Mo/SiO₂ 촉매상에서 t-Butyl hydroperoxide에 의한 염화알릴의 에폭시화반응에 관한 속도론적 연구

김성우,박대원,정종식,박대철,Kim, Sung-Woo,Park, Dae-Won,Chung, Jong-Shik,Park, Dae-Chul 한국공업화학회 1992 공업화학 Vol.3 No.4

The synthesis of epichlorohydrin was carried out by the epoxidation of allyl chloride with tert-butyl hydroperoxide(TBHP) over silica supported molybdenum catalyst. Kinetic study was performed at $60-80^{\circ}C$ and 10 atm with the molar ratio of TBHP/Allyl chloride between 0.01 and 0.1 in a batch reactor. The epoxidation of allyl chloride was inhibited by tert-butyl alcohol and kinetic data could be represented by Michaelis-Meten type rate equation. The reaction mechanism could be explained by the combination of reversible adsorption of TBHP and tert-butyl alcohol accompanied by reaction of allyl chloride with TBHP adsorbed on $Mo/SiO_2$ catalyst. t-Butyl hydroperoxide(TBHP)에 의한 염화알릴의 에폭시화에 의해서 에피클로로히드린을 합성하는데 실리카에 담지된 몰리브데늄 촉매를 사용하였다. 속도론적 연구는 회분 반응기를 사용하여 $60-80^{\circ}C$, 10기압에서 TBHP/염화알릴의 농도비를 0.01-0.1의 범위내에서 수행하였다. t-butyl alcohol(TBA)에 의해서 염화알릴의 에폭시화 반응이 억제되었고, 반응속도는 Michaelis-Menten 형태의 속도식으로 표현할 수 있었다. 반응기구는 TBHP와 TBA의 가역흡착과 $Mo/SiO_2$에 흡착된 TBHP와 염화알릴의 표면반응으로 설명할 수 있었다.

공간(空間)과 천지(天地) - 동서양 건축에서의 공간관 -

김성우,Kim, Sung-Woo 한국건축역사학회 2005 건축역사연구 Vol.14 No.4

We are so used to the concept of the term 'space' that we do not question its conceptual validity. However, this paper argues that the notion of space prevailing all over the world, is not a universal concept that can be applicable to all architectures of the world, but is a particular concept that is generated from the Western way of thinking. This paper alms to identify the conceptual structure of the idea of space as it is originated in the tradition of the West, and, as an alternative view of space, tries to identify the nature of the view of space perceived in the tradition of the Eastern architecture. Comparison of the two views, that of the East and the West, and their meaning in the future of architecture, is another task to discuss in this paper. To be able to clarify the meaning of space in East Asian tradition, a set of new perspective of understanding of space was invited. They are ; 1. sky-earth(天地); insisting that the notion of space should be replaced within the context of sky, which is one half of sky-earth totality 2. energy of the air (空氣), space is not empty part inside of a building, but is a dynamic condition of air that is a part of the sky which always exist in form of energy 3. place(자리): instead of space, which, basically. is a man-made concept, idea of place is necessary, which include not only space but also earth Such concept of space which is different from the notion of space of the West, is meaningful not only to identify the idea of space in the East, but also to be able to contribute for more dynamic, varied, and balanced understanding of space.

항공 통신, 항법, 식별장비 시험평가

김성우,김민수,이영식,이병화,오우섭,Kim, Sung Woo,Kim, Min Su,Lee, Young Sik,Lee, Byoung Hwa,Oh, Woo Seop 한국군사과학기술학회 2012 한국군사과학기술학회지 Vol.15 No.5

Airborne radio communications, navigation, and identification equipments are the basic equipment of airplane. Airborne radio communications, navigation, and identification equipments are characterized by user's many quantitative and qualitative requirements. These equipment look like simple test and evaluation, but they have many complex factors. This paper describe the test and evaluation of airborne radio communications, navigation, and identification equipments.

시각(視覺)과 감응(感應) : 동서양건축에서의 경험의 문제

김성우,Kim, Sung-Woo 한국건축역사학회 2004 건축역사연구 Vol.13 No.4

Perception of architectural experience is different in different culture. This paper aims to identify how the experience of architecture is understood to be different in Eastern and Western culture. The discussion is based on the idea that the Western architecture placed more emphasis on visual perception, while the Eastern, on mutual responsiveness between man and built environment. The fact that the Western culture is more visually oriented than other culture, and therefore visual aspect of architecture, too, is considered to be very important, is already widely agreed among scholars. But, then, what had been considered to be important in the architectural experience in the East? It is the degree and quality of mutual responsiveness between man and architectural environment. This fact influenced much on the making of architecture of course, and the same fact played the key role in making the Eastern architecture different from that of the West. We are so used to the way of architecture of the West, that the quality of responsiveness is unknown if not forgotten. However, it is not the quality that was useful only in traditional society of the East, but necessary in our modem period as well. The quality for responsiveness, therefore, should be rediscovered and restored as the prime value and quality of architecture in the future architecture.

Measurement of Electron Beam Output for the Prototype Compact Linac

김성우,강상구,이동주,임희진,이만우,이준규,이무진,양광모,노태익,정동혁,Kim, Sung-Woo,Kang, Sang Koo,Rhee, Dong Joo,Lim, Heuijin,Lee, Manwoo,Yi, Jungyu,Lee, Mujin,Yang, Kwangmo,Ro, Tae Ik,Jeong, Dong Hyeok Korean Society of Medical Physics 2015 의학물리 Vol.26 No.1

The C-band compact linear accelerator (linac) is being developed at Dongnam Institute of radiological & Medical Sciences (DIRAMS) for medical and industrial applications. This paper was focused on the output measurement of the electron beam generated from the prototype electron linac. The dose rate was measured in unit of cGy/min per unit pulse frequency according to the IAEA TRS-398 protocol. Exradin-A10 Markus type plane parallel chamber used for the measurement was calibrated in terms of dose to water at the reference depth in water. The beam quality index ($R_{50}$) was determined by the radiochromic film with a solid water phantom approximately due to low energy electrons. As a result, the determined electron beam output was $17.0cGy/(min{\cdot}Hz$. The results were used to monitor the accelerator performance during the development procedure. 의료용 및 산업용으로 활용하기 위한 C-밴드형 콤팩트 선형가속기의 개발이 동남권원자력의학원에서 진행되고 있다. 본 논문에서는 선형가속기 시작품에서 발생한 전자빔의 출력 측정 결과를 보고하고자 한다. 출력 측정은 물흡수선량에 대해 교정된 Exradin-A10 마커스형 평행평판형 전리함을 사용하여 물속 기준 깊이에서 IAEA TRS-398 프로토콜에 따라 흡수선량율을 결정하는 과정으로 진행되었다. 전자선 에너지가 낮은 점으로 인하여 선질지표($R_{50}$)은 필름 측정법을 써서 근사적으로 결정하였다. 결과로서 단위 펄스 진동수당의 선형가속기 전자빔의 출력은 $17.0cGy/(min{\cdot}Hz$로 나타났다. 본 연구의 결과는 개발 중인 전자가속기의 성능 평가 자료로 활용될 것이다.

비례(比例)와 기운(氣韻) - 동서양 건축에서의 심미성 -

김성우,Kim, Sung-Woo 한국건축역사학회 2005 건축역사연구 Vol.14 No.2

All architectures in the history have certain attitudes of aesthetic expression of their own. Depending on the culture, such aesthetic attitudes are not the same but different. This paper aims to identify the nature of the difference of aesthetic attitude in the architectures of the East and the West. As a way of approach for this purpose, two keywords are employed as representative concept. They are: 'proportion' and 'vitality'. Proportion, of course, represent the attitude of the Western, while, vitality, the Eastern. Although these two words are subjective selection, it is hoped that the nature of aesthetic attitudes could be observed through the windows of these two representative concepts. We all know that the architects and students of architecture of this period, are very much concerned about the aesthetic expression of their design. However, the value judgement of aesthetic quality seems quite confused in modem period. If the nature of aesthetic attitudes of the Eastern and the Western architecture is well understood, such understanding will help much for the direction of architectural aesthetic of future architecture.

북한의 핵테러와 대응방안

김성우,Kim, Sung Woo 한국융합보안학회 2014 융합보안 논문지 Vol.14 No.6

한국은 북한의 핵무기 위협에 우선적으로 대응하여야 하는 상황에 직면해 있다. 전략적으로 대응방향은 한국 자체 및 미국의 억제전력을 강화함과 동시에 현재 상태에서 그에 대한 현실적인 해결책은 선제타격을 통한 사전 제거라는 점도 인정할 필요가 있다. 현재 북한의 미사일 위협은 상존하고 있으며 미사일에 탑재시킬 정도의 핵무기를 소형화하는데 성공하였을 가능성도 매우 높다. 한국은 적의 미사일 방어에 관심을 가져야 하며 대공방어는 하층방어와 상층방어를 중심으로 한 전반적인 미사일 방어 체제의 구축방향을 토의 연구하는 한편 인구밀집 도시와 국가 전략시설을 방호할 수 있는 체계를 구축해야한다. 지금까지 북한의 핵무기 위협과 관련된 쟁점은 6자 회담과 같은 국제적이고 외교적인 접근에 의해 문제를 해결하려고 주 노력을 경주하였는데 이 방법이 과연 효율적인지, 북한의 핵무기 위협에 대한 정보의 신뢰도는 과연 어느 정도 인지와 이것을 기초로 우리 군의 방어태세의 하나인 킬체인(Kill Chain)이 효과적인 방어수단이 될 수 있는가 등이다. 지금까지 우리가 얻은 교훈은 북한이 스스로 핵무기 개발을 포기하지 않는 한 외교적 노력으로만 북한의 핵무기를 개발을 억제하는 것은 불가능하다는 것을 알았다. 외교적인 노력과 더불어 군사적인 방법으로 다양한 억제 대책도 실제로 시행할 수 있도록 준비해야 한다. South Korea should correspond to the primary threat to North Korea's nuclear weapons. It is necessary to have countermeasures to solve the realistic problems of North Korea's nuclear weapons. We can intensify military pact between the United States and Korea and at the same time strengthening the current military power. Currently, we take note the threat North Korea's missile. We can not control the development of a nuclear weapon and there are possibilities that North Korea have successfully miniaturized nuclear enough to carry by the missile. We should overview and check the Korea's missile defenses system. While the direction of the overall missile defense system deployment with a focus on lower and upper air defense network. And discuss defense research should be to build a system that can be protected with a key strategic facilities and cities. While North Korea have nuclear weapon, the main issues related to North Korea's nuclear threat. The six party talks countries try to solve the problem by the international and diplomatic approach. At the same time we should make somewhat to defend measures such as military defenses of Kill chain system to protect our country. Kill Chain is on of the effective defense system. We know that North Korea do not abandon to develop nuclear weapons by diplomatic efforts. We should performed in fact by a variety of military suppression method.

동서양 건축에서의 공간과 시간

김성우,Kim, Sung-woo 한국건축역사학회 2004 건축역사연구 Vol.13 No.3

The tradition of architecture in the East and the West are different in many ways. One of the basic cause of such difference, however, is the different ways of perception of space and time. This paper aims to identify the attitude of perception of space and time in the cultures of the East and the West, and its influence on architecture. Degrees of importance placed on either space or time, as well as the modes of perception of space and time are discussed in relation to architecture. Basically, the architecture of the West seems to be more spatially oriented than the East, and this have much to do with the fact that the tradition of Western architecture is visually oriented. On the other hand, East Asian architecture have been more conscious on bodily feeling and its movement in architecture. Spatial units of traditional Eastern architecture, are arranged in such a way in which man can experience the change of space that is supposed to be organized to form a sequential message. Thus, in the East, temporal dimension is more deliberately included in the course of architectural experience compared to the cases of the West. Although it is not easy to attempt any kind of value judgment on such aspects, it is necessary to understand how the different perception of space and time influenced architectural outcome, especially when one wants to understand the cultural cause that have made the architectures of the East and the West very different. Such understanding is particularly important in East Asia where their future of architecture depends much on how they harmonize the Eastern and Western background which are already built up as two cultural structure in their consciousness to be able to create more desirable architecture for themselves.

비평 - 관행과 파행, 민정학원의 경우

김성우,Kim, Sung-Woo 대한건축사협회 1994 建築士 Vol.1994 No.11

한국형 가동헬기 임무탑재장비 요구항법성능 구현

김성우,이병화,오우섭,Kim, Sung-Woo,Lee, Byoung-Hwa,Oh, Woo-Seop 한국군사과학기술학회 2011 한국군사과학기술학회지 Vol.14 No.5

A number of navigation improvements are envisaged : Differential GPS - WAAS, LAAS, and Performance Based Navigation. The GPS receiver verifies the integrity(usability) of the signals received from the GPS constellation through a process called receiver autonomous integrity monitoring(RAIM) to determine if a satellite is providing corrupted information. This paper describe the RAIM function and Performance-Based Navigation implementation of Mission Equipment Package(MEP) for Korean Utility Helicopter.