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고성능 쉴드 세그먼트용 고로슬래그 미분말을 혼입한 콘크리트의 역학적 특성 및 증기양생 효과 분석
김병권,이진섭,이규필,장수호,배규진,Kim, Byoung-Kwon,Lee, Jin-Seop,Lee, Gyu-Phil,Chang, Soo-Ho,Bae, Gyu-Jin 한국터널지하공간학회 2011 한국터널지하공간학회논문집 Vol.13 No.3
본 연구에서는 쉴드터널에 사용되는 세그먼트의 성능향상과 경제성향상을 위하여 고로슬래그 미분말을 혼합한 고강도 콘크리트에 대한 기초 연구를 실시하였다. 특히, 설계강도가 60 MPa 세그먼트용 콘크리트에 대해서 고로슬래그 미분말의 최적 치환율과 최적의 증기양생 조건을 도출하고자 하였다. 이상의 결과로부터, 고로슬래그 치환율 50%와 단위수량 125 kg/$m^3$ 일 경우가 성능과 경제적인 측면에서 가장 적합한 배합조건으로 나타났다. 또한 표준양생 조건과 비교할 때 증가양생에 의하여 약 110~442%의 강도증진 효과를 기대할 수 있는 것으로 확인되었다. This study aims to evaluate the applicability of high-strength concrete mixed with blast furnace slag to shield segment lining in order to improve its performance and economic efficiency. Especially, it was also intended to derive the optimum replacing ratio of ground granulated blast furnace slag to ordinary cement as well as the optimum steam curing condition for shield segment concrete with the design strength of 60 MPa. From a series of experiments, the condition of 50% replacement of ordinary cement by ground granulated blast furnace slag and unit water content of 125 kg/$m^3$ was proposed as the optimum mixing condition. Comparing with standard curing conditions, it was also possible to expect approximately 110~442% strength improvement of concrete by steam curing in the same mixing condition.
흑연로 원자 흡광 광도기와 유도 결합 플라즈마 질량 분석기를
권정연(Jung-Yeon Kwon),김병권(Byoung-Gwon Kim),임현주(Hyoun-Ju Lim),서정욱(Jeong-Wook Seo),강민경(Min-Kyung Kang),김유미(Yu-Mi Kim),홍영습(Young-Seoub Hong) 한국환경보건학회 2018 한국환경보건학회지 Vol.44 No.5
Objectives: The aims of this study were to compare concentrations and the correspondence of human blood cadmium by using graphite furnace atomic absorption spectrometry (GF-AAS) and inductively coupled plasmamass spectrometry (ICP-MS), which are representative methods of heavy metal analysis. Methods: We randomly selected 79 people who agreed to participate in the research project. After confirming the linearity of the calibration curves for GF-AAS and ICP-MS, the concentrations of cadmium in a quality control standard material and blood samples were measured, and the correlation and the degree of agreement were compared. Results: The detection limit of ICP-MS (IDL: 0.000 µg/L, MDL: 0.06 µg/L) was lower than that of GF-AAS (IDL: 0.085 µg/L, MDL: 0.327 µg/L). The coefficient of variation of the quality control standard material showed stable values f or both ICP-MS (clinchek-1: 5.35%, clinchek-2: 6.22%) and GF-AAS (clinchek-1: 7.92%, clinchek-2: 5.22%). Recovery was relatively high for both ICP-MS (clinchek-1: 95.1%, clinchek-2: 92.8%) and GF-AAS (clinchek-1: 91.4%, clinchek-2: 98.8%), with more than 90%. The geometric mean, median, and percentile of blood samples were all similar. The agreement of the two instruments compared with the bias of the analytical values found that about 81% of the analytical values w ere within ± 30% of the deviation from the ideal reference line (y=0). As a result of the agreement limit, the value included in the confidence interval was about 94%, which shows high agreement. Conclusion: In this study, we confirmed there was no significant difference in concentrations of a quality control standard material and blood samples. Since ICP-MS showed lower concentrations than GF-AAS at concentrations below the method detection limit of GF-AAS, it is expected that more precise results will be obtained by analyzing blood cadmium with ICP-MS.
폐금속광산 지역 주민의 비소 대사에 영향을 미치는 MTHFR , As3MT, GSTO1 유전자 다형성
울지(Ulziikhishig Surenbaatar),김병권(Byoung-Gwon Kim),손현진(Hyun-Jin Son),조성식(Seong-Sik Cho),김권민(Gwon-Min Kim),임현주(Hyoun-Ju Lim),권정연(Jung-Yeon Kwon),김기환(Ki-Hwan Kim),홍영습(Young-Seoub Hong) 한국환경보건학회 2021 한국환경보건학회지 Vol.47 No.6
Background: In South Korea, areas around abandoned metal mines are designated as regions with high arsenic (As) contamination. However, studies assessing urinary As exposure, As metabolism, and relevant genetic polymorphisms in residents of these metal mine areas are lacking. Objectives: To identify factors associated with As exposure and evaluate the effects of MTHFR , As3MT, and GSTO1 genetic polymorphisms on As metabolism in residents of abandoned metal mine areas by measuring urinary As species. Methods: Urinary As species (arsenite [As3+], arsenate [As5+], monomethyl arsonic acid, and dimethylarsinic acid) were isolated using high-performance liquid chromatography in combination with inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Four genetic polymorphisms (MTHFR A222V, MTHFR E429A, GSTO1 A140D, As3MT M287T) were analyzed in 144 residents of four areas around abandoned metal mines. Results: The study sample was comprised of 34.7% men and 65.3% women, with a mean age of 70.7±10.9 years. The urinary inorganic As concentration was higher among those consuming more than half locally produced rice (0.31 μg/L) than those consuming less than half such rice (0.18 μg/L). The urinary dimethylarsinic acid concentration was higher in the group that had consumed seafood in the past day (31.68 μg/L) than in those who had not (22.37 μg/L). Furthermore, individuals heterozygous in the MTHFR A222V and GSTO1 A140D polymorphism had higher urinary arsenic species concentrations than did individuals with a wild type or homozygous for the variant allele. Conclusions: Consumption of locally produced rice was associated with inorganic As exposure, whereas seafood consumption was associated with organic As exposure among residents of abandoned metal mine areas. There was no clear association between MTHFR A222V and GSTO1 A140D polymorphisms and As metabolism.
광물질혼화재 혼합 고강도 콘크리트의 양생조건에 따른 염화물이온 침투저항성
문한영 ( Moon Han-young ),김병권 ( Kim Byoung-kwon ) 한국구조물진단유지관리공학회 2004 한국구조물진단유지관리공학회 논문집 Vol.8 No.2
근년에 와서 우리나라 건설업체의 해외진출이 빈번해 지고 있는 시점에서 특히 동남아 지역에서 대형 해양콘크리트구조물 등의 수주물량이 크게 증가하고 있는 추세를 감안하여 콘크리트 품질향상의 일환으로 광물질혼화재를 혼합한 고강도콘크리트에 착안하게 되었다. 그래서 광물질혼화재의 혼합률을 각각 달리하여 현장의 기후조건을 고려한 양생온도 23℃ 및 35℃의 2 종류와 양생조건을 3 종류로 변화시킨 4 배합, 16종류의 고강도콘크리트를 제조하였다. 본 연구 결과, 광물질혼화재를 혼합한 고강도콘크리트를 35℃로 양생한 경우 초기재령에서 압축강도가 23℃로 양생한 경우보다 컸으나 재령 28일 이후에는 반전되었다. 특히 고로슬래그미분말, 실리카흄과 팽창재 혼합 및 고로슬래그미분말과 실리카흄을 혼합한 고강도콘크리트의 총통과전하량은 각각 Negligible 및 Very low에 해당되는 매우 좋은 결과를 나타내었다. 따라서 고로슬래그미분말, 실리카흄 및 팽창재를 각각 적정량 혼합함에 따라 밀실한 고강도콘크리트의 제조가 가능하게 됨으로써 염화물이온 침투저항성이 크게 향상되었다. In recent years, construction company makes inroads into the world construction market, and receives the order of extra-large concrete structure under marine environment in south-east asia specially. At this point of time, to enhance the quality of concrete, we research the High Strength Concrete (HSC) containing mineral admixtures. In this study, therefore, HSC with various combination of ordinary portland cement(OPC), blast-furnace slag(SG), silica fume(SF), and expansion admixture(SS) are cured 23 and 35℃ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. Test results show that the HSC cured at 35℃ gains higher early-age strength but eventually gains lower later-age strength compare with the HSC cured at 23℃. Especially, HSC with combination of OPC+SG+SF+SS or OPC+SG+SF show very excellent resistance of chloride penetration. The permeability of HSC was therefore enhanced as because of containing the proper content of SG, SF, and SS and making dense micro-structure of HSC.
고유동 자기충전 콘크리트의 압축강도 수준에 따른 수화발열 특성
최연왕(Choi Yun Wang),정재권(Jung Jea Gwone),이재남(Lee Jae Nam),김병권(Kim Byoung Kwon) 대한토목학회 2009 대한토목학회논문집 A Vol.29 No.5A
본 연구에서는 강도수준(30, 50 및 70 ㎫)에 따른 고유동 자기충전 콘크리트의 수화발열 특성을 알아보기 위하여 2성분계 및 3성분계 고유동 자기충전 콘크리트를 제조하여 일반콘크리트와 수화열, 응결 및 역학적 특성을 분석 고찰 하였으며, 콘크리트에 사용된 분체에 대한 미소수화열량을 측정하여 얻은 분체의 열특성값, 간이단열온도실험을 실시하여 얻은 콘크리트의 열특성값 및 콘크리트에 사용된 재료의 일반적인 열특성값을 간편한 방법의 추정식을 이용하여 콘크리트 단열온도를 추정하였다. 또한, 온도해석에 의하여 얻어진 수화열 및 단열온도 특성값을 MIDAS CIVIL 06 프로그램을 이용하여 3차원 온도응력 해석을 실시하여 고유동 자기충전 콘크리트의 수화발열 특성 및 수화열에 의한 온도응력을 분석 고찰하였다. The research analyzes and investigates conventional concrete, hydration heat, set, and mechanical properties by making high flowing self-compacting concretes of binary blend and ternary blend as one of evaluations about the properties of the hydration heat of high flowing self-compacting concrete with a strength of 30, 50, and 70 ㎫. In addition, it estimates concrete adiabatic temperatures by calculating a thermal property value of powder obtained by measuring a heat evolution amount for powder used in concrete, a thermal property value of concrete obtained by conducting a simple adiabatic temperature test, and a normal thermal property value of material used in concrete, using a simple equation. Moreover, it analyzes and investigates the hydration heat property of high flowing self-compacting concrete and the thermal stress caused by hydration heat by conducting a 3D temperature stress analysis for the hydration heat and the adiabatic temperature obtained by temperature analysis, using MIDAS CIVIL 06 program.