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Zhengwei Tang,Aimin Liang,Handong Liang,Jiangwei Zhao,Lin Xu,Jie Zhang 한국고분자학회 2019 Macromolecular Research Vol.27 No.8
This study involves an investigation of the chain transfer reaction of butadiene (Bd) polymerization, under the neodymium tris[bis(2-ethylhexyl)phosphate] (Nd)/diisobutyl aluminum hydride (Al)/ethylaluminum sesquichloride (Cl)/Bd catalytic system. The results show that the chain transfer reaction itself is reversible. Only chain propagation and chain exchange reactions occurred during the later period of polymerization, and there was a linear relationship between the molecular weight and the conversion rate. All polymer chains showed sufficient reactivity to propagate by reacting with the monomer. The degree of the chain transfer reaction can be determined by the amount of Al, and the molecular weight in the synthetic polybutadiene can be accurately designed by the formula Mn=54·Bd/Nd/(0.67Al/Nd-7.17). The catalyst-polymerized butadiene afforded products featuring a relatively narrow molecular weight distribution and a high cis-1,4 stereospecificity. One of these products, polybutadiene rubber, showed narrow distribution in the sample, and exhibited good physical and mechanical properties, low abrasion, and low rolling resistance.
Zihua Hu,Changjiang Qin,Xiaogao Chen,Aimin Tang,Tao Fang,Zhiping Yang,Sheng Luo,Meijiao Mao 한국정밀공학회 2020 International Journal of Precision Engineering and Vol.21 No.8
To extend the tool life of conventional uncoated grinding cemented carbide inserts (CUG inserts) in turning GH4169 nickelbased superalloy, chemical–mechanical polishing (CMP) is applied to appropriately treat the rake face of the CUG insert to address the defects including grinding burn, crack, and thermal deformation. The material removal rate (MRR) and the rake face roughness Ra of YG10 chemical–mechanical polished cemented carbide inserts (CMP inserts) corresponding to the six types of abrasives particles are investigated by applying the single factor method, and the diamond powder is the most suitable to polish YG10 inserts. Thus, CMP parameters are optimized using Taguchi method coupled with both the grey relation analysis and fuzzy inference. Furthermore, the comparison experiments of the cutting performance of the CUG insert and the CMP insert in turning GH4169 are carried out, under the same cutting condition, compared with the CUG insert, the average tool life of the CMP insert is increased by 35.92%. This study demonstrates that the CMP technique is an effective potential method to improve the surface integrity, the cutting performance and the tool life of conventional uncoated grinding cemented carbide inserts & tools in the machining of difficult-to-cut materials.
Cong Mao,Yujie Zhong,Yongle Hu,Weidong Tang,Z. M. Bi,Zhaohong Lei,Changchun Jiang,Aimin Tang 한국정밀공학회 2022 International Journal of Precision Engineering and Vol.9 No.5
Electroplated grinding wheel has significant advantages, such as longer service life, higher removal rate, reduction of preparation work, reapplication of the wheel bub. Then it is an efficient, green and eco-friendly abrasive tool. In order to reveal the mechanism that the service life of the electroplated grinding wheel is increased by pre-quenched substrate, the tensile behavior and interfacial stresses of the laser-discrete-quenched substrate/nickel coating were studied through tensile experiment and simulation. The results show that random initial cracks appear in the nickel coating over the unquenched zone before the tensile experiment. There is an inter-diffusion region at the interface of steel substrate and nickel coating; in comparison with the unquenched zone, the size of the inter-diffusion region in the laser-quenched zone was decreased significantly (e.g., 1.2 μm in comparison with 2.6 μm). In tensile testing, the coating over the pre-quenched specimen remains bonded with the substrate firmly even the fracture occurs. In contrast, the damages in the forms of blistering, stripping and exfoliating occurred in the coating over the unquenched specimen. When a fracture occurs, there is a significant difference of the ultimate strains of quenched and unquenched zones; the ultimate strain of quenched zone is 0.0714, while that of the unquenched zone is 0.1667. At the bonding interface, the pre-quenched specimen ensured the overall shear stress and the maximum normal stress, which are lower than those of unquenched specimen. The initial cracks in pre-quenched specimen propagate during stretching, the effect of the absorbed strain energy reduces strain mismatch between the substrate and coating at the interface, and this improves the bonding strength at the interface of the laser-discrete-quenched specimen significantly.