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설수덕,신동욱,표명수 동아대학교 환경문제연구소 1997 硏究報告 Vol.20 No.1
The chlorination of PTS was reacted at temperature 45~85℃, chlorine flow rate 158~475 cc/min, respectively, and thermal decomposed at flow rate of nitrogen 30 cc/min and heating rate(B) 4~20℃/min, respectively, in a batch reactor. Some conclusions are as follows : 1. The maximum conversion of PTSCI mixture was 81%, the optimum reaction temperature and chlorine flow rate were 65℃ and 316.5 cc/min, respectively. 2. The reaction activation energy of PTSCI and OTSCI were 2,423 kcal/mol and 2,125 kcal/mol. And the reaction order was 0.4 3. The activation energy for decomposition of the PTSCI mixture was 21.4kcal/mol and the reaction was first order. 4. The PTSCI mixture was the best for thermal degradation that was reacted at reaction temperature and chlorine volume were 65℃ and 316.5 cc/min, respectively.