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Rashid Md Al Mamunur,Kim Junkyu,Long Dang Xuan,Kwak Kyungwon,Hong Jongin 대한화학회 2022 Bulletin of the Korean Chemical Society Vol.43 No.5
Density functional theory (DFT), time-dependent DFT, and Marcus theory were used to probe the optoelectronic and charge-transport properties of compounds obtained by inserting long-chain aliphatic alkenes or condensed aromatic rings between the planar quinacridone core and the terminal donor diphenylamine moiety of a reference hole-transporting material (HTM). Compared to the reference HTM, its newly designed derivatives showed lower-lying highest occupied molecular orbitals that were well matched in energy with the valence band maximum of a representative perovskite absorber. HTMs obtained via the insertion of condensed aromatic rings showed higher hole mobilities than those obtained via the insertion of aliphatic alkenes. Overall, hole mobility was mainly influenced by the charge-transfer integral, while other factors, such as the hole reorganization energy, hole hopping rate, and centroid distance, had only minor effects.
Long, Dang Xuan,Noh, Yong-Young American Scientific Publishers 2017 Journal of nanoscience and nanotechnology Vol.17 No.8
<P>We report on high-performance organic field-effect transistors (OFETs) with low-cost Mo source/drain electrode by water base solution-processed hybrid PEI:V2O5 interlayers. We were success control of the metal electrode's work function (W-f) by ratio of mixture of contact interlayers and obtain the work function of the Mo electrodes progressively changed from 4.16 to 4.9 eV to reduce energy barriers of ambipolar semiconductor. With the insertion of the mixed layer, OFETs gained significantly improved performance for ambipolar 3,6-Bis-(5bromo-thiophen-2-yl)-N, N-bis (2-octyl-1-dodecyl)-1,4-dioxo-pyrrolo[3,4-c]pyrrole (DPPT-TT) polymer semiconductors, OFETs on the basis DPPT-TT with hybid mixed interlayer/Mo electrodes exhibit field-effect mobilities of 0.8 and 1.9 cm(2)/Vs for electron and hole mobility, respectively.</P>
Long, Dang Xuan,Karakawa, Makoto,Noh, Yong-Young The Royal Society of Chemistry 2016 Physical chemistry chemical physics Vol.18 No.34
<P>The high performance of soluble [60]fulleropyrrolidine upon its use as the active layer of n-channel organic field-effect transistors (OFETs) is reported. The two materials, N-phenyl derivatives C60-fused-N-phenyl-2-phenylpyrrolidine ([C60]PhNPh) and C60-fused N-phenyl-2-hexylpyrrolidine ([C60]HexNPh), have well-controlled molecular structures with a modification of the pyrrolidine ring, with no increase in the LUMO level, achieving a high mobility and highly ambient stable n-type OFET. The top-gate, bottom-contact device shows a high electron charge-carrier mobility of up to 0.14 and 0.08 cm(2) V-1 s(-1) for [C60]PhNPh and [C60]HexNPh, respectively, (I-on/I-off = 10(6)) with the commonly used CYTOP dielectric. Excess carriers introduced by a small amount of chemical doping of polyethyleneimine (PEI) compensate traps by shifting the Fermi level (E-F) toward the respective transport energy levels and therefore increase charge-carrier mobility (0.26 and 0.1 cm(2) V-1 s(-1)) and provide good ambient operational stability compared with pristine devices.</P>
Baking soda: an ultra-cheap and air stable electron injection layer for organic electronic devices
Long, Dang Xuan,Noh, Yong-Young The Royal Society of Chemistry 2018 Journal of materials chemistry. C, Materials for o Vol.6 No.47
<P>To realize high performance printed organic optoelectronic devices, the development of air-stable, cheap, and solution-processable electron injection layers (EILs) is urgently required to avoid the use of a low work-function metal electrode with poor air stability. We report sodium bicarbonate (baking soda, NaHCO3) as an efficient, low-cost, air-stable, and environmentally friendly EIL material in various printed organic electronic devices including organic solar cells (OSCs), organic light-emitting diodes (OLEDs), organic photodiodes (OPDs) and n-channel organic thin film transistors (OFETs). UV photoelectron spectroscopy results indicated that the work-function of various common electrodes used for organic devices such as ITO, Au, Al and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) decreased significantly by more than 1 eV following deposition of a thin NaHCO3 film. The performance and stability of these organic devices improved by around 15% overall with ultra-cheap, air stable EILs. In particular, high performance OSCs based on PTB7:PC71BM with a power conversion efficiency of 8.40% and solution processed OLEDs based on PVK:PBD:Ir(ppy)3 with light emitting efficiencies of 68.5 cd A<SUP>−1</SUP> and 20 lm A<SUP>−1</SUP> were achieved by applying a NaHCO3 interlayer.</P>
Long, Dang Xuan,Choi, Eun-Young,Noh, Yong-Young American Chemical Society 2017 ACS APPLIED MATERIALS & INTERFACES Vol.9 No.29
<P>We report a new p-type dopant, manganese oxide (Mn3O4) nanoparticle, to enhance the performance of organic field-effect transistors (OFETs) with conjugated polymers, including poly(3-hexylthiophene-2,5-diyl), poly[[N,N 9-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diyl]-alt-5,59-(2,29-bithiophene)], and poly[[2,5-bis(2-octyldodecyl)-2,3,5,6-tetrahydro-3,6-dioxopyrrolo[3,4-c]pyrrole-1,4-diyl]-alt-[[2,2'-(2,5-thiophene)bis-thieno(3,2b) thiophene]-5,5'-diyl]] (DPPT-TT). Incorporating a small amount of Mn3O4 nanoparticles in the semiconductor film significantly improved the hole mobility and decreased the threshold voltage for all OFETs, indicating efficient Mn3O4 nanoparticle p-type doping. The Mn3O4 nanoparticle showed a better doping efficiency than the widely used FeCl3 dopant due to better mixability with the host conjugated polymers. In particular, doped DPPT-TT OFETs showed significantly improved mobility up to 2.35 (+/- 0.4) cm(2)/(V.s) with enhanced air and operational stability at 0.1 wt % doping concentration from 1.2 cm(2)/(V.s) for pristine devices.</P>
Long-Xuan Zhao,박형근,주상섭,Mi Kyeong Lee,Young Choong Kim,Pritam Thapa,Radha Karki,장영동,정병선,이응석 대한화학회 2007 Bulletin of the Korean Chemical Society Vol.28 No.6
For the development of novel hepatoprotective agents, C11, C28, C2,3,23 or C2,23,28 functional groups on asiatic acid were modified, and their hepatoprotective effects were evaluated. Most of the prepared compounds displayed potent hepatoprotective activities against CCl4- and galactosamine (GaIN)-induced hepatotoxicity. Especially, compounds 16 and 20 showed the most significant hepatoprotective effects against GaIN-induced hepatotoxicity (54.2% and 46.4% protection at 50 mM, respectively).
Synthesis, Cytotoxicity and Structure-Activity Relationship Study of Terpyridines
Long-Xuan Zhao,Jyoti Sherchan,Jung Ki Park,장영동,정병선,정태천,이종순,이응석 대한약학회 2006 Archives of Pharmacal Research Vol.29 No.12
For the development of novel antitumor agents, we designed and synthesized terpyridines, and their biological activities were evaluated. Although most of the newly prepared terpyridines showed strong cytotoxicity against several human cancer cell lines, [2,2';6',2'']-terpyridine displayed the most significant cytotoxicity.
Gu, Yiren,Zhou, Rui,Jin, Long,Tao, Xuan,Zhong, Zhijun,Yang, Xuemei,Liang, Yan,Yang, Yuekui,Wang, Yan,Chen, Xiaohui,Gong, Jianjun,He, Zhiping,Li, Mingzhou,Lv, Xuebin Asian Australasian Association of Animal Productio 2020 Animal Bioscience Vol.33 No.5
Objective: We investigated the temporal expression profiles of long noncoding RNA (lncRNA) and mRNA in the peripheral blood of pigs during development and identified the lncRNAs that are related to the blood-based immune system. Methods: Peripheral blood samples were obtained from the pigs at 0, 7, 28, and 180 days and 2 years of age. RNA sequencing was performed to survey the lncRNA and mRNA transcriptomes in the samples. Short time-series expression miner (STEM) was used to show temporal expression patterns in the mRNAs and lncRNAs. Gene ontology and Kyoto encyclopedia of genes and genomes analyses were performed to assess the genes' biological relevance. To predict the functions of the identified lncRNAs, we extracted mRNAs that were nearby loci and highly correlated with the lncRNAs. Results: In total of 5,946 lncRNA and 12,354 mRNA transcripts were identified among the samples. STEM showed that most lncRNAs and mRNAs had similar temporal expression patterns during development, indicating the expressional correlation and functional relatedness between them. The five stages were divided into two classes: the suckling period and the late developmental stage. Most genes were expressed at low level during the suckling period, but at higher level during the late stages. Expression of several T-cell-related genes increased continuously during the suckling period, indicating that these genes are crucial for establishing the adaptive immune system in piglets at this stage. Notably, lncRNA TCONS-00086451 may promote blood-based immune system development by upregulating nuclear factor of activated T-cells cytoplasmic 2 expression. Conclusion: This study provides a catalog of porcine peripheral blood-related lncRNAs and mRNAs and reveals the characteristics and temporal expression profiles of these lncRNAs and mRNAs during peripheral blood development from the newborn to adult stages in pigs.
Long, Dang Xuan,Xu, Yong,Wei, Huai-xin,Liu, Chuan,Noh, Yong-Young The Royal Society of Chemistry 2015 Physical chemistry chemical physics Vol.17 No.31
<P>A simply and facilely synthesized MoO<SUB>3</SUB> solution was developed to fabricate charge injection layers for improving the charge-injection properties in p-type organic field-effect transistors (OFETs). By dissolving MoO<SUB>3</SUB> powder in ammonium (NH<SUB>3</SUB>) solvent under an air atmosphere, an intermediate ammonium molybdate ((NH<SUB>4</SUB>)<SUB>2</SUB>MoO<SUB>4</SUB>) precursor is made stable, transparent and spin-coated to form the MoO<SUB>3</SUB> interfacial layers, the thickness and morphology of which can be well-controlled. When the MoO<SUB>3</SUB> layer was applied to OFETs with a cost-effective molybdenum (Mo) electrode, the field-effect mobility (<I>μ</I><SUB>FET</SUB>) was significantly improved to 0.17 or 1.85 cm<SUP>2</SUP> V<SUP>−1</SUP>s<SUP>−1</SUP> for polymer semiconductors, regioregular poly(3-hexylthiophene) (P3HT) or 3,6-bis-(5bromo-thiophen-2-yl)-<I>N</I>,<I>N</I>′-bis(2-octyl-1-dodecyl)-1,4-dioxo-pyrrolo[3,4-<I>c</I>]pyrrole (DPPT-TT), respectively. Device analysis indicates that the MoO<SUB>3</SUB>-deposited Mo contact exhibits a contact resistance <I>R</I><SUB>C</SUB> of 1.2 MΩ cm comparable to that in a device with the noble Au electrode. Kelvin-probe measurements show that the work function of the Mo electrode did not exhibit a dependence on the thickness of MoO<SUB>3</SUB> film. Instead, ultraviolet photoemission spectroscopy results show that a doping effect is probably induced by casting the MoO<SUB>3</SUB> layer on the P3HT semiconductor, which leads to the improved hole injection.</P> <P>Graphic Abstract</P><P>A simply synthesized MoO<SUB>3</SUB> is used as charge injection layers for printed p-type organic field-effect transistors (OFETs). <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c5cp03369a'> </P>