http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Synthesis and Solution Properties of Fluorinated Amphiphilic Polyacrylamide
Fangyuan Zhao,Kai Du,Zhuo Yi,Chao Du,Zhao Fang,Bingquan Mao 한국고분자학회 2015 폴리머 Vol.39 No.3
A series of hydrophobically associating fluorinated amphiphilic polyacrylamide copolymers with remarkably high heat resistance and salt tolerance were synthesized by free radical micellar copolymerization, using acrylamide (AM) and sodium 2-acrylamido-tetradecane sulfonate (AMC14S) as amphiphilic monomers, and 2-(perfluorooctyl) ethyl acrylate (PFHEA) as hydrophobic monomer. The structure of the terpolymer was characterized by FTIR, <SUP>1</SUP>H NMR and <SUP>19</SUP>F NMR. The solution properties of the terpolymers were investigated in details, and the results showed that the terpolymer solution had strong intermolecular hydrophobic association as the concentration exceeded the critical association concentration 1.5 g/L. The terpolymer solution possessed high surface activity, viscoelasticity, excellent heat resistance, salt tolerance and shearing resistance. The viscosity retention rate of copolymer solution was as high as 59.9% under the condition of fresh wastewater, 85℃ and a 60-days aging test.
Wang, Shuaifei,Li, Fangyuan,Qiao, Ruirui,Hu, Xi,Liao, Hongwei,Chen, Lumin,Wu, Jiahe,Wu, Haibin,Zhao, Meng,Liu, Jianan,Chen, Rui,Ma, Xibo,Kim, Dokyoon,Sun, Jihong,Davis, Thomas P.,Chen, Chunying,Tian, American Chemical Society 2018 ACS NANO Vol.12 No.12
<P>Ferroptosis, an iron-based cell-death pathway, has recently attracted great attention owing to its effectiveness in killing cancer cells. Previous investigations focused on the development of iron-based nanomaterials to induce ferroptosis in cancer cells by the up-regulation of reactive oxygen species (ROS) generated by the well-known Fenton reaction. Herein, we report a ferroptosis-inducing agent based on arginine-rich manganese silicate nanobubbles (AMSNs) that possess highly efficient glutathione (GSH) depletion ability and thereby induce ferroptosis by the inactivation of glutathione-dependent peroxidases 4 (GPX4). The AMSNs were synthesized <I>via</I> a one-pot reaction with arginine (Arg) as the surface ligand for tumor homing. Subsequently, a significant tumor suppression effect can be achieved by GSH depletion-induced ferroptosis. Moreover, the degradation of AMSNs during the GSH depletion contributed to <I>T</I><SUB>1</SUB>-weighted magnetic resonance imaging (MRI) enhancement as well as on-demand chemotherapeutic drug release for synergistic cancer therapy. We anticipate that the GSH-depletion-induced ferroptosis strategy by using manganese-based nanomaterials would provide insights in designing nanomedicines for tumor-targeted theranostics.</P> [FIG OMISSION]</BR>
Untargeted metabolite profiling of serum in rats exposed to pyrraline
Chuanqin Hu,Jiahui Wang,Fangyuan Qi,Yingli Liu,Fen Zhao,Jing Wang,Baoguo Sun 한국식품과학회 2023 Food Science and Biotechnology Vol.32 No.11
Pyrraline, one of advanced glycation end-products, is formed in advanced Maillard reactions. It was reported that the presence of pyrraline was tested to be associated with nephropathy and diabetes. Pyrraline might result in potential health risks because many modern diets are heat processed. In the study, an integrated metabolomics by ultra-high-performance liquid chromatography with mass spectrometry was used to evaluate the effects of pyrraline on metabolism in rats. Thirty-two metabolites were identified as differential metabolites. Linolenic acid metabolism, phenylalanine, tyrosine and tryptophan biosynthesis, arachidonic acid metabolism, tyrosine metabolism and glycerophospholipid metabolism were the main perturbed networks in this pathological process. Differential metabolites and metabolic pathways we found give new insights into studying the toxic molecular mechanisms of pyrraline.
Study on surface physical and chemical mechanism of nanobubble enhanced flotation of fine graphite
Tang Chongliang,Ma Fangyuan,Wu Tingyu,Zhang Di,Wang Ye,Zhao Tonglin,Fan Zhaolin,Liu Xinyue 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.122 No.-
It has been concluded in a recently published investigation that the nanobubble flotation process significantlyreduces the number of fine flake graphite flotation stages and improves the flotation performance. The present study was conducted to explore the mechanisms of surface nanobubbles enhancing flake graphiteflotation by investigating effects of nanobubbles on surface properties of graphite and interactionsbetween particles and bubbles by use of contact angle analyzer, zeta potential analyzer, FourierTransform Infrared Spectroscopy (FTIR), and X-ray Photoelectron Spectroscopy (XPS). The study resultsshow that nanobubbles can improve the surface properties of graphite and enhance the adsorption effectof collector, which increased the contact angle of the graphite surface by 11.93 compared with conventionalflotation. Infrared spectroscopy and potential analysis showed that the nanobubbles could enhancethe hydrophobic attraction and reduce the electrostatic repulsion between the collector and the graphitesurface, which was beneficial to enhance the hydrophobic surface of the graphite and enhance theagglomeration of fine graphite particles. XPS analysis showed that the nanobubbles covered polar hydrophilicgroups (such as CAO, C@O, COOH) on the graphite surface, which enhanced the adsorption of collectorto improve the hydrophobicity of graphite surface.
Kai Wu,Jiangpeng Zhai,Jianyang Xue,Fangyuan Xu,Hongtie Zhao 사단법인 한국계산역학회 2019 Computers and Concrete, An International Journal Vol.23 No.5
A low-cycle loading experiment of 16 transfer column specimens was conducted to study the influence of parameters, likes the extension length of shape steel, the ratio of shape steel, the axial compression ratio and the volumetric ratio of stirrups, on the shear distribution between steel and concrete, the concrete damage state and the degradation of lateral stiffness. Shear force of shape steel reacted at the core area of concrete section and led to tension effect which accelerated the damage of concrete. At the same time, the damage of concrete diminished its shear capacity and resulted in the shear enlargement of shape steel. The interplay between concrete damage and shear force of shape steel ultimately made for the failures of transfer columns. With the increase of extension length, the lateral stiffness first increases and then decreases, but the stiffness degradation gets faster; With the increase of steel ratio, the lateral stiffness remains the same, but the degradation gets faster; With the increase of the axial compression ratio, the lateral stiffness increases, and the degradation is more significant. Using more stirrups can effectively restrain the development of cracks and increase the lateral stiffness at the yielding point. Also, a formula for calculating the yielding lateral stiffness is obtained by a regression analysis of the test data.