http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Toluene Diisocyanate/KOH 촉매작용에 의한 2-Pyrrolidone의 음이온 중합
정발,권기성,최삼권,유문삼,Bal Jung,Ki Sung Kwon,Sam Kwon Choi,Mun Sam Ryoo 대한화학회 1983 대한화학회지 Vol.27 No.1
TDI (Toluene Diisocyanate)/KOH 촉매작용에 의한 2-pyrrolidone의 음이온 중합에 있어서 TDI / KOH 몰비율, KOH의 농도, 온도 및 시간이 중합에 미치는 영향을 조사하였다. TDI / KOH 몰비율이 0.25일 때 중합속도가 가장 빠르고 전환율도 높았으며, 또 KOH의 농도가 5몰퍼센트일 때 가장 높은 전환율과 점도가 얻어졌다. 중합온도는 $30^{\circ}C$인 경우가 $50^{\circ}C$에 비해 전환율이 높았으며 점도도 높았다. 최소자승법으로 계산하여 구한 중합속도상수($k_p$)의 값은 $30^{\circ}C$일 때 $57.53 {\ell}/mole{\cdot}min$였고, $50^{\circ}C$일 때 $52.36{\ell}/mole{\cdot}min$였다. Anionic polymerization of 2-pyrrolidone was carried out by TDI (Toluene Diisocyanate)/KOH catalysis. The effects of TDI / KOH mole ratio, KOH concentration, temperature and time on polymerization were investigated. It was observed that the highest rate of polymerization and maximum conversion were obtained when TDI / KOH mole ratio was about 0.25. The maximum conversion and the highest viscosity were obtained when the concentration of KOH was 5 mole percent. It was also found that the rate of polymerization and inherent viscosity at $30^{\circ}C$ were higher than those at $50^{\circ}C$. The rate constant ($k_p$) of polymerization was determined by least square method; the values of kp obtained were $57.53{\ell}/mole{\cdot}min\;at\;30^{\circ}C$ and $52.36{\ell}/mole{\cdot}min\;at\;50^{\circ}C$, respectively.
$CO_2$/KOH Catalysis 에 의한 2-Pyrrolidone 과 $\varepsilon$-Caprolactam 의 음이온 중합 (제1보)
정발,최삼권,서길수,Jung Bal,Choi Sam-Kwon,Seo Gil Soo 대한화학회 1976 대한화학회지 Vol.20 No.6
Anionic polymerization of 2-pyrrolidone and ${\varepsilon}$-Caprolactam via $CO_2/KOH catalysis was attempted in order to find reaction condition and physical properties of polymers. In case of polymerization of 2-pyrrolidone, the yield of conversion was increased when the concentration of potassium hydroxide was reached above 8 mole percent. The optimum of CO_2/KOH$ mole ratio was 0.45. It was also found that the polymerization was taking place at moderate temperature which was around $50^{\circ}C$. With regard to polymerization of-caprolactam, the yield of conversion was relatively low at $80^{\circ}C$ to $90^{\circ}C$and higher yield of conversion was obtained at higher temperature between $150^{\circ}C$ to $180^{\circ}C$ regardless of $CO_2/KOH mole ratio. The inherent viscosity of nylon 4 and nylon 6 which was made via CO_2/KOH$ catalysis was measured. The observed inherent viscosity was between 2.0 to 5.0. CO2/KOH catalysis에 의해 2-pyrrolidone과 ${\varepsilon}$-caprolactam의 음이온 중합을 시도하였으며 이 polymer의 물리적 성질을 조사하였다. 2-Pyrrolidone 중합의 경우는, KOH의 농도가 8mole%이상이고 $CO_2/KOH$ mole ratio가 0.45일 때 percent conversion이 가장 높았으며 $50^{\circ}C$가 최적의 온도임을 알았다. ${\varepsilon}$-Carprolactam의 중합에 있어서는 80 ∼ $90^{\circ}C$에서 percent conversion이 낮았고, 150 ∼ $180^{\circ}C$의 온도에서는$ CO_2/KOH$ mole ratio에 크게 관계없이 높은 percent conversion을 얻을 수 있었다. 이들 polymer의 고유점도는 대략 2.0 ∼ 5.0dl/g의 높은 값이었다.
박정학,정발,최삼권,Jung Hag Park,Bal Jung,Sam K. Choi 대한화학회 1980 대한화학회지 Vol.24 No.2
PPBC/KOH 촉매작용에 의한 2-pyrrolidone의 음이온중합에 있어서 PPBC/KOH 몰비, KOH의 농도 및 온도가 중합에 미치는 영향을 조사하였다. PPBC/KOH 몰비가 0.5일때 중합속도가 가장 빠르고 전환율도 가장 높았으며, 또 KOH 의 농도는 2몰%일때 가장 높은 전환율과 점도가 얻어졌다. $50^{\circ}C$에서의 중합은 $30^{\circ}C$에서의 중합보다 초기반응속도는 빠르나 시간이 경과할 수록 전환율과 점도가 오히려 낮아지는 경향이 관찰되었다. 최소자승법으로 계산하여 구한 중합속도상수$(k_p)$의 값은 $30^{\circ}C$일때 $22.4\;l/mole{\cdot}hr$ 였고 $50^{\circ}C$일때 $191.9\;l/mole{\cdot}hr$ 였다. Anionic polymerization of 2-pyrrolidone was carried out via PPBC/KOH catalysis. The effects of PPBC/KOH mole ratio, KOH concentration and temperature on polymerization have been investigated. It was observed that the highest rate of polymerization and maximum conversion were obtained when PPBC/KOH mole ratio was around 0.5. The maximum conversion and the highest viscosity were obtained when the concentration of KOH was 2 mole percent. It was also found that while the rate of polymerization at $50^{\circ}C$ was higher than at $30^{\circ}C$ in the initial stage of polymerization, the conversion and viscosity were decreased as polymerization time was extended. The rate constant $(k_p)$ of polymerization was determined by least square method; the values of $k_p$ obtained were $22.4\;l/mole{\cdot}hr\;at\;30^{\circ}C\;and\;191.9\;l/mole{\cdot}hr\;at\;50^{\circ}C$, respectively.