치형오차를 가진 헬리컬기어의 진동특성에 관한 연구

박찬일,이장무,Park, Chan-Il,Lee, Jang-Moo 대한기계학회 1996 大韓機械學會論文集A Vol.20 No.5

Gear vibration is caused by the mesh stiffness, gear accuracy, and assembling errors. For these reasons, helical gear has the azial, radial, and rotational vibrations. In this study, the mesh stiffness is calculated by considering the tooth bending, contact, and foundation deformations. Rotational vibration of helical gear with tooth error is modeled by the nonlidear equation of motion with single degree of freedom and is anlyzed numerically. Also, by a specially designed experimental set-up, the analysis are cross-checked and the vibration characteristics of helical gear are discussed.

리드오차의 영향에 대한 헬리컬 기어 소음의 실험적 연구

박찬일,이장무,Park, Chan-Il,Lee, Jang-Mu 대한기계학회 2001 大韓機械學會論文集A Vol.25 No.9

Nowadays reduction of gear noise in power transmission is very important, because the noise regulation is severe and demand of customer on noise is increased. To reduce gear noise, it is necessary to understand the noise characteristics of helical gear. In this work, we designed test rig for the study of gear noise and installed in semi-anechoic chamber. By using this rig, sound pressure level is measured under varying rotational speed and torque. The frequency characteristics of helical gear noise on the effect of lead errors and torque are discussed.

태양전지 응용을 위한 ZnO:Al 박막의 전기적·물리적 특성에서 증착 온도의 영향

박찬일,Park, Chan Il 한국전기전자재료학회 2021 전기전자재료학회논문지 Vol.34 No.1

In the case of ZnO:Al thin films, it is the best material that can replace ITO that is mainly used as a transparent electrode in electronic devices such as solar cells and flat-panel displays. In this study, ZnO:Al films were fabricated by using the RF dual magnetron sputtering method at various substrate temperatures. As the substrate temperature increased, the crystallinity of the ZnO:Al thin films was improved, and the electrical conductivity and electrical properties of the thin film improved owing to the increase in grain size. In addition, the surface roughness of the ZnO:Al thin films increased due to changes in the surface and density of the thin films. Moreover, the substrate temperature increased the density of thin films and improved their transmittance. To be applied to solar cells and other several electronic devices in the future, the hardness and adhesion properties of the thin film improve as the substrate temperature increases.

N-(2,4-dinitrophenyl)benzhydrazonyl Bromide 유도체의 가수분해 반응메카니즘

박찬일,차기원,이익춘,장병두,Park, Chan Il,Cha, Ki Won,Lee, Ik Choon,Chang, Byung Du 대한화학회 1997 대한화학회지 Vol.41 No.4

N-(2,4-dinitrophenyl)benzhydrazonyl bromide 유도체들의 가수분해 반응속도상수를 20$^{\circ}C$의 수용액에서 자외선 분광광도법으로 측정하여 넓은 pH 범위에서의 반응속도식을 구하였다. 반응속도식, 용매효과, 치환기 효과, 염효과, 열역학적 활성화 파라미터 등의 결과로부터 가수분해 반응메카니즘을 제안하였다. 즉, pH 3.0에서는 carbonium ion 중간체를 거쳐 SN1 반응에 의해 진행되며, pH 10.0에서는 1,3-dipolar 반응 메카니즘 또는 SN2 반응에 의해 진행됨을 제안하였다. The rate constants for the hydrolysis of N-(2,4-dinitrophenyl)benzhydrazonyl bromide and its derivatives were determined by ultraviolet visible spectrophotometry at 20$^{\circ}C$ and a rate equation which could be applied over a wide pH range was obtained. On the basis of rate equations derived and judging from the solvent effect, substituent effect, salt effect, thermodynamic parameter, plausible mechanisms of hydrolysis have been proposed. It may be concluded that the hydrolysis through SN1 mechanism via carbonium ion intermdiate to pH 3.0, and pH 10.0, the hydrolysis proceeds through 1,3-dipolar or SN2 mechanism.

Xylenol Orange가 결합된 양이온 교환체에 의한 금속이온의 농축 및 Fe(III)의 분리

박찬일,김현수,차기원,Park, Chan Il,Kim, Hyun Soo,Cha, Ki Won 대한화학회 1999 대한화학회지 Vol.43 No.6

Xylenol Orange was bonded on an anion-exchange resin (Amberlite lRA 400, in $Cl^-$form) by batch equilibration. The resin was proved to be stable in acidic solutions of about 0.1 M HCl, $HNO_3$ or $H_2SO_4$. Sorption capacities for the metal ions on the Amberlite IRA 400 bonded with xylenol orange have been measured by batch method. The result showed that Fe(III) is higher than any other metals for sorption capacity. The preconcentration and the separation of Fe(lll) from the mixture soIution, therefore, were carried out with the 0.1 M sulfosalicylic acid as an eluent. 뱃치법을 이용하여 음이온 교환수지(Amberlite IRA 400, $Cl^-$형)에 Xylenol Orange를 결합시킨 수지를 얻었다. 이 수지는 0.1 M 정도의 무기산에서 안정하였으며, Xylenol Orange가 결합된 Amberlite lRA-400 수지의 금속 이온들에 대한 흡착능을 측정해 본 결과, Fe(lll) 이온의 흡착력이 다른 이온에 비해 컸다. 따라서 Fe(III) 이온을 예비 농축할 수 있었으며 다른 이온으로 부터 분리하는데는 용리액으로 0.1 M sulfosalicylic acid 용액이 사용되었다.

스퍼터링 질화탄소 박막의 트라이볼로지 및 전기적 특성의 기판 온도 영향

박찬일,Park, Chan Il 한국전기전자재료학회 2021 전기전자재료학회논문지 Vol.34 No.1

Using facing target magnetron sputtering (FTMS) with a graphite target source, carbon nitride thin films were deposited on silicon and glass substrates at different substrate temperatures to confirm the tribological, electrical, and structural properties of thin films. The substrate temperatures were room temperature, 150℃, and 300℃. The tribology and electrical properties of the carbon nitride thin films were measured as the substrate temperature increased, and a study on the relation between these results and structural properties was conducted. The results show that the increase in the substrate temperature during the fabrication of the carbon nitride thin films increased the hardness and elastic modulus values, the critical load value was increased, and the residual stress value was reduced. Moreover, the increase in the substrate temperature during thin-film deposition was attributed to the improvement in the electrical properties of carbon nitride thin film.

Ge(Ⅳ)-Mercaptoacetic Acid 착물에 의한 흡착벗김 전압-전류법

박찬일,성숙희,차기원,Park, Chan Il,Seong, Suk Hee,Cha, Ki Won 대한화학회 1999 대한화학회지 Vol.43 No.1

The adsorptive stripping voltammetric determination method of trace germanium (IV) using mercaptoacetic acid as a ligand was studied. Optimal conditions were found to be 0.25 M NaCl solution (pH 6.0) containing mercaptoacetic acid concentration of $5.0{\times}10^{-6}M$. The peak potential appeared at - 1.402 V vs. Ag/AgCl. Effects of sodium chloride concentration, mercaptoacetic acid concentration, and accumulation time for the complex of Ge(IV)-Mercaptoacetic acid on the peak current were studied. Amberlite IRC-718 chelating resin was applied to the separation of Ge(IV) from other metal ions. Mercaptoacetic acid를 이용하여 흡착벗김 전압전류법으로 미량의 게르마늄을 정량하는 방법을 연구하였다. 이때 지지전해질은 0.25 M NaCl 용액(pH 6.0)을 사용하였고, mercaptoacetic acid의 농도는 $5.0{\times}10^{-6}M$이 되도록 조절하여 실험하였다. Ge(IV)-Mercaptoacetic acid 착물의 봉우리 전위는 -1.402V vs. Ag/AgCl에서 나타났다. 착물의 봉우리 전위에 미치는 NaCl의 농도, mercaptoacetic acid의 농도, 축적 시간등에 대하여 조사하였다. 또한, Amberlite IRC-718 킬레이트 수지를 다른 이온들로 부터 Ge(IV)을 분리하는데 적용하였다.

Spectrophotometric Determination of Iron with 2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone after Separation with Amberlite XAD-7 Nonionic Resin

박찬일,장병두,정덕채,차기원,Park, Chan Il,Chung, Byung Doo,Jung, Duck Chae,Cha, Ki Won Korean Chemical Society 1999 대한화학회지 Vol.43 No.5

2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone(2HB-5NPH)를 합성하여 철의 분광학적 정량에 응용하였다. 이 시약은 pH 6.0-7.5 범위에서 철과 반응하여 메탄올 용액에서 매우 안정한 노란색의 1:2킬레이트를 형성한다. 철의 농도범위가 0.05∼2.0 ${\mu}gmL^{-1}$일 때 Beer's law에 적용되고 미량의 철을 분광학적으로 정량하기 위하여 Amberlite XAD-7 비이온성 킬레이트 수지로 채워진 짧은 컬럼을 사용하여 분리과정에 적용하였다. 몇가지 이온들의 방해 효과를 연구하였다. 혼합용액으로부터 철이온의 분리는 완충용액(pH 5.0)과 용리액으로서 0.25M HCl을 가지고 수행하였다. 2-Hydroxybenzaldehyde-5-nitro-pyridylhydrazone (2HB-5NPH) was synthesized and its application to the spectrophotometric determination of iron was studied. The reagent reacts with iron in the pH range 6.0-7.5 to form a yellow coIored 1:2 chelate which is very stable in methanol solution. Beer's law is obeyed in the concentration range 0.05∼2.0 ${\mu}gmL^{-1}$ iron and separation procedure using a short column filled with Amberlite XAD-7 nonionic chelating resin is proposed for the spectrophotometric determination of traces of iron. The influence of several ions as interference was discussed. The separation of Fe(III) ion from the mix-ture solution were carried out with the buffer solution (pH 5.0) and 0.25M HCl as eluents.

엘리베이터용 헬리컬기어의 전달오차 해석

박찬일,김대식,Park, Chan-Il,Kim, Dae-Sik 대한기계학회 2002 大韓機械學會論文集A Vol.26 No.12

The elevator gear box with the helical gears needs to be developed instead of the one with the worm gears to improve the efficiency. In order to develop the gear box, the analytical tool to predict the helical gear noise is necessary to meet customer's noise requirement. Gear noise is related to the loaded transmission error. Therefore, the simulation program fer the loaded transmission error analysis of the helical gears is developed in this study. Using the developed program, the effects of tooth modification such as tip relief and the extent of tip relief are investigated. Finally, the procedures to determine the tip relief and the extent of tip relief are proposed.

Spectrophotometric Determination of Uranium(Ⅵ)with Pyrocatechol Violet in Surfactant Media

박찬일,차기원,Park, Chan Il,Hua-Zi Huang,Cha, Gi Won Korean Chemical Society 2001 Bulletin of the Korean Chemical Society Vol.22 No.1