산소와 구리의 공정반응에 의한 구리와 알루미나의 직접접합

이임렬,유환성 단국대학교 신소재기술연구소 1991 신소재 Vol.1 No.-

본 연구에서는 구리표면의 구리-산소간의 공정반응에 의하여 형성된 Cu-Cu_2O 공용액상 피막으로 고체 Cu금속과 Al_2O_3세라믹을 압력없이 직접접합시키는 방법을 조사하였으며 접합조건에 따른 접합특성, 파면 및 계면분석을 SEM, EDS, XRD 및 peeling 시험을 통하여 분석하였다. 1.5×10^-1 torr 진공하에서 1015℃의 온도에서 산화시킨 구리시편은 미세한 산화물 Cu_2O가 표면에 잘 형성되었다. 그후 공정온도 1065℃ 이상의 접합온도 1075℃에서 5분간 10^-3 torr의 진공하에서 직접접합시킨 시편은 접합력이 우수한 Cu/Al_2O_3 접합이 되었으며 접합후 구리기니 내에는 Cu2O가 석출된 공융조직을 갖고 있었다. 3분 산화조건에서 충분한 액상이 형성되어 29kg의 최대 접합강도를 보였으며 산회시간이 이보다 짧거나 불충분한 액상의 형성이나 산화물내의 균열 등으로 결합력이 저하하였다. 파단후 Al_2O_3 표면에는 Cu_2O nodule이 존재하였고 Cu족에는 nodule이 빠진홈을 관찰할 수 있었는바 cu2O/Al_2O_3계면 접착력은 Cu.Cu_2O계면보다 강함을 알 수 있었다. 또한 파단면에는 반응 생성물 CuAlO_2가 접합중 형성되었으나 이 반응층 두께는 SEM분해능 이하인 매우 얇은 것으로 생각된다. The direct bonding between Cu and Al_2O_3, utilizing Cu-Cu_2O skin melt formed on Cu surface by eutectic reation of Cu-O, is investigated in this study. The bond strength, fracture surface and interface structure with bonding conditions have been studied using SEM, EDS, XRD and peeling test. A fine Cu_2O is formed on the surface of Cu with oxidation at 1015℃ under 1.5×10^-1torr vacuum. After oxidation, the bonded specimen conducted at 1075℃ in 10^-3torr vacuum for 5minutes, higher temperature than its eutectic temperature of 1065℃, has a good strength having a Cu_2O precipitated structure in Cu matrix upon cooling. It has been found that the maximum bonding force of 29kg is obtatined for 3 minutes of oxidation. However, the adhesion forces are decreased with shorter or longer oxidation than this due to the formation of insufficient liquid skin or crack within oxide. After peeling test, Al_2O_3 surface is covered with Cu_2O nodules which are pulled out of Cu surface indication that Cu_2O/Al_2O_3 adhesion force is stronger than that of Cu/Cu_2O. Moreover a reaction phase of CuAlO_2, thought to be very thin layer below the resolution of SEM, is also formed during the bonding process.

冷間加工의 磨耗에 對한 影響

李任烈 단국대학교 1986 論文集 Vol.20 No.-

The wear experiment was conducted on couples consisting of iron, nickel, Fe-36% Ni and 3% silicon steel pins sliding against a tool steel disc. It has been found that the wear rate in air at room temperature lis independent to me hardness. The experimental observations are well related to the oxidation characteristics. However, the rate of oxidative wear is much higher than that for static oxidation due to the difference in the activation energy for oxidative wear. The lower energy for oxidational wear indicates that the rubbing surfaces are mechanically activated and high diffusivity path for diffusion of matrix elements and oxygen are produced during the sliding motion. The higher wear rate for cold-worked samples than for the annealed ones are associated with the higher oxidation rate for the cold-worked specimen.

Evaluation of Structural Integrity and Performance Using Nondestructive Testing and Monitoring Techniques

Rhim Hong Chul 한국지진공학회 1998 한국지진공학회논문집 Vol.2 No.3

In this paper, the necessity of developing effective nondestructive testing and monitoring techniques for the evaluation of structural integrity and performance is described. The evaluation of structural integrity and performance is especially important when the structures and subject to abrupt external forces such as earthquake. A prompt and extensive inspection is required over a large area of earthquake-damaged zone. This evaluation process is regarded as a part of performance-based design. In the paper, nondestructive testing and monitoring techniques particularly for concrete structures are presented as methods for the evaluation of structural integrity and performance. The concept of performance-based design is first defined in the paper followed by the role of evaluation of structures in the context of overall performance=based design concept. Among possible techniques for the evaluation, nondestructive testing methods for concrete structures using radar and a concept of using fiber sensor for continuous monitoring of structures are presented.

Differences in Breeding Bird Communities Between Deciduous Forests of Gwangneung and Mt. Namsan Areas

Rhim, Shin-Jae,Kim, Min-Jin,Lee, Ju-Young,Kang, Jeong-Hoon Korean Society of Forest Science 2007 한국산림과학회지 Vol.96 No.5

This study was conducted to clarify the differences in breeding bird communities between deciduous forests of Gwangneung and Mt. Namsan areas from April to August 2006. Two 10ha area were selected for territory mapping of breeding bird community in both study area. The DBH distribution of trees and average foliage profiles were significantly different between study areas. Also, breeding bird communities were different. Number of breeding species and pairs, breeding density, and bird species diversity were higher in Gwangneung area than in Mt. Namsan area. When examining relationship between forest habitat structure and bird community, Number of bird species and breeding pairs belonged to hole and canopy guild were increase as the increase of coverstory coverage and number of large trees. Therefore, it is necessary to make vertical structure more various to plant bushes, and to make DBH distribution more diverse for enhancing bird species diversity in the degraded ecosystem.

Caveolin-1 as a Novel Indicator of Wound-Healing Capacity in Aged Human Corneal Epithelium

Rhim, Ji Heon,Kim, Jae Hoon,Yeo, Eui-Ju,Kim, Jae Chan,Park, Sang Chul Springer (Biomed Central Ltd.) 2010 Molecular Medicine Vol. No.

Radionuclide-labeled nanostructures for In Vivo imaging of cancer

Rhim Won-Kyu,Kim Minho,HARTMANKEVIN LAURENCE,강건욱,남좌민 나노기술연구협의회 2015 Nano Convergence Vol.2 No.10

Molecular imaging plays an important role in the non-invasive diagnosis and the guiding or monitoring of disease treatment. Different imaging modalities have been developed, and each method possesses unique strengths. While a variety of molecules have been used previously in nuclear imaging, the exceptional properties of nanostructures in recent research enable the deployment of accurate and efficient diagnostic agents using radionuclide-nanostructures. This review focuses on the radionuclide labeling strategies of various nanostructures and their applications for multimodality tumor imaging.

Isolation of cellulose nanocrystals from onion skin and their utilization for the preparation of agar-based bio-nanocomposites films

Rhim, Jong-Whan,Reddy, Jeevan Prasad,Luo, Xiaogang Springer-Verlag 2015 CELLULOSE Vol.22 No.1

Nanocrystalline Ferrihydrite-Based Catalysts for Fischer-Tropsch Synthesis: Part II. Effects of Activation Gases on the Catalytic Performance

Rhim, Geun Bae,Hong, Seok Yong,Park, Ji Chan,Jung, Heon,Rhee, Young Woo,Chun, Dong Hyun American Scientific Publishers 2016 Journal of Nanoscience and Nanotechnology Vol.16 No.2

<P>Fischer-Tropsch synthesis (FTS) was carried out over nanocrystalline ferrihydrite-based (Fe9O2(OH)(23)) catalysts activated by different reducing agents: syngas (H-2+CO), CO, and H-2. The syngas activation successfully changed the ferrihydrite-based catalysts into an active and stable catalytic structure with chi-carbide (Fe2.5C) and epsilon'-carbide (Fe2.2C). The crystal structure of the catalysts obtained by syngas activation was similar to the structure obtained by CO activation; this similarity was probably due to the peculiar reduction behavior of the ferrihydrite-based catalysts, which exhibit much greater reducibility in CO atmosphere than in H-2 atmosphere. The performance of the catalysts activated by syngas was much higher than the performance of the catalysts activated by H-2 and was comparable to the performance of the catalysts activated by CO. This strongly demonstrates that the ferrihydrite-based catalysts are advantageous for industrial FTS processes because syngas can be commonly used for both activation pre-treatment and subsequent reaction.</P>

Generation of Discrete $G^1$ Continuous B-spline Ship Hullform Surfaces from Curve Network Using Virtual Iso-parametric Curves

Rhim, Joong-Hyun,Cho, Doo-Yeoun,Lee, Kyu-Yeul,Kim, Tae-Wan The Society of Naval Architects of Korea 2006 Journal of ship and ocean technology Vol.10 No.2

Ship hullform is usually designed with a curve network, and smooth hullform surfaces are supposed to be generated by filling in (or interpolating) the curve network with appropriate surface patches. Tensor-product surfaces such as B-spline and $B\'{e}zier$ patches are typical representations to this interpolating problem. However, they have difficulties in representing the surfaces of irregular topological type which are frequently appeared in the fore- and after-body of ship hullform curve network. In this paper, we proposed a method that can automatically generate discrete $G^1$ continuous B-spline surfaces interpolating given curve network of ship hullform. This method consists of three steps. In the first step, given curve network is reorganized to be of two types: boundary curves and reference curves of surface patches. Especially, the boundary curves are specified for their surface patches to be rectangular or triangular topological type that can be represented with tensor-product (or degenerate) B-spline surface patches. In the second step, surface fitting points and cross boundary derivatives are estimated by constructing virtual iso-parametric curves at discrete parameters. In the last step, discrete $G^1$ continuous B-spline surfaces are generated by surface fitting algorithm. Finally, several examples of resulting smooth hullform surfaces generated from the curve network data of actual ship hullform are included to demonstrate the quality of the proposed method.

The Role of Research Center for the Development of Urban Underground Space for the Future

Rhim, Hong Chul,Kim, Sang Il 대한건축학회 2012 建築 Vol.56 No.2