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- 저자 : Ahmed M. Alloush (검색결과 1 건)
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Microwave-assisted synthesis of novel porous organic polymers for effective selective capture of CO2
Ahmed M. Alloush,Hamza Abdulghani,Hassan A. Amasha,Tawfik A. Saleh,Othman Charles S. Al Hamouz 한국공업화학회 2022 Journal of Industrial and Engineering Chemistry Vol.113 No.-
Performing carbon dioxide (CO2) capture in an environmentally benign and cost-effective way is challengingowing to several factors including selectivity. Thus, the development of polymers that providehigh capacity and selectivity for the removal of CO2 gas is important. N-based porous polymers arepromising for CO2 capture due to their abundant porosity, variable surface characteristics, and great stability. Herein, porous organic polymers were synthesized by microwave-assisted Freidel-Crafts alkylationof 2,20-bipyridine and pyrrole with dimethoxymethane as a cross-linker. The synthesized polymers werecharacterized by Fourier transform infrared, nuclear magnetic resonance, thermogravimetric analyzers,and surface analyzers based on Brunauer–Emmett–Teller theory (BET). The porous polymers exhibitedhigh surface areas of 580 – 930 m2/g. The polymers showed high ideal adsorbed solution theory (IAST)selectivity of 53 – 63 toward CO2 over N2 at 1 bar and 298 K under flue gas composition. Whereas theselectivity toward CO2 over CH4 at 1 bar and 298 K under natural gas composition was 12 – 18. The synthesizedpolymers achieved exceptional H2O adsorption capacity at P/P0 = 0.9 and 293 K of 35 – 45 mmol/g. The results reveal the polymers provide promising candidates for the CO2 capture from various mixtures,such as flue gas and natural gas.
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