Effect of coloring treatment of translucent zirconia on the masking ability of metal abutment

이명재,박미경 대한치과재료학회 2023 대한치과재료학회지 Vol.50 No.3

Translucent monolithic zirconia is widely used because it has continuously enhanced color and translucency. However, when translucent monolithic zirconia are used for esthetic zone like anterior, it has problem to be exposed to color of titanium abutment. The purpose of this study was to evaluate the effect of coloring and cementing of translucent zirconia on the color masking of titanium abutments. The CIE L*, a*, and b* values were measured using a spectrophotometer in three subgroups after coloring with A2 colorant and white opaque colorant, and the color difference and translucency of each group were analyzed. In the A2 colorant application group, the color difference (ΔE* ) between zirconia and zirconia on titanium abutments was not clinically acceptable (ΔE* >3.3). In the white opaque group and the white opaque plus A2 colorant group, the color difference (ΔE* ) between zirconia and zirconia on titanium abutments was clinically acceptable (1<ΔE* <3.3). The translucency of zirconia was significantly affected by the coloring treatment (P<.001). The Pearson correlation between color difference and translucency parameters was high (r=0.982, R2=0.965). The white coloring treatment to translucent zirconia affected masking of titanium abutment. The combination of A2 colorant and white opaque colorant increased the color masking effect of titanium abutments and achieved a shade similar to natural teeth. Resin cement adhesion to translucent zirconia did not affect the color masking of titanium zirconia. As the zirconia translucency increases, it had less of an effect on the titanium abutment.

Evaluation of translucency of monolithic zirconia and framework zirconia materials

İlkin Tuncel,Işıl Turp,Aslıhan Üşümez 대한치과보철학회 2016 The Journal of Advanced Prosthodontics Vol.8 No.3

PURPOSE The opacity of zirconia is an esthetic disadvantage that hinders achieving natural and shade-matched restorations. The aim of this study was to evaluate the translucency of non-colored and colored framework zirconia and monolithic zirconia. MATERIALS AND METHODS The three groups tested were: non-colored framework zirconia, colored framework zirconia with the A3 shade according to Vita Classic Scale, and monolithic zirconia (n=5). The specimens were fabricated in the dimensions of 15×12×0.5 mm. A spectrophotometer was used to measure the contrast ratio, which is indicative of translucency. Three measurements were made to obtain the contrast ratios of the materials over a white background (L*w) and a black background (L*b). The data were analyzed using the one-way analysis of variance and Tukey HSD tests. One specimen from each group was chosen for scanning electron microscope analysis. The determined areas of the SEM images were divided by the number of grains in order to calculate the mean grain size. RESULTS Statistically significant differences were observed among all groups (P<.05). Non-colored zirconia had the highest translucency with a contrast ratio of 0.75, while monolithic zirconia had the lowest translucency with a contrast ratio of 0.8. The mean grain sizes of the non-colored, colored, and monolithic zirconia were 233, 256, and 361 nm, respectively. CONCLUSION The translucency of the zirconia was affected by the coloring procedure and the grain size. Although monolithic zirconia may not be the best esthetic material for the anterior region, it may serve as an alternative in the posterior region for the bilayered zirconia restorations

The effect of plasma on shear bond strength between resin cement and colored zirconia

박찬,유승환,박상원,윤귀덕,지민경,신진호,임현필 대한치과보철학회 2017 The Journal of Advanced Prosthodontics Vol.9 No.2

PURPOSE. To investigate the effect of non-thermal atmospheric pressure plasma (NTAPP) treatment on shear bond strength (SBS) between resin cement and colored zirconia made with metal chlorides. MATERIALS AND METHODS. 60 zirconia specimens were divided into 3 groups using coloring liquid. Each group was divided again into 2 sub-groups using plasma treatment; the experimental group was treated with plasma, and the control group was untreated. The sub-groups were: N (non-colored), C (0.1 wt% aqueous chromium chloride solution), M (0.1 wt% aqueous molybdenum chloride solution), NP (non-colored with plasma), CP (0.1 wt% aqueous chromium chloride solution with plasma), and MP (0.1 wt% aqueous molybdenum chloride solution with plasma). Composite resin cylinders were bonded to zirconia specimens with MDP-based resin cement, and SBS was measured using a universal testing machine. All data was analyzed statistically using a 2-way ANOVA test and a Tukey test. RESULTS. SBS significantly increased when specimens were treated with NTAPP regardless of coloring (P<.001). Colored zirconia containing molybdenum showed the highest value of SBS, regardless of NTAPP. The molybdenum group showed the highest SBS, whereas the chromium group showed the lowest. CONCLUSION. NTAPP may increase the SBS of colored zirconia and resin cement. The NTAPP effect on SBS is not influenced by the presence of zirconia coloring.

The effect of plasma on shear bond strength between resin cement and colored zirconia

Park, Chan,Yoo, Seung-Hwan,Park, Sang-Won,Yun, Kwi-Dug,Ji, Min-Kyung,Shin, Jin-Ho,Lim, Hyun-Pil The Korean Academy of Prosthodonitics 2017 The Journal of Advanced Prosthodontics Vol.9 No.2

PURPOSE. To investigate the effect of non-thermal atmospheric pressure plasma (NTAPP) treatment on shear bond strength (SBS) between resin cement and colored zirconia made with metal chlorides. MATERIALS AND METHODS. 60 zirconia specimens were divided into 3 groups using coloring liquid. Each group was divided again into 2 sub-groups using plasma treatment; the experimental group was treated with plasma, and the control group was untreated. The sub-groups were: N (non-colored), C (0.1 wt% aqueous chromium chloride solution), M (0.1 wt% aqueous molybdenum chloride solution), NP (non-colored with plasma), CP (0.1 wt% aqueous chromium chloride solution with plasma), and MP (0.1 wt% aqueous molybdenum chloride solution with plasma). Composite resin cylinders were bonded to zirconia specimens with MDP-based resin cement, and SBS was measured using a universal testing machine. All data was analyzed statistically using a 2-way ANOVA test and a Tukey test. RESULTS. SBS significantly increased when specimens were treated with NTAPP regardless of coloring (P<.001). Colored zirconia containing molybdenum showed the highest value of SBS, regardless of NTAPP. The molybdenum group showed the highest SBS, whereas the chromium group showed the lowest. CONCLUSION. NTAPP may increase the SBS of colored zirconia and resin cement. The NTAPP effect on SBS is not influenced by the presence of zirconia coloring.

The effect of plasma on shear bond strength between resin cement and colored zirconia

Chan Park†,Seung-Hwan Yoo†,Sang-Won Park,Kwi-Dug Yun,Min-Kyung Ji,Jin-Ho Shin,Hyun-Pil Lim 대한치과보철학회 2017 The Journal of Advanced Prosthodontics Vol.9 No.2

PURPOSE. To investigate the effect of non-thermal atmospheric pressure plasma (NTAPP) treatment on shear bond strength (SBS) between resin cement and colored zirconia made with metal chlorides. MATERIALS AND METHODS. 60 zirconia specimens were divided into 3 groups using coloring liquid. Each group was divided again into 2 sub-groups using plasma treatment; the experimental group was treated with plasma, and the control group was untreated. The sub-groups were: N (non-colored), C (0.1 wt% aqueous chromium chloride solution), M (0.1 wt% aqueous molybdenum chloride solution), NP (non-colored with plasma), CP (0.1 wt% aqueous chromium chloride solution with plasma), and MP (0.1 wt% aqueous molybdenum chloride solution with plasma). Composite resin cylinders were bonded to zirconia specimens with MDP-based resin cement, and SBS was measured using a universal testing machine. All data was analyzed statistically using a 2-way ANOVA test and a Tukey test. RESULTS. SBS significantly increased when specimens were treated with NTAPP regardless of coloring (P<.001). Colored zirconia containing molybdenum showed the highest value of SBS, regardless of NTAPP. The molybdenum group showed the highest SBS, whereas the chromium group showed the lowest. CONCLUSION. NTAPP may increase the SBS of colored zirconia and resin cement. The NTAPP effect on SBS is not influenced by the presence of zirconia coloring.

Effects of colored zirconia surface treatment on the bond strength of veneering ceramics

SA-Hak Kim,Chong-Kyen Kim 대한치과기공학회 2021 대한치과기공학회지 Vol.43 No.4

Purpose: In this study, when the etching treatment method, which is a chemical surface treatment method, is applied to colored zirconia, the shear bond strength between the veneering ceramic material and colored zirconia is compared with that without surface treatment, and the fracture type is observed to evaluate the etching treatment effect of colored zirconia. Methods: Experiments were conducted after dividing the study sample into two groups, which are the zirconia control group without surface treatment using colored zirconia blocks (without etching zirconia, NZC group) and the zirconia group treated with a commercially available etching solution (etching liquid zirconia, EZC group). Results: The mean shear bond strength of the NZC group was 20.31±2.32 Mpa, and that of the EZC group was 25.95±2.34 Mpa, and the difference between these two values was statistically significant (p<0.05). Further, the surface roughness Ra value was higher in the EZC group than in the NZC group. In the fracture pattern, cohesive fractures were dominant, and adhesive fractures and cohesive fractures were mixed. Conclusion: The bond strength was significantly higher in the group treated with colored zirconia. The fracture pattern was mostly cohesive failure in the group not treated with etching and changed to mixed failure as the etching treatment progressed.

색소체용액 침투가 지르코니아 및 전장용 세라믹의 전단결합강도에 미치는 영향

정종현,오계정 대한치과기공학회 2016 대한치과기공학회지 Vol.38 No.4

Purpose:This study was to evaluate the effect of coloring liquids on the shear bond strength between zirconia and veneering ceramic. Methods: Zirconia(15 mm in diameter, 2.5 mm in thickness; n=40) used in the experiment were divided into 5 groups depending on the coloring liquid. Each specimen were polished using a polishing machine(LaboPol-2,Struers, UK). A cylinder of veneering porcelain(6 mm in diameter, 3 mm in thickness) was fabricated and fired on zirconia surfaces. The shear bond strength was measured using a universal testing machine(Model 4302, Instron,USA). All data were analyzed statistically using a one-way ANOVA and Tukey s multiple comparisons test. After the shear bond test, fracture surfaces were examined by SEM. Results: Colored zirconia showed a higher shear bonding strength than that of uncolored zirconia except for colored zirconia immersed in Zirkonzahn coloring liquid. In particular, colored zirconia immersed in Kuwotech coloring liquid showed the highest shear bond strength. After the shear bond test, mixed failure patterns were mainly observed in the failure between zirconia and veneering ceramic. Conclusion: Coloring liquid enhanced the shear bond strength zirconia and veneering ceramic than uncolored zirconia.

Effect of the shades of background substructures on the overall color of zirconia-based all-ceramic crowns

Wannaporn Kamchatphai,Jatuphol Mamani,Noparat Thongpun,Chantana Tulapornchai,Kallaya Suputtamongkol 대한치과보철학회 2013 The Journal of Advanced Prosthodontics Vol.5 No.3

PURPOSE The objective of this study was to determine the effect of the color of a background substructure on the overall color of a zirconia-based all-ceramic crown. MATERIALS AND METHODS Twenty one posterior zirconia crowns were made for twenty subjects. Seven premolar crowns and six molar crowns were cemented onto abutments with metal post and core in the first and second group. In the third group, eight molar crowns were cemented onto abutments with a prefabricated post and composite core build-up. The color measurements of all-ceramic crowns were made before try-in, before and after cementation. A repeated measure ANOVA was used for a statistical analysis of a color change of all-ceramic crowns at α=.05. Twenty four zirconia specimens, with different core thicknesses (0.4-1 mm) were also prepared to obtain the contrast ratio of zirconia materials after veneering. RESULTS L*, a*, and b* values of all-ceramic crowns cemented either on a metal cast post and core or on a prefabricated post did not show significant changes (P>.05). However, the slight color changes of zirconia crowns were detected and represented by ΔE*ab values, ranging from 1.2 to 3.1. The contrast ratios of zirconia specimens were 0.92-0.95 after veneering. CONCLUSION No significant differences were observed between the L*, a*, and b* values of zirconia crowns cemented either on a metal cast post and core or a prefabricated post and composite core. However, the color of a background substructure could affect the overall color of posterior zirconia restorations with clinically recommended core thickness according to ΔE*ab values.

Effect of the shades of background substructures on the overall color of zirconia-based all-ceramic crowns

Suputtamongkol, Kallaya,Tulapornchai, Chantana,Mamani, Jatuphol,Kamchatphai, Wannaporn,Thongpun, Noparat The Korean Academy of Prosthodonitics 2013 The Journal of Advanced Prosthodontics Vol.5 No.3

PURPOSE. The objective of this study was to determine the effect of the color of a background substructure on the overall color of a zirconia-based all-ceramic crown. MATERIALS AND METHODS. Twenty one posterior zirconia crowns were made for twenty subjects. Seven premolar crowns and six molar crowns were cemented onto abutments with metal post and core in the first and second group. In the third group, eight molar crowns were cemented onto abutments with a prefabricated post and composite core build-up. The color measurements of all-ceramic crowns were made before try-in, before and after cementation. A repeated measure ANOVA was used for a statistical analysis of a color change of all-ceramic crowns at ${\alpha}$=.05. Twenty four zirconia specimens, with different core thicknesses (0.4-1 mm) were also prepared to obtain the contrast ratio of zirconia materials after veneering. RESULTS. $L^*$, $a^*$, and $b^*$ values of all-ceramic crowns cemented either on a metal cast post and core or on a prefabricated post did not show significant changes (P>.05). However, the slight color changes of zirconia crowns were detected and represented by ${\Delta}E{^*}_{ab}$ values, ranging from 1.2 to 3.1. The contrast ratios of zirconia specimens were 0.92-0.95 after veneering. CONCLUSION. No significant differences were observed between the $L^*$, $a^*$, and $b^*$ values of zirconia crowns cemented either on a metal cast post and core or a prefabricated post and composite core. However, the color of a background substructure could affect the overall color of posterior zirconia restorations with clinically recommended core thickness according to ${\Delta}E{^*}_{ab}$ values.

Color Variation in Color-shade Polycrystalline Zirconia Ceramics by the Atmosphere Controlled Firing

Chang, Myung Chul The Korean Ceramic Society 2018 한국세라믹학회지 Vol.55 No.2

Color shade variation was investigated in zirconia dental blocks, prepared using commercial powders. As a reference color-shade block we used the color indexes of A2, A3.5, A4 and B3, according to the VITA classical color scale. The zirconia powders for color shade blocks showed colors of white, yellow, pink and grey, respectively, after firing at $1530^{\circ}C$. The zirconia powders were mixed according to the recipe of color shade blocks and shaped at lower pressure using a uniaxial hydrostatic press. The shaped sample was inserted into a vinyl pack and sealed in a vacuum form machine. The shaped block samples were reshaped at 450 bar using an isostatic cold press and fired at $1530^{\circ}C$ for three hours. In order to investigate the atmospheric color variation with firing temperature, the A2, A3.5, A4 and B3 sintered blocks were fired between $700^{\circ}C$ and $1300^{\circ}C$ under controlled atmosphere of $pN_2$ and $pO_2$. The surface color picture was taken using a smart phone camera and compared with the results obtained using the VITA classical color scale. Quantitative color index value, CIELAB, was measured using a color-meter. Above $800^{\circ}C$, the color darkness greatly increased with the increase of the reduction temperature and keeping time.