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Zhang, Han,Liu, Guangliang,Song, Haiyan,Chen, Chunxia,Han, Fuqin,Chen, Ping,Zhao, Zhixi,Hu, Shaozheng Korean Chemical Society 2013 Bulletin of the Korean Chemical Society Vol.34 No.10
Direct synthesis of $H_2O_2$ and in situ oxidative desulfurization of model fuel over Au/Ti-HMS and Au/TS-1 catalysts has been comparatively investigated in water or methanol. Maximum amount (82%) of active $Au^0$ species for $H_2O_2$ synthesis was obtained. Au/Ti-HMS and Au/TS-1 exhibited the contrary performances in $H_2O_2$ synthesis as $CH_3OH/H_2O$ ratio of solvent changed. $H_2O_2$ decomposition and hydrogenation in water was inhibited by the introduction of methanol. Effect of $O_2/H_2$ ratio on $H_2O_2$ concentration, $H_2$ conversion and $H_2O_2$ selectivity revealed a relationship between $H_2O_2$ generation and $H_2$ consumption. The highest dibenzothiophene removal rate (83.2%) was obtained over Au/Ti-HMS in methanol at 1.5 of $O_2/H_2$ ratio and $60^{\circ}C$. But removal of thiophene over Au/TS-1 should be performed in water without heating to obtain a high removal rate (61.3%). Meanwhile, $H_2$ conversion and oxidative desulfurization selectivity of $H_2$ were presented.
Research on non-destructive testing technology for existing bridge pile foundations
Zhang, Xue-feng,Ni, Ying-sheng,Song, Chunxia,Xu, Dong Techno-Press 2020 Structural monitoring and maintenance Vol.7 No.1
Pile foundations of existing bridges lie in soil and water environment for long term and endure relatively heavy vertical loads, thus prone to damages, especially after stricken by external forces, such as earthquake, collision, soil heap load and etc., and the piles may be injured to certain degrees as well. There is a relatively complete technical system for quality inspection of new bridge pile foundations without structures on the top. However, there is no mature technical standard in the engineering community for the non-destructive testing technology specific to the existing bridge pile foundations. The quality of bridge pile foundations has always been a major problem that plagues bridge maintenance. On the basis of many years' experiences in test engineering and theoretical studies, this study developed a new type of detection technology and equipment for the existing bridge piles.
Han Zhang,Guangliang Liu,Haiyan Song,Chunxia Chen,Fuqin Han,Ping Chen,Zhixi Zhao,Shaozheng Hu 대한화학회 2013 Bulletin of the Korean Chemical Society Vol.34 No.10
Direct synthesis of H2O2 and in situ oxidative desulfurization of model fuel over Au/Ti-HMS and Au/TS-1 catalysts has been comparatively investigated in water or methanol. Maximum amount (82%) of active Au0 species for H2O2 synthesis was obtained. Au/Ti-HMS and Au/TS-1 exhibited the contrary performances in H2O2 synthesis as CH3OH/H2O ratio of solvent changed. H2O2 decomposition and hydrogenation in water was inhibited by the introduction of methanol. Effect of O2/H2 ratio on H2O2 concentration, H2 conversion and H2O2 selectivity revealed a relationship between H2O2 generation and H2 consumption. The highest dibenzothiophene removal rate (83.2%) was obtained over Au/Ti-HMS in methanol at 1.5 of O2/H2 ratio and 60 oC. But removal of thiophene over Au/TS-1 should be performed in water without heating to obtain a high removal rate (61.3%). Meanwhile, H2 conversion and oxidative desulfurization selectivity of H2 were presented.
Gong Xiaowei,Luo Huajun,Hong Liu,Wu Jun,Wu Heng,Song Chunxia,Zhao Wei,Han Yi,Dao Ya,Zhang Xia,Zhu Donglai,Luo Yiyong 한국미생물학회 2022 The journal of microbiology Vol.60 No.8
Tryptophol (TOL) is a metabolic derivative of tryptophan (Trp) and shows pleiotropic effects in humans, plants and microbes. In this study, the effect of Trp and phenylalanine (Phe) on TOL production in Saccharomyces cerevisiae was determined, and a systematic interpretation of TOL accumulation was offered by transcriptomic and metabolomic analyses. Trp significantly promoted TOL production, but the output plateaued (231.02−266.31 mg/L) at Trp concentrations ≥ 0.6 g/L. In contrast, Phe reduced the stimulatory effect of Trp, which was strongly dependent on the Phe concentration. An integrated genomic, transcriptomic, and metabolomic analysis revealed that the effect of Trp and Phe on TOL production was mainly related to the transamination and decarboxylation of the Ehrlich pathway. Additionally, other genes, including thiamine regulon genes (this), the allantoin catabolic genes dal1, dal2, dal4, and the transcriptional activator gene aro80, may play important roles. These findings were partly supported by the fact that the thi4 gene was involved in TOL production, as shown by heterologous expression analysis. To the best of our knowledge, this novel biological function of thi4 in S. cerevisiae is reported here for the first time. Overall, our findings provide insights into the mechanism of TOL production, which will contribute to TOL production using metabolic engineering strategies.