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RISS 인기검색어
- 검색키워드
- 저자 : Tawfik A. Saleh (검색결과 3 건)
- 무료
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Mehrez E. El-Naggar,Ola A. Abu Ali,Dalia I. Saleh,K. M. Abu-alnja,Abd-allah M. Mnsour,Mohammed A. Abu-Saied,Tawfik A. Khattab 한국섬유공학회 2022 Fibers and polymers Vol.23 No.6
Despite the fact that Pyrovatex is widely used as a commercial flame-retardant, the release of toxic formaldehyderemains a serious problem. Fluorine-based compounds, on the other hand, have been employed to impart hydrophobic textilesurfaces, although they are exceedingly costly and poisonous. Based on those difficulties, we describe a simple one-stepmethod for coating electrically conductive cotton-nickel (Cot-Ni) blend fabric providing flame-retardant and water-repellentcharacteristics. A nickel ribbon was firstly bent around a cotton yarn as a core, and then woven into an electrically conductiveCot-Ni blend fabric, which was created by weaving the cotton-nikel hybrid threads with regular cotton yarns. The conductivefabric was coated with a composite consisting of silicone rubber (RTV) and ammonium polyphosphate (APP). The strongbinding of RTV with both APP and cotton fibres increased the flame-retardant action of cotton, according to the findings. Asa result, varied concentrations of APP were used in the composite to show that only 100 g/l of APP combined with RTVimproved the fire-retardancy. Depending on the concentration of APP, distinct hierarchical morphologies appeared on thesurface of the coated Cot-Ni fabrics. RTV also improved the hydrophobic character of the blend surface. Measurements of airpermeability, surface roughness, and stiffness were used to investigate the comfort qualities of the coated Cot-Ni blends. Eventually, those multifunctional (Cot-Ni)/RTV-APP textiles might be used in a variety of applications, such as grain storagecontainers, car seat mats, and firefighters' uniforms.
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Rahmat Hidayat,Rahmat Hidayat,Tawfik A. Saleh 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
Water purification is a global issue, and most traditional methods have several drawbacks. As a result,new methods and materials must be devised to address the problem of water filtration. The hydrophobicTiO2-ZnO/rGO has been synthesized via single-step hydrothermal methods for the efficiency and effectiveindigo carmine (IC) solution degradation. The characterization of hydrophobic TiO2-ZnO/rGO has shownthat the material has a high contact angle value of around 103.6. Several photocatalytic parameters, pHof IC solution, the dosage of catalyst, and light intensity, were optimized for obtaining the highest degradationefficiency. The results of the photocatalytic study showed that the IC dye degradation process wascontrolled by superoxide anion radical (O2 radicals) to produce more specific products. Modificationswith hydrophobic compounds such as hexamethyldisilizane (HDMS) showed that they could increasethe photocatalytic properties and reusability of the material with a degradation percentage value of upto 95% with a constant rate of 0.0361 min1. Based on these results, this material has the potential tobe further developed for micro and complex photodegradation and self-cleaning materials.
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Microwave-assisted synthesis of novel porous organic polymers for effective selective capture of CO2
Ahmed M. Alloush,Hamza Abdulghani,Hassan A. Amasha,Tawfik A. Saleh,Othman Charles S. Al Hamouz 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
Performing carbon dioxide (CO2) capture in an environmentally benign and cost-effective way is challengingowing to several factors including selectivity. Thus, the development of polymers that providehigh capacity and selectivity for the removal of CO2 gas is important. N-based porous polymers arepromising for CO2 capture due to their abundant porosity, variable surface characteristics, and great stability. Herein, porous organic polymers were synthesized by microwave-assisted Freidel-Crafts alkylationof 2,20-bipyridine and pyrrole with dimethoxymethane as a cross-linker. The synthesized polymers werecharacterized by Fourier transform infrared, nuclear magnetic resonance, thermogravimetric analyzers,and surface analyzers based on Brunauer–Emmett–Teller theory (BET). The porous polymers exhibitedhigh surface areas of 580 – 930 m2/g. The polymers showed high ideal adsorbed solution theory (IAST)selectivity of 53 – 63 toward CO2 over N2 at 1 bar and 298 K under flue gas composition. Whereas theselectivity toward CO2 over CH4 at 1 bar and 298 K under natural gas composition was 12 – 18. The synthesizedpolymers achieved exceptional H2O adsorption capacity at P/P0 = 0.9 and 293 K of 35 – 45 mmol/g. The results reveal the polymers provide promising candidates for the CO2 capture from various mixtures,such as flue gas and natural gas.
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