(Keun-Hyung Park),문제학(Jae-Hak Moon) 한국식품과학회 2013 한국식품과학회지 Vol.45 No.5

본 연구에서는 배의 유용성 증명을 위한 일환으로 배의 화학성분을 분자수준에서 밝히고자 하였다. 이에 배 과피 MeOH 추출물을 용매분획하여 얻은 EtOAc-산성 분획과 EtOAc-중성분획을 대상으로 Sephadex LH-20, silica gel, 그리고 ODS colmn chromatography와 HPLC를 이용하여 정제 및 단리하였다. 그 결과, EtOAc-산성 분획과 EtOAc-중성 분획으로부터 각각 2종씩의 화합물을 단리하였다. 단리된 화합물 1-4는 1H- 및 13C-NMR 분석을 통하여 각각 (S)-(+)-2-cis-abscisic acid O-β-D-glucopyranosyl ester (화합물 1), 1-[4-O-β-D-glucopyranosyl]phenyl ethanone(piceoside, 화합물 2), β-sitosterol (화합물 3), 그리고 β-sitosteryl 3-O-β-D-glucopyranoside (화합물 4)로 동정되었다. 단리된 3종의 배당체 화합물(화합물 1, 2, 4)들은 본 연구에 의해 배로부터 처음 동정되었으며, 화합물 3은 추황배로부터 처음 동정되었다. 본 연구결과가 배 함유 성분연구는 물론 배의 기능성 해명 연구에도 추후 중요한 기초자료로 활용되길 기대한다. We isolated and identified antioxidants from acidic and neutral ethyl acetate fractions of the peel of pear (Pyrus pyrifolia N. cv. Chuhwangbae). We isolated 4 compounds from the methanol extract, by using 3 different types of column chromatography (Sephadex LH-20, silica gel, and octadecylsilane) and preparative HPLC. We identified the isolated compounds as (S)-(+)-2-cis-abscisic acid O-β-D-glucopyranosyl ester (compound 1), 1-[4-O-β-D-glucopyranosyl]phenyl ethanone (picroside, compound 2), β-sitosterol (compound 3), and β-sitosteryl 3-O-β-D-glucopyranoside (compound 4) by nuclear magnetic resonance analysis. We are the first to report the identification of compounds 1, 2, and 4 from pear.

지역 간 시계열 인구이동의 정량적 특징 분석 및 인구이동 네트워크의 연결중심성 분석

이상현,오윤경,Lee, Sang-Hyun,Oh, Yun-Gyeong 한국농공학회 2017 한국농공학회논문집 Vol.59 No.5

In this study, we visualized the regional migration in Korea from 2001 to 2015 using the Chord diagram which can represents amount of migration and flows at the same time. In addition, we constructed a migration network and analyzed the degree centrality of each region for identifying the main regions linking to various regions. In 2001~2005, most of population moved into Geonggi from various regions. However, the capital function was transferred to Sejong in 2011~2015, and population moving into Sejong and Chungnam was increased significantly. The main outflow of population in migration network were shown at the regions in Jeonbuk and Gyeongbuk province in 2001~2004, and recently the regions in Gyeongnam, Gyeonggi, and Seoul were identified as the main nodes in terms of outflow of population. We also focused on migration in rural area through degree centrality, and cord diagram in Chungnam, Jeonbuk, and Jeonnam where include the representative crop area. In 2015. there was the significant increase of migration from Gyeonggi to Chungnam, and internal migration within Jeonbuk increased rather than cross-border migration. In addition, migration from Jeonam to capital area decreased in 2015 but migration among cities within Jeonman increased. In particular, Yesan-gun showed the significant migration to other cities in Jeonnam. Population is necessary to develop community and sustain economic growth in rural regions. Therefore, migration is important for the transfer of manpower. The strength of this study is to approach the temporal change of migration from the viewpoint on quantitative and structural characteristics.

복층터널 안정성 분석을 위한 빔-스프링 모델 개발

이상현,안준상,강경남,김병찬,송기일,Lee, Sang-Hyun,An, Joon-Sang,Kang, Kyung-Nam,Kim, Byung-Chan,Song, Ki-Il 한국터널지하공간학회 2017 한국터널지하공간학회논문집 Vol.19 No.2

In this study, as an initial study for development of stability analysis program of a double-deck tunnel during life cycle, a structural analysis solver based beam-spring model for the double-deck tunnel is constructed. Effect of parameters(slab supporting type, depth of the tunnel and ground elastic modulus) is analyzed with the beam-spring model. The model is also compared and verified by commercial structural analysis program. It is considered that the slab supporting type affects the integrated behavior with segment lining and influence of intermediate slab on the stability of the tunnel decreases as the tunnel depth increases. The relationship between the ground elastic modulus and the effect of the intermediate slab on the segment lining needs further investigation. 본 연구는 복층터널 생애전주기 안정성 평가 프로그램 개발을 위한 초기 연구로서, 복층터널 안전성 분석을 위한 빔-스프링 모델 기반의 구조해석 솔버를 개발하였다. 구축된 복층터널의 빔-스프링 모델을 사용하여 중간슬래브 지지방식, 터널심도 및 지반탄성계수가 복층터널의 안정성에 미치는 영향에 대하여 분석하였으며, 상용 구조해석 프로그램과 비교검토를 수행하였다. 중간슬래브의 지지방식은 세그먼트 라이닝과 일체화 거동에 영향을 미치고, 터널심도가 깊어질수록 중간슬래브가 복층터널의 안정성에 미치는 영향력이 상대적으로 작아지는 것으로 판단된다. 지반탄성계수와 중간슬래브가 세그먼트 라이닝 부재력 분포에 미치는 영향의 관계는 추가적인 연구가 필요할 것으로 판단된다.

방약합편(方藥合編) 상통(上統) 처방(處方)에 대한 방제학적(方劑學的) 고찰(考察)

이상현,Lee, Sang-Hyun 대한한의학방제학회 2009 大韓韓醫學方劑學會誌 Vol.17 No.1

This report describes the studies as follows through the research of Basic-prescriptions about 123 prescriptions in high-chepter(上統) from Bang-Yak-Hap-Pyun(方藥合編). There are 24 Basic-prescriptions including Sagunja-tang(四君子湯), Samul-tang(四物湯), Sogeonjung-tang(小建中湯), lijung-tang(理中湯), Dangguibohyul-tang(當歸補血湯), Yijin-tang(二陳湯), Gauwon-chun(擧元煎), Jeongweon-eum(貞元飮), and Yukmichiwhang-won(六味地黃元), etc. about 123 prescriptions in high-chepter(上統) from Bang-Yak-Hap-Pyun(方藥合編). There were many cases compounding the Basic-prescriptions each other. So I investigated those cases. The results were the other typed (blended) Basic-prescriptions including Palmul-tang(八物湯), Sipjeondaebo-tang(十全大補湯), Yukgunja-tang(六君子湯), Bojungyikkee-tang(補中益氣湯), SsangHwa-tang(雙和湯), and Gwibitang(歸脾湯). And I investigated about pathologies in connection with these Basic-prescriptions. Oriental Medical Pathology applied with these Basic-prescriptions were Giheo(氣虛), hyulheo(血虛), Gihyulguheo(氣血俱虛), Biheohan(脾虛寒), Giheo-dameum(氣虛痰飮), Giheohaham(氣虛下陷), Sineumheo(腎陰虛), etc. These results indicated that 123 prescriptions in high-chepter from Bang-Yak-Hap-Pyun are composed of Bojei(補劑) to treatment against many kinds of Infirmity and promote physiological function.

비선형 구조물에 대한 수정 슬라이딩모드 제어알고리즘 성능 평가

이상현,Lee, Sang-Hyun 한국전산구조공학회 2007 한국전산구조공학회논문집 Vol.20 No.2

본 논문에서는 수정 슬라이딩 모드제어기의 비선형 이력구조물의 지진응답 제어성능이 평가되었다. 수정 슬라이딩모드 제어는 제어력을 계산하기 위해 Lyapunov함수의 목표변화율을 이용하는 기법으로 기존 연구에서는 선형구조물에 대한 성능만이 조사되었다. 그러나 강진시 대부분의 구조물은 비선형 거동을 보인다는 점을 고려할 때 기존 연구의 결과는 실제 적용에 있어 제한점을 가지고 있다. Bouc-Wen 모델을 사용하여 구조물의 비선형 거동을 모델링 하였으며, 이력이선형 단자유도 구조물에 대한 통계해석과 비선형이력 면진구조물에 대한 해석결과는 제안된 수정 슬라이딩모드 제어알고리즘이 기존의 슬라이딩모드 제어기보다 우수한 성능을 가짐을 보여준다. In this study, the performance of the modified sliding mode control proposed in the previous study is evaluated for seismic response control of nonlinear hysteretic structures. Modified sliding mode control(MSMC) utilizes the target derivative of Lyapunov function in order to calculate control force, and its performance was evaluated only lot linear structures in the previous study. However, considering that most structures subject to strong earthquake show nonlinear hysteretic behivior, the results from the previous study have limitations in practical application. The results from numerical analyses of single degree of freedom systems and base isolated system, which were described using Bouc-Wen model, indicate that the proposed MSMC algorithm shows better control performance than the existing sliding mode controller.

인진호탕(茵蔯蒿湯)과 오수목과탕(吳茱木瓜湯)의 항산화(抗酸化) 및 간세포(肝細胞) 보호효과(保護效果)

이상현,김영복,Lee, Sang-Hyun,Kim, Young-Bok 대한한의학방제학회 2008 大韓韓醫學方劑學會誌 Vol.16 No.1

Korean traditional medicine has been used for the treatment of the various diseases based on both oriental medicinal theory and clinical trials. Thus, the prescriptions of Korean traditional medicine would be useful for the development of new therapeutics. This research focuses on the fundamental study in Korean traditional prescriptions for the development of new hepatoprotective agents. We found two prescriptions. Injinho-Tang and Osumogwa-Tang, showed the significant DPPH free radical scavenging and hepatoprotective effect, respectively. It is well-known that free radical scavenging effect is related to the prevention of various pathological events including liver injury. This paper deals with hepatoprotective effects on tacrine-induced cytotoxicity in Hep G2 cells, free radicals scavenging on both DPPH and superoxide of above two prescriptions. Hot water extract of Injinho-Tang did not show the significant hepatoprotective effect on tacrine-induced cytotoxicity in Hep G2 cells, however, it shows the significant scavenging effects for both DPPH and superoxide radicals. On the other hand, all of the hot water extracts of constituent herbal drugs in Injinho-Tang exhibited the promising protective effect on tacrine-induced cytotoxicity in Hep G2 cells. Of these, water extract of Rhei Rhizoma showed the most prominent effect on tacrine-induced cytotoxicity in Hep G2 cells. Bioassay-guided fractionation of Rhei Rhizoma extract has furnished four compounds, and their chemical structures have been identified by comparison of their spectral data with those of literature as chrysophanol (1), emodin (2), 3,5-dihydroxy-4'- methoxystilbene (3), and rhapontigenin (4), respectively. Among the isolated compounds, compounds 2-4 revealed the significant hepatoprotective effect in vitro when their $EC_{50}$ values compare with that of silybin, as a positive control. It also exhibited that emodin possessed the most hepatoprotective effect among these active compounds. In case of Osumogwa-Tang, its hot water extract showed the moderate protective effect on tacrine-induced cytotoxicity in Hep G2 cells. Hot water extract of Chaenomelis Fructus, one of the constituent herbal drug of this prescription, exhibited the significant hepatoprotective effect with $EC_{50}$ value of $7.8{\pm}0.1\;{\mu}g/ml$, however, it showed strong cytotoxicity in Hep G2 cells above the concentration of $25\;{\mu}g/ml$. It was revealed that both hot water extract of Evodiae Fructus and its butanol soluble fraction showed the moderate hepatoprotective effect but concentration-dependent activity in Hep G2 assay system. Two quinolone alkaloids, evocarpine and dihydroevocarpine, also tested for their hepatoprotective effects on tacrine-induced cytotoxicity in Hep G2 cells, however, these two compounds derived from the Evodiae Fructus as the major constituents did not show in vitro hepatoprotective effect. From these results, it would be necessary to further isolation of its hepatoprotective compounds from the butanol soluble fraction of the hot water extract of Evodiae Fructus.

Antitumor and Immunostimulating Activities of Acanthopanax sessiliflorus Fruits

이상현,Yeon Sil Lee,Sang Hoon Jung,Jun Ji,Kuk Hyun Shin,Bak-Kwang Kim,강삼식 한국생약학회 2003 Natural Product Sciences Vol.9 No.2

The antitumor and immunostimulating activities of Acanthopanax sessiliflorus fruits were investigated. Polysaccharide isolated from this plant, when administered consecutively for 9 days at 50 and 100 mg/kg i.p. in mice, caused a significant increase in the life span and a significant decrease in the tumor weight and volume in mice inoculated with Sarcoma-180 tumor cells. Polysaccharide was also demonstrated to exhibit phagocytosis-enhancing activity as measured by the carbon clearance in mice. Polysaccharide, when administered i.p. at 50 and 100 mg/kg/day for 3 consecutive days, exhibited a significant RCtr/RCc [the rate of regression coefficient of the animals teated (RCtr) to that of the control (RCc)], being 1.44 (PI = 1), 1.52 (PI = 2) which was approximately the same with that of enhancement of phagocytosis, its potency as expressed by the regression coefficient ratio of zymosan (RCtr/RCc = 1.55, PI = 2), a typical phagocytosis enhancer. Polysaccharide also caused a significant increase in the acid phosphatase activity representing lysosomal enzymes in macrophages at 1-100 ig/ml in vitro in compliance with in vivo results. These results suggest that the antitumor activity of polysaccharide might be related to the immunostimulating function.