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N<sub>2</sub>/NF<sub>3</sub> 분리용 폴리썰폰 중공사막 제조 연구
임민수,김성중,강하성,박호범,남승은,박호식,이평수,박유인,Lim, Min Su,Kim, Seong-Joong,Kang, Ha Sung,Park, Ho Bum,Nam, Seung Eun,Park, Ho Sik,Lee, Pyung Soo,Park, You In 한국막학회 2016 멤브레인 Vol.26 No.1
Fabrication of polysulfone (PSf) hollow fiber membranes was investigated for the separation of $N_2/NF_3$ gas mixtures, which are emitted from the display and the semiconductor industries. A combination of the non-solvent induced phase separation (NIPS) and the vapor-induced phase separation (VIPS) technique was applied to develop high flux hollow fiber membranes. Thin polymer layers were further coated onto the surface of the hollow fiber membranes by using polydimethylsiloxiane (PDMS) or Teflon AF1600(R), which contributes to improve the $N_2/NF_3$ selectivity. The $N_2/NF_3$ separation performances of our PSf hollow fiber membranes were determined by the intrinsic properties of coating materials. Especially, the PSf hollow fiber membrane coated with Teflon AF 1600(R) exhibited a higher $N_2/NF_3$ selectivity (> 14) with a slightly lower $N_2$ permeance (4.5 GPU), as compared to the commercial PSf counterparts. This feature provides a good potential as a membrane structure to separate $N_2/NF_3$. 반도체 및 디스플레이 공정에서 배출되는 $N_2/NF_3$ 혼합 가스 분리를 위한 폴리썰폰 중공사막 제조 연구를 수행하였다. 먼저 non-solvent induced phase separation (NIPS)와 vapor induced phase separation (VIPS) 혼합 공정을 이용하여 기체투과성이 높은 고분자 중공사막을 제조하였다. 제조된 중공사막 표면에 PDMS(polydimethylsiloxiane)와 Teflon AF1600(R) 고분자 소재를 이용하여 얇은 박막을 추가적으로 코팅하는 방법으로 기체 분리막을 완성하였다. 제조된 분리막은 코팅된 고분자 소재의 기체 분리 특성에 따라 상이한 $N_2/NF_3$ 분리 성능을 보여주었다. 특히 Teflon AF1600(R) 이 코팅된 중공사막의 경우 $N_2/NF_3$ 분리 성능(> 14)을 보여주었고, $N_2$ 투과도는 4.5 GPU를 나타내었다. 상용 폴리썰폰 막과 비교해 볼 때, 투과도는 약간 감소하였지만 기체 선택도는 크게 증가하였다. 이런 특징은 $N_2/NF_3$를 분리하는 분리막 구조로써 큰 가능성을 지니는 것으로 판단된다.
김동언(Kim, Dong-Eon),이홍기(Lee, Hong-Gi),한홍식(Han, Hong-Sik),정영규(Jung, Yung-Gyu),서형석(Suh, Hyung-Suck),정진화(Chung, Chin-Wha),임민수(Lim, Min-Soo),곽승근(Kwak, Seung-Keun),오만수(Oh, Man-Soo),최준혁(Choi, June-Hyuk) 한국신재생에너지학회 2008 한국신재생에너지학회 학술대회논문집 Vol.2008 No.05
Pohang Wind Energy Research Center (PoWER-C) is developing a 3 MW Radial Flux Permanent Magnet (RFPM) Synchronous Generator for offshore Wind Energy Converter (WEC). The blade rotor rpm is 15.7 and the gear ratio is set to be 92.93. The nominal generator rpm at the rated load is about 1459. Baseline design with surface mounted PM magnets are completed. However, there is some concern about the excessive eddy current heating in the magnets. To alleviate this problem, another design with embedded magnet is going on. With embedded magnets, the generator length should be increased to compensate the increased flux leakage. But the field fluctuation in the magnets due to the slots are greatly reduced. This means less eddy currents and lower magnet operating temperature. In this report, engineering efforts for embedded rotor is presented.