In situ synthesis NiO/F-MWCNTs nanocomposite for adsorption of malachite green dye from polluted water

Alwan Salam Hussein,Alshamsi Hassan Abbas 한국탄소학회 2022 Carbon Letters Vol.32 No.4

The presence of dyes in water is the most popular problem recently, so the current study was directed towards the synthesis of an effective material consisting of NiO and MWCNTs. The NiO/F-MWCNTs nanocomposite was synthesized using a simple hydrothermal method after functionalization of MWCNTs using sulfuric acid and nitric acid and utilized as an efficient surface to adsorption of malachite green dye from polluted water. The nanocomposite sample was characterized using several techniques are X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis (TGA), Field emission scanning electron microscopy (FESEM), High- resolution transmission electron microscopy (HRTEM), Brunauer–Emmett–Teller (BET) surface area analysis, Barrett-Joyner-Halenda (BJH) analysis and Energy dispersive X-ray (EDX). The analytical results showed that the prepared nanocomposite is of good crystalline nature with a particle size of 25.43 nm. A significant specific surface area was 412.08 m2/g which indicates the effective impact of the nanocomposite in the adsorption of malachite green (MG) dye. On the other hand, the effect of adsorbent dose, temperature, acidic function and contact time on the adsorption efficiency of dye was studied. The kinetics of dye adsorption were also investigated employing two kinetic models, pseudo-first-order model and pseudo-second-order model. Finally, the thermodynamic functions were determined to identify the type of the reaction and the spontaneity of the process.

How Total Quality Management Mediates Antecedent Variables of Employee Performance?

KUSTONO, Alwan Sri Korea Distribution Science Association 2020 The Journal of Asian Finance, Economics and Busine Vol.7 No.12

The research objective was to find out how Total Quality Management (TQM) mediates antecedents of employee performance variables? The research was conducted with a quantitative approach while the research design was cross sectional. The research model was tested using the structural equation modeling approach with partial least square analysis tools to test the influence among research variables. The research sample consisted of 315 respondents who answered a questionnaire in August-September 2019 at manufacturing companies in East Java. The results showed that situational leadership did not affect employee performance, but did affect the successful implementation of TQM. The performance measurement system has no direct effect on employee performance. The performance measurement system has a direct effect on employee performance. Organizational culture has a direct effect on both employee performance and the application of TQM, so that the application of TQM can improve employee performance. TQM implementation variable acts as a mediation between situational leadership and organizational culture on employee performance. The relationship that was originally a direct influence turned into an indirect effect through TQM. The TQM variable is not proven to be an intervening variable between the performance measurement system and employee performance. There is a direct relationship between these two variables.

Earnings Quality and Income Smoothing Motives: Evidence from Indonesia

KUSTONO, Alwan Sri,ROZIQ, Ahmad,NANGGALA, Ardhya Yudistira Adi Korea Distribution Science Association 2021 The Journal of Asian Finance, Economics and Busine Vol.8 No.2

Earnings management is very important for companies that aim for decision-making. The research was conducted to analyze the quality of earnings and income smoothing motives in manufacturing companies in Indonesia. The research approach is carried out with a quantitative approach. The sampling method using purposive sampling was associated with several criteria so that a sample of 130 was determined, which was analyzed during the 4 years of the study. The partial least square method was used for data analysis. The results of the study state that institutional ownership has no effect on earnings quality, institutional ownership has a negative effect on income smoothing, leverage has a negative effect on income smoothing, independent commissioners have a positive effect on earnings quality as well as independent commissioners have a positive effect on income smoothing. We assume that the tendency of income smoothing can affect the quality of efficient earnings. Meanwhile, income smoothing affects the quality of company earnings. Management that performs income smoothing is more aimed at conveying the company's prospects for generating profits rather than opportunistic motives.

Analytical solution of free vibration of FG beam utilizing different types of beam theories: A comparative study

Hiyam Hazim Saeed AlSaid-Alwan,Mehmet Avcar 사단법인 한국계산역학회 2020 Computers and Concrete, An International Journal Vol.26 No.3

In engineering structures, to having the projected structure to serve all the engineering purposes, the theory to be used during the modeling stage is also of great importance. In the present work, an analytical solution of the free vibration of the beam composed of functionally graded materials (FGMs) is presented utilizing different beam theories. The comparison of supposed beam theory for free vibration of functionally graded (FG) beam is examined. For this aim, Euler-Bernoulli, Rayleigh, Shear, and Timoshenko beam theories are employed. The functionally graded material properties are assumed to vary continuously through the thickness direction of the beam with respect to the volume fraction of constituents. The governing equations of free vibration of FG beams are derived in the frameworks of four beam theories. Resulting equations are solved versus simply supported boundary conditions, analytically. To verify the results, comparisons are carried out with the available results. Parametrical studies are performed for discussing the effects of supposed beam theory, the variation of beam characteristics, and FGM properties on the free vibration of beams. In conclusion, it is found that the interaction between FGM properties and the supposed beam theory is of significance in terms of free vibration of the beams and that different beam theories need to be used depending on the characteristics of the beam in question.

Optimization of accurate controlled formation of Au MNPs via non-thermal microplasma continuous glow discharge within aqueous electrochemical (GDE) method

Khamis Raad A.,Alwan Alwan M.,Dheyab Amer B.,Abdallah Shahad M. 한국물리학회 2021 Current Applied Physics Vol.24 No.-

In this work, micro plasma-induced non-equilibrium liquid chemistry was utilized to synthesize and controlled formation of gold metallic nanoparticles (Au MNPs) by governing the concentration of (HAuCl4). These new approaches based on both plasma and liquid electrolytes contain charged species, and the interactions between the two phases represent a unique combination of physics, chemistry, and materials science. Continuous and stable DC glow discharge was done in home–made cavity to synthesize the definite sizes of (Au MNPs) by means of (3 kV) discharge voltage and (2 mA) discharge current for a period of (7 min) in aqueous solution of HAuCl4 with four different concentrations of about 1 mM, 5 mM, 10 mM and 20 mM at room temperature. The atmospheric pressure plasma discharge between stainless steel capillary tube cathode electrode over the (HAuCl4) solution and platinum plate as an anode dipped in solution for rapid formation of colloidal Au MNPs. Morphology aspects of the synthesized Au MNPs layer were studied by examining the (FE-SEM), HR-TEM images and X-ray difraction (XRD) pattern. Optical features of (Au MNPs) were considered via a UV–Vis beam spectrophotometer. These measurements showed that Au MNPs were organized by governing the concentration of HAuCl4, and uniform Au MNPs with specific exclusive sizes were acquired. Grain size, specific surface area and optical stability of Au MNPs strongly be affected by the HAuCl4 concentrations.

Accurate controlled deposition of silver nanoparticles on porous silicon by drifted ions in electrolytic solution

Mehdi Q. Zayer,Alwan M. Alwan,Ahmed S. Ahmed,Amer B. Dheyab 한국물리학회 2019 Current Applied Physics Vol.19 No.9

In this study, a low-cost, simple, single-step low-voltage operation and a well-controlled method for deposition of uniformed and unique size distributions of silver nanoparticles (AgNPs) on the porous silicon (PS) layer were achieved via controlling the drift velocity of electrons in an aqueous solution of AgNO3. The laser diode of 530 nm and 60 mW/cm2 laser wavelength and illumination power density was employed to prepare PS layer by a laser-assisted etching process. The PS layer was incorporated on the platinum disk cathode electrode, and a stainless steel plate as an anode was employed. Low applied operating voltage of about 3V DC at different drift currents of 10, 20, 30 and 40 mA for 2 min was applied to sustain the drift motion of Ag2+. Structural properties of AgNPs layer were examined via the field emission scanning electron microscope (FE-SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD) pattern. These measurements exposed that AgNPs were adjusted by controlling the drift current, and a uniform AgNPs with specific unique sizes were obtained. Grain size, specific surface area and nucleation sites of metallic AgNPs were intensely influenced by the drift current.

Experimental Investigation of Mechanical and Tribological Characteristics of Al 2024 Matrix Composite Reinforced by Yttrium Oxide Particles

Hamada, Mohanad Lateef,Alwan, Ghazwan Saud,Annaz, Abdulkader Ahmed,Irhayyim, Saif Sabah,Hammood, Hashim Shukur Materials Research Society of Korea 2021 한국재료학회지 Vol.31 No.6

Composite materials offer distinct and unique properties that are not naturally inherited in the individual materials that make them. One of the most attractive composites to manufacture is the aluminum alloy matrix composite, because it usually combines easiness of availability, light weight, strength, and other favorable properties. In the current work, Powder Metallurgy Method (PMM) is used to prepare Al2024 matrix composites reinforced with different mixing ratios of yttrium oxide (Y₂O₃) particles. The tests performed on the composites include physical, mechanical, and tribological, as well as microstructure analysis via optical microscope. The results show that the experimental density slightly decreases while the porosity increases when the reinforcement ratio increases within the selected range of 0 ~ 20 wt%. Besides this, the yield strength, tensile strength, and Vickers hardness increase up to a 10 wt% Y₂O₃ ratio, after which they decline. Moreover, the wear results show that the composite follows the same paradigm for strength and hardness. It is concluded that this composite is ideal for application when higher strength is required from aluminum composites, as well as lighter weight up to certain values of Y₂O₃ ratio.

Predicting Brain Tumor Using Transfer Learning

Mustafa Abdul Salam,Sanaa Taha,Sameh Alahmady,Alwan Mohamed International Journal of Computer ScienceNetwork S 2023 International journal of computer science and netw Vol.23 No.5

Brain tumors can also be an abnormal collection or accumulation of cells in the brain that can be life-threatening due to their ability to invade and metastasize to nearby tissues. Accurate diagnosis is critical to the success of treatment planning, and resonant imaging is the primary diagnostic imaging method used to diagnose brain tumors and their extent. Deep learning methods for computer vision applications have shown significant improvements in recent years, primarily due to the undeniable fact that there is a large amount of data on the market to teach models. Therefore, improvements within the model architecture perform better approximations in the monitored configuration. Tumor classification using these deep learning techniques has made great strides by providing reliable, annotated open data sets. Reduce computational effort and learn specific spatial and temporal relationships. This white paper describes transfer models such as the MobileNet model, VGG19 model, InceptionResNetV2 model, Inception model, and DenseNet201 model. The model uses three different optimizers, Adam, SGD, and RMSprop. Finally, the pre-trained MobileNet with RMSprop optimizer is the best model in this paper, with 0.995 accuracies, 0.99 sensitivity, and 1.00 specificity, while at the same time having the lowest computational cost.

Numerical Study of Fan Coil Heat Exchanger with Copper-Foam

Ahmed M. Hassan,Adil Abbas Alwan,Hameed K. Hamzah 한국유체기계학회 2023 International journal of fluid machinery and syste Vol.16 No.1

Due to its high porosity as well as a high specific surface area, the use of open cell metallic foam in heat transfer applications has received increasing interest. In present study, the dynamic and thermal performance of heat exchanger composed of copper foam incorporated in a fan coil was numerically analyzed. Darcy-Brinkman-Forchheimer model was used to represent the momentum equation inside the metallic foam (a porous medium). A local thermal equilibrium was used to solve the energy equation through the porous medium. Different porosity values were taken during the study, ranging from 0.88 to 0.98, while the velocity of inlet air of the heat exchanger ranged from 1 m/s to 10 m/s. The objective of current study is to compare the thermal and dynamic performance of the heat exchanger affected by several variables such as heat transfer coefficient, friction factor, pressure drop, Colburn factor, and area goodness factor. The results showed that increasing the air inlet velocity will increase the heat transfer coefficient, but on the other hand, increasing the velocity ten times will rise pressure drop from 19.032 Pa to 335.76 Pa. Also, the area goodness factor value will decrease with increasing inlet velocity. Finally, we found that increasing in medium porosity will reduce heat transfer coefficient but increase pressure drop

Determination of Chemical Composition of Gallbladder Stones and their Association with Induction of Cholangiocarcinoma

Hussain, Saad Muhmood,Al-Jashamy, Karim Alwan Asian Pacific Journal of Cancer Prevention 2013 Asian Pacific journal of cancer prevention Vol.14 No.11

Gallstone disease is a major surgical problem in many populations; it is probably related to diet, especially excessive consumption of meat. The objective of this study was to determine the chemical composition of gallstones and their association with neoplastic changes including cholangiocarcinomas in cholecystectomised patients. The chemical composition of gallstones from 40 patients (8 males and 32 females) was analyzed. This is a prospective study performed in Baquba teaching hospital in the period from 1/10/2012 to 1/1/2013 in which we collected the gallstones for the patients who underwent cholecystectomy, whether open or laparoscopic. The stones were classified according to their chemical composition as a mixed stones (MS), and examined using a stone analysis set (chemical qualitative method) for calcium, magnesium, phosphate, uric acid and oxalate which was used reagent for qualitative determination of main individual components of stones. The results of this study showed the highest incidence of gallstones in the age group 40-49 was 13 cases followed by 11, 8 and 4 cases for age groups 30-39, 50-59, 20-29 and 60 and above, respectively. The chemical analysis showed the majority of gallstones were mixed, 38 containing calcium followed by 37 cases with uric acid, 28 with magnesium, and 25 and 22 stones with oxalate and phosphate, respectively. Microscopically, we confirmed neoplastic changes (17.5%) as cholangiocarcinomas (CCCs) (7.55%) and dysplastic cells of carcinoma in situ in 4 (10%), 31 (77.5%) cases were chronic cholecystitis and 2 (5%) cases were acute cholecystitis with empyema out of bile duct disorders patients. In conclusion, majority of cases had mixed gallstones that involved five and four of inorganic chemicals of calcium, magnesium and phosphate, the highest incidence of gallstones in age group 40-49 years old was 13 cases, and neoplastic changes were confirmed (17.5%) including CCCs, (7.5%) and dysplastic cells of carcinoma in situ (10%), while 31 (77.5%) cases were chronic cholecystitis.