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Thanh, T.D.,Nan, W.Z.,Nam, G.,Van, H.T.,You, T.S.,Phan, T.L.,Yu, S.C. Elsevier 2015 CURRENT APPLIED PHYSICS Vol.15 No.10
A systematic study of the conventional and inverse magnetocaloric effects, and critical behaviors in an alloy ingot of Ni<SUB>43</SUB>Mn<SUB>46</SUB>Sn<SUB>8</SUB>In<SUB>3</SUB> has been performed. Our results reveal the sample exhibiting structural and magnetic phase transitions at temperatures T<SUB>C</SUB><SUP>M</SUP> = 166 K (T<SUB>C</SUB> of the martensitic phase), T<SUB>M-A</SUB> = 260 K (the martensitic-to-austenitic phase transformation) and T<SUB>C</SUB><SUP>A</SUP> = 296 K (T<SUB>C</SUB> of the austenitic phase). The large values of refrigerant capacity (RC) around T<SUB>M-A</SUB> and T<SUB>C</SUB><SUP>A</SUP> are found to be RC<SUB>M-A</SUB> = 172.6 and RC<SUB>A</SUB> = 155.9 J kg<SUP>-1</SUP>, respectively, under an applied field change of 30 kOe. Our critical analyses near the T<SUB>C</SUB><SUP>M</SUP> and T<SUB>C</SUB><SUP>A</SUP> reveal that a coexistence of the long- and short-range ferromagnetic order in the martensitic phase, while the long-range ferromagnetic order exists in the austenitic phase. Interestingly, at around T<SUB>C</SUB><SUP>A</SUP>, the maximum magnetic entropy change (|ΔS<SUB>max</SUB>|) versus magnetic field H obeys a power law, |ΔS<SUB>max</SUB>| = a.H<SUP>n</SUP>, where the exponent n is found to be about 0.66.
Tran Dang Thanh,Phan, T. L.,Phung Quoc Thanh,Hoang Nam Nhat,Duong Anh Tuan,Yu, S. C. IEEE 2014 IEEE transactions on magnetics Vol.50 No.6
<P>This paper presents a detailed study on the Co-doping influence on the electrical and magnetotransport properties of La0.7Ca0.3Mn1-xCoxO3(x = 0.09-0.17) prepared by solid-state reaction. Magnetic measurements versus temperature revealed a gradual decrease of the magnetization (M) and Curie temperature (T-C) with increasing Co concentration (x). The T-C values vary from 194 to 159 K as changing x from 0.09 to 0.17, respectively. H/M versus M-2 performances around T-C prove the x = 0.09 sample undergoing a first-order magnetic phase transition (FOMT) while the samples with x >= 0.11 undergo a second-order magnetic phase transition (SOMT). The other with x = 0.10 is considered as a threshold concentration of the FOMT-SOMT transformation. Considering temperature dependences of resistivity, rho(T), in the presence and absence of the magnetic field, the samples (excepting for x = 0.17) exhibit a metal-insulator transition at T (P) = 60-160 K, which shifts toward lower temperatures with increasing x. In the metallic-ferromagnetic region, the rho(T) data are well fitted to a power function rho(T) = rho(0) + rho(2) T-2 + rho(4.5) T-4.5. This indicates electron-electron and electron-magnon scattering processes are dominant at temperatures T < T (P). In addition, the conduction data at temperatures T > theta(D)/2 (theta(D) is the Debye temperature) and T (P) < T < theta(D)/2 obey the small-polaron and variable-range hopping models, respectively. The values of activation energy E-p, and density of states at the Fermi level N(E-F) were accordingly determined. Here, N(E-F) increases while E-p decreases when an external magnetic field is applied. We also have found that N(E-F) increases when materials transfer from the FOMT to the SOMT, and N(E-F) value becomes smallest for the sample having the coexistence of the FOMT and SOMT (i.e., x = 0.10).</P>
Phuong T.M. Ha,Binh T.T. Le,Trung C. To,Son H. Doan,Tung T. Nguyen,Nam T.S. Phan 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.54 No.-
Iron-organic framework Fe3O(BPDC)3 was synthesized, and subsequently utilized as an productive heterogeneous catalyst for the cyclization reaction of N,N-dialkylanilines with ketoxime carboxylates to produce aryl-substituted pyridines. This iron-organic framework catalyst demonstrated remarkably higher catalytic productivity for the synthesis of aryl-substituted pyridines as compared to numerous conventional homogeneous catalysts as well as MOF-based catalysts. It was possible to reuse the iron- framework catalyst in the cyclization transformation for numerous cycles without a noticeable decline in activity. To our best knowledge, this is the first heterogeneous catalytic approach towards the synthesis of aryl-substituted pyridines from ketoximes.
Khoa D. Nguyen,Son H. Doan,Anh N.V. Ngo,Tung T. Nguyen,Nam T.S. Phan 한국공업화학회 2016 Journal of Industrial and Engineering Chemistry Vol.44 No.-
A metal–organic framework Fe3O(BPDC)3 was synthesized, and used as a productive heterogeneouscatalyst for the direct C–N coupling of azoles with ethers via oxidative C–H activation to produce azolederivatives. The MOF-based catalyst displayed higher catalytic efficiency than many homogeneouscatalysts as well as several MOFs in the transformation. The MOF-based catalyst could be reused manytimes for the synthesis of azole derivatives by the direct C–N coupling of azoles with ethers without anoteworthy deterioration in catalytic efficiency. To the best of our knowledge, this direct C–N couplingreaction was not previously performed in the presence of heterogeneous catalysts.
Khang X. Nguyen,Phuc H. Pham,An C.D. Nguyen,Chuc T. Nguyen,Tung T. Nguyen,Phong D. Tran,Nam T.S. Phan 한국공업화학회 2020 Journal of Industrial and Engineering Chemistry Vol.92 No.-
A Fe-Mo-Se nanopowder, synthesized by a solvothermal protocol, was utilized as a heterogeneouscatalyst for the synthesis of 2-arylquinazolines from DL-α-phenylglycine-based α-amino acids and2-nitrobenzyl alcohols via domino transformations. High yields and selectivity were achieved undersolvent-free conditions. The Fe-Mo-Se catalyst offered considerably higher activity than numeroushomogeneous and heterogeneous catalysts. To our best knowledge, this domino reaction is new, and theutilization of iron-molybdenum selenide catalyst in the synthesis of quinazolines was not previouslyreported.
Yen H. Vo,Thanh V. Le,Hieu D. Nguyen,Tuong A. To,Hiep Q. Ha,Anh T. Nguyen,Anh N.Q. Phan,Nam T.S. Phan 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.64 No.-
Zirconium-based metal-organic framework MOF-808 was synthesized, and sulfated with aqueous sulfuric acid. Sulfated MOF-808 was utilized as a recyclable heterogeneous catalyst for the synthesis of quinazolinones from β-ketoesters and benzamides, and for the synthesis of benzimidazoles from β-ketoesters and o-phenylenediamines in glycerol as a green solvent. The sulfated MOF-808 catalyst was more active than many heterogeneous and homogeneous catalysts. The combination of the sulfated MOF-808 and glycerol was also effective for the reaction of o-aminothiophenols with β-diketones or cyclic β-diketones to produce benzothiazoles. To our best knowledge, MOF-based catalysts were not previously utilized as heterogeneous catalyst in glycerol as green solvent.