李相定(1897~1947)의 在中獨立運動

崔起榮(Choi Ki-young) 역사학회 2008 역사학보 Vol.0 No.200

Lee Sang-jung who was born in Daegu in 1897 went to Seijo Middle School in Tokyo and studied history at Kokugakuin University. He returned to Korea in 1917 and had worked as a teacher in Daegu and northwestern province in Korea. Then, he exiled himself to China in 1925. He once participated in education for Korean in Manchuria and worked for Chinese Warlord Feng Yuxiang's army as a staff officer. Lee Sangjung had lived with Kwon Ki-ok who had worked for Feng Yuxiang's air force. He settled down in Nanjing where he worked as a Chinese soldier in Jiangsu and Zhejiang province in the late 1920s. Both Lee and Kwon were once suspected of being Communist party members in 1928. Before and after the outbreak of the Sino-Japanese War in 1937, Lee took the head of the National Front Unification Movement and participated in Korea National Revolution Party. Then, he withdrew from Nanjing and moved to Chungching to serve as a military officer for the Nationalist Government of China. He joined the Korean Provisional Government and worked as a member of Korean Provisional Assembly. He emphasized the independence and autonomy of Korea and claimed that the equal relationship between Korea and China would lead to the development of two countries' solidarity. He took part in the formation of New Korean Democratic Party in February 1945. After liberation, he devoted himself to solving the problems of Korean residents in China. He returned to Korea in 1947, but passed away soon after his arrival.

Zinc(Ⅱ) Tetraaza-Crown-Allkanoic Acids 착물의 형성 및 해리 반응속도론

최기영,김동원,김창석,박병빈,최석남,홍춘표,류해일,Choi, Ki Young,Kim, Dong Won,Kim, Chang Suk,Park, Byung Bin,Choi, Suk Nam,Hong, Choon Pyo,Ryu, Hae Il 대한화학회 2000 대한화학회지 Vol.44 No.5

1,4,7,10-tetraaza13,16-dioxacyclooctadecane-N,N',N",N'"-tetraacetic acid (1), 1,4,7,10-tetraaza-13,16-dioxactclootadecane-N,N',N",N'"-tramethylacetic acid (2), 및 1,4,7,10-tetraaza-13,16-dixacyclooc-tedecane-N,N',N",N'"-tetrapropionic acid (3)와 $Zn^{2+}$ 착물의 형성 및 해리 속도를 멈춤-흐름법 및 분광학적방법으로 측정하였다. 측정 조건을 온도 25.0$\pm$0.1 $^{\circ}C$ 및 이온강도 0.10 M NaClO4 이었다. $Zn^{2+}$이온과 1과 2의 형성 반응은 빠르게 중간 생성물($ZnH_3L^+$)를 형성한다. 여기서 $Zn^{2+}$ 이온은 부분적으로 배위되어 있고 속도 결정 단계는 최종 생성물이었다. pH범위 4.76-5.76에서, 2가 양성자($H_2L^{2-}$) 형태가 매우 낮은 농도임에도 불구하고 속도론적으로 활성화종임을 알 수 있었다. 또한 중간체 착물의 안정도 상수(log$K_{(ZnH_3L^+)}$)와 고유 물분자-보조 속도상수(KOH)가 속도론적 자료로부터 계산되었다. $Zn^{2+}$이온과 1,2, 및 3의 해리 반응은 아세테이트 완충 용액 하에서 청소군 $Cu^{2+}$ 이온을 이용하여 측정하였다. 모든 착물의 해리 반응은 산-무관 및 산-촉매 반응으로 진행됨을 알 수 있었다. $Zn^{2+}$ 착물의 해리 속도에 영향을 미치는 완충 용액 및 $Cu^{2+}$농도의 효과를 알아보았으며, 아울러 리간드 효과를 곁가지에 매달려있는 치환기와 킬레이트 고리크리로 논하였다. The formation and dissociation rates of $Zn^{2+}$ Complexes with l,4,7,10-tetraaza-13,16-diox-acyclooctadecane-N,N',N",N'"-tetraacetic acid (1), 1,4,7,10-tetraaza-13,16- dioxacyclooctadecane-N,N',N",N'"-tetramethylacetic acid (2), and 1,4,7,10-tetraaza-13,16- dioxacyclooctadecane-N,N',N",N'"-tetrapropionic acid(3) have been measured by stopped-flow and conventional spectrophotometry. Observations were made at 25.0$\pm$0.1 $^{\circ}C$ and at an ionic strength of 0.10 M NaClO$_4$. The formation reactions of $Zn^{2+}$ ion with 1 and 2 took place by the rapid formation of an intermediate complex (ZnH$_3L^+$) in which the $Zn^{2+}$ ion is incompletely coor-dinated. This might then lead to be a final product in the rate-determining step.ln the pH range 4.76-5.76, the diprotonated (H2L2-) form is the kinetically active species despite of its low concentration. The stability con-stants (log$K_{(ZnH$_3$3$L^+$)}$) and specific water-assisted rate constants (koH) of intermediate complexes have been deter-mined from the kinetic data. The dissociation reactions of $Zn^{2+}$ complexes of 1,2, and 3 were investigated with $Cu^{2+}$ ions as a scavenger in acetate buffer. All complexes exhibit acid-independent and acid-catalyzed con-tributions. The effect of buffer and $Cu^{2+}$ concentration on the dissociation rate has also been investigated. The ligand effect on t dissociation rate of $Zn^{2+}$ complexes is discussed in terms of the side-pendant armsand the chelate ring sizes of the ligands.

지방중소도시 택지개발지구 단독주택지의 개발경향에 관한 연구 - 1992년부터 1996년까지 조성된 지구를 중심으로 -

최기영,Choi, Ki-Young 한국주거학회 2011 한국주거학회 논문집 Vol.22 No.2

The growth of housing complex in the Housing Development District in local small and medium cities can be defined to process individual lots are possessed by buildings. The study is the basic research of analysis for the internal factors that affect on the each lot, and is for hypothesis of the verification about the Housing Development District growth. So, it can be applied in the Housing Development District of the site conditions and restriction of use of buildings and infrastructure works and the constant boundary of the region. The rate of the development is the occupation of the individual lots per entire lots was limited as the factor of analysis. As above conditions haver no possibility to change in the Housing Development District, the results of this study and further are available to consider. By the results of the connected study, it can be used for Planning and management of the Housing Development District in local small and medium cities. by the adjustment of the relation between growth tendecy and city's properties or district characters.

Synthesis and Crystal Structure of 13-Membered Tetraaza Macrocyclic Cobalt(III) Complex with Azido Ligand

최기영,Choi, Ki-Young Korea Crystallographic Association 2006 韓國結晶學會誌 Vol.17 No.2

[ $cis-[Co(13-aneN_4)(N_3)_2]Cl{\cdot}H_2O$ ] (1) (13-ane$N_4$ = 1,4,7,10-tetraazacyclotridecane) 착물(錯物)을 합성(合成)하고 구조(構造)를 규명(糾明)하였다. 이 착물(錯物)은 단사정계(單斜晶系), 공간군(空間群) Pbca, a = 7.8282(4) ${\AA}$, b = 14.3197(7) ${\AA}$, c = 29.9021(15) ${\AA}$, V= 3351.9(3) ${\AA}^3$, Z = 8로 결정화(決定化) 되었다. 착물(錯物) 1의 코발트(III)이온은 거대(巨大)고리 리간드의 4개(個)의 질소원자(窒素原子)와 시스 위치에 2개(個)의 azide 리간드가 결합(結合)한 고천(若干) 일그러진 팔면체(八面體) 구조(構造)를 갖는데, 착물(錯物)의 양이온, 염소(鹽素) 음이온 및 물분자(分子)를 통하여 1차원의 수소결합(水素結合)을 형성(形成)한다. The complex $cis-[Co(13-aneN_4)(N_3)_2]Cl\cdot H_2O$ (1) (13-ane$N_4$ = 1,4,7,10-tetraazacyclotridecane) has been synthesized and structurally characterized by X-ray crystalloaraphy. It crystallizes in the orthorhombic system Pbca, a = 7.8282(4) ${\AA}$, b = 14.3197(7) ${\AA}$, c = 29.9021(15) ${\AA}$, V = 3351.9(3) ${\AA}^3$, Z = 8. The cobalt(III) ion in 1 is coordinated to four nitrogen atoms from the macrocycle and two azide ligands of cis position in a distorted octahedral environment, which forms the 1D polymer through hydrogen bonding contacts involving the cation, chloride anion and solvent water molecules.

치주질환 환자의 염증도와 in vivo 치은열구 다형핵 백혈구 화학주성에 관한 비교 연구

최기영,정종평,Choi, Ki-Young,Chung, Chong-Pyong 대한치주과학회 1984 Journal of Periodontal & Implant Science Vol.14 No.1

치주질환에서 Bacteroides intermedius의 혈청형 특성에 관한 연구

최기영,정종평,손성희,Choi, Ki-Young,Chung, Chong-Pyoung,Son, Seong-Heui 대한치주과학회 1990 Journal of Periodontal & Implant Science Vol.20 No.2

Synthesis and Crystal Structure of Zinc(II) Complex of a Di-N-acetamide Tetraaza Macrocycle

최기영,김한형,서일환,Choi, Ki-Young,Kim, Han-Hyoung,Suh, Il-Hwan Korean Chemical Society 2001 대한화학회지 Vol.45 No.2

Enantiomorphic 공간군 $P4_12_12$을 갖는 Di-(2-Picolyl) sulfur Dichloro Zinc(II)의 Absolute Configuration

최기영,이한형,김민희,황민아,강상욱,손호진,손기철,한원식,서일환,Choi Ki-Young,Lee Han-Hyoung,Kim Min-Hee,Whang Min-Ah,Kang Sang Ook,Son Ho-Jin,Son Ki-Chul,Han Won-Sik,Suh Il-Hwan 한국결정학회 2005 韓國結晶學會誌 Vol.16 No.1

The crystal structure of an enantiomeric compound di-(2-picolyl)sulfur dichloro zinc(II), $C_{12}H_{12}N_2SCl_2Zn$, could be elucidated with two space groups $P4_12_12\;and\;P4_32_12$. However, its absolute configuration with the space group $P4_12_12$ was confirmed by means of the effect of anomalous dispersion. 거울상 이성질체인 di-(2-picolyl) sulfur dichloro Zinc(II), $C_{12}H_{12}N_2SCl_2Zn$의 결정구조가 두 개의 공간군 $P4_12_12\;과\;P4_32_12$로 밝혀질 수 있었다. 그러나 공간군 $P4_12_12$를 갖는 그의 absolute configuration이 anomalous dispersion의 효과에 의하여 확인되었다.

Synthesis and Crystal Structure of Syn-Anti Carboxylate-Bridged Dinuclear Copper(II) Complex

최기영,Choi, Ki-Young Korea Crystallographic Association 2006 韓國結晶學會誌 Vol.17 No.2

이핵 구리 착물(錯物) {[Cu(pmea)Cl][Cu$(H_2O)_3]}Cl_2\cdot H_2O$ (1) (Hpmea=bis(2-pyridylmethyl)amino-2-ethanoic acid)을 합성(合成)하고 구조(構造)를 규명(糾明)하였다. 이 착물(錯物)은 단사정계(單斜晶系), 공간군(空間群) $P2_1/c$, a=9.0008(6) ${\AA}$, b=28.0171(19) ${\AA}$, c=8.5590(6) ${\AA}$, $\beta$=104.2280(10)$^{\circ}$, V=2092.2(2) ${\AA}^3$, Z=4로 결정화(決定化) 되었다. 착물(錯物) 1의 결정구조(結晶構造)는 대칭(對稱)-반대칭(反對稱) carboxylate 다리로 연결(連結)된 이핵 착물(錯物)로서, 각각(各各) 구리원자의 배위환경(配位環境)은 고천(若千) 일그러진 사각뿔구조(構造)와 고천(若干) 일그러진 사각평면구조(構造)를 갖는다. The dinuclear copper(II) complex {[Cu(pmea)Cl][Cu$(H_2O)_3]}Cl_2{\cdot} H_2O$ (1) (Hpmea=bis(2-pyridvlmethyl)amino-2-ethanoic acid) has been synthesized and characterized. It crystallizes in the monoclinic system $P2_1/c$, a=9.0008(6) ${\AA}$, b=28.0171(19) ${\AA}$, c=8.5590(6) ${\AA}$, $\beta$=104.2280(10)$^{\circ}$, V=2092.2(2) ${\AA}^3$, Z=4. Crystal structure of 1 reveals a syn-anti carboxylate-bridged dinuclear complex, in which the coordination environment around each copper atom exhibits a distorted square-pyramid and a distorted square plane, respectively.

Synthesis, Properties, and X-ray Crystal Structure of Copper(II) Complex with Bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine

최기영,Choi, Ki-Young Korean Chemical Society 2007 대한화학회지 Vol.51 No.1

트리포달 구리(II) 착물 [Cu(pmea)(H2O)](ClO4)2·H2O (1) (pmea=bis[(2-pyridyl)methyl]-2-(2-pyridyl)-ethylamine)을 합성하고 X-선 회절법으로 구조를 규명하였다. 이 착물은 삼사정계, 공간군 P-1, a = 9.9362(9) A, b = 15.7299(17) A, c = 18.0562(11) A, α = 68.760(8)°, β = 76.331(6)°, γ = 77.092(9)°, V = 2526.2(4) A3, Z = 2로 결정화 되었다. 각각의 구리 원자는 약간 일그러진 사각뿔 구조를 갖는데, 바탕 면은 pmea 리간드에 있는 세 개의 질소원자와 물 분자가 포함되어 있으며 축 방향에는 피리딘 고리의 질소 원자가 포함되어있다. 착물 1의 순환 전압전류 그림은 가역 일-전자 산화 CuIII 및 환원 CuI 과정으로 진행됨을 보여주었다. The tripodal copper(II) complex [Cu(pmea)(H2O)](ClO4)2·H2O (1) (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine) has been synthesized and structurally characterized by X-ray diffraction method. It crystallizes in the triclinic system P-1 with a = 9.9362(9), b = 15.7299(17), c = 18.0562(11) A, α = 68.760(8), β = 76.331(6), γ = 77.092(9)°, V = 2526.2(4) A3, Z = 2. Each copper atom reveals a distorted square pyramidal with three nitrogen atoms of the pmea ligand and water molecule occupying the basal plane and one nitrogen atom from the pyridine ring according the axial position. The cyclic voltammogram of 1 undergoes reversible one-electron oxidation to the CuIII and reversible one-electron reduction to the CuI.