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( Raji Atchudan ),이용록 한국공업화학회 2015 한국공업화학회 연구논문 초록집 Vol.2015 No.0
The graphitic carbon nanostructures (GCNs) were synthesized over the catalytic templates using acetylene as carbon precursor by simple chemical vapor deposition (CVD) method. The catalytic templates such as iron oxide nanoparticles (IONPs) and Mn impregnated MgO (Mn-MgO) were characterized and were used for the production GCNs. The reaction parameters such as temperature and flow of carbon precursor were optimized in order to achieve GCNs with excellent quality and quantity. The interlayer distance of resulted GCNs is match well with the bulk graphite. All the analytical results strongly support that the prepared GCNs to be highly ordered and well graphitic in nature. Further, the results demonstrate that the GMC/g-CNTs synthesized over Mn-MgO/IONPs might be a promising contender for the large-scale process. Moreover, the produced GCNs might be an ideal candidate for nanoelectronic applications.
Raji Atchudan,차봉근,나스리나론,김재윤,주진 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.1
Well-graphitized carbon nanotubes (CNTs) were grown by using monodisperse spherical mesoporous silica encapsulating single iron oxide (Fe3O4) nanoparticles (MSEINPs) as catalytic templates by chemical vapor deposition (CVD) and using acetylene as carbon source. The catalytic templates were synthesized by a sol-gel method. The MSEINPs exhibited better activity and selectivity in CNT synthesis than bare Fe3O4 catalysts. The synthesized multiwall carbon nanotubes (MWCNTs) were analyzed by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and Raman spectroscopy. The carbon deposits are rich in MWCNTs, as confirmed by FESEM and TGA. The wall thickness of the MWCNTs is controlled primarily by the size of the spherical mesoporous silica layer encapsulating the Fe3O4 NPs, while the inner diameter of the CNTs is determined by the size of the Fe3O4 NPs at the center of the MSEINPs. The average diameter of the MWCNTs increased significantly with increases in the growth temperature and acetylene flow rate. The analytical results show that the CNTs prepared on MSEINPs are well graphitized with a narrow size distribution in thickness, and straight and longer tubes are obtained without major defects as compared to the CNTs grown on bare Fe3O4 NPs.
Hollow mesoporous silica spheres supported Ag and Ag–Au catalyzed reduction of 4-nitrobenzo-15-crown
Raji Vadakkekara,Mousumi Chakraborty,Parimal A. Parikh 한국공업화학회 2014 Journal of Industrial and Engineering Chemistry Vol.20 No.3
Hollow mesoporous silica (HMS) spheres of size within the range 120–220 nm have been prepared usingpropanol–water solvent as template and cetyltrimethylammonium bromide (CTAB) as stabilizer. HMSsupported silver and silver–gold catalysts were prepared by impregnating metal nanoparticles on HMSand were characterized by ultraviolet–visible spectroscopy (UV–vis), dynamic light scattering (DLS),optical microscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transforminfrared spectroscopy (FTIR), inductive coupled plasma optical emission spectroscopy (ICP-OES) and N2adsorption–desorption. The reduction of 4-nitrobenzo-15-crown (4-NB-15-C) was compared using HMSsupported silver and silver–gold nanocatalysts varying experimental parameters. Bimetallic Ag–Au/HMS nanocatalysts was found to be more active than monometallic Ag/HMS nanocatalyst.
Analysis of Stability and Dynamic Behaviour of Ultra Lift Luo Converter
Raji, J.,Kamaraj, V. The Korean Institute of Electrical Engineers 2017 Journal of Electrical Engineering & Technology Vol.12 No.5
Ultra Lift Luo Converter (ULC) gained considerable research interest in recent years. The stability analysis of voltage mode and peak current mode controlled ULC in continuous conduction mode is analyzed in this paper. The Eigen value theory is used for the stability analysis of voltage mode controlled ULC. Then to characterize the dynamics of inner current loop, the expressions of closed loop transfer function and loop gain are determined. An algorithm has been developed to analyze the stability of the peak current mode controlled ULC. The theoretical results are correlated with the simulation results obtained using PSIM 9.1(SMARTCTRL 1.0) software. Finally it is proposed to fabricate a prototype and validate the performance by suitable experimental setup.
Investigation of ultra-lift Luo-converter with peak, average and hysteresis current-mode control
Raji, J.,Kamaraj, V. The Korean Institute of Power Electronics 2021 JOURNAL OF POWER ELECTRONICS Vol.21 No.6
The Renewable energy system, electric vehicle, and telecommunication applications require relatively stable power converters with a high gain and enhanced noise immunity. A study of three different types of current-mode controllers for high-gain ultra-lift Luo-converter (ULC) is discussed in this paper. The stability of a constant frequency peak current-mode controller (PCM), an average current-mode controller (ACM) and a variable frequency hysteresis current-mode controller (HCM) are analyzed based on small-signal characteristics. Using mathematical modeling of the controllers, the closed-loop transfer functions such as control voltage to output voltage, current loop gain, inductor current to control voltage, and audio susceptibility are obtained. These transfer functions along with MATLAB simulation results for PCM, ACM and HCM controllers are compared. Then, the component losses of the ULC converter using PCM, ACM and HCM controllers are calculated and an efficiency comparison of different control techniques is done. Investigations of the voltage and current stresses of the switch and diodes are also carried out. Finally, a prototype is fabricated to validate the performance of the converter.
Robust decentralized control of structures using the LMI H<sub>∞</sub>controller with uncertainties
Raji, Roya,Hadidi, Ali,Ghaffarzadeh, Hosein,Safari, Amin Techno-Press 2018 Smart Structures and Systems, An International Jou Vol.22 No.5
This paper investigates the operation of the $H_{\infty}$ static output-feedback controller to reduce dynamic responses under seismic excitation on the five-story and benchmark 20 story building with parametric uncertainties. Linear matrix inequality (LMI) control theory is applied in this system and then to achieve the desired LMI formulations, some transformations of the LMI variables is used. Conversely uncertainties due to material properties, environmental loads such as earthquake and wind hazards make the uncertain system. This problem and its effects are studied in this research. Also to decrease the transition of large amount of data between sensors and controller, avoiding the disruption of whole control system and economy problems, the operation of the decentralized controllers is investigated in this paper. For this purpose the comparison between the performance of the centralized, fully decentralized and partial decentralized controllers in uncoupled and coupled cases is performed. Also, the effect of the changing the number of stories in substructures is considered. Based on the numerical results, the used control algorithm is very robust against the parametric uncertainties and structural responses are decreased considerably in all the control cases but partial decentralized controller in coupled form gets the closest results to the centralized case. The results indicate the high applicability of the used control algorithm in the tall shear buildings to reduce the structural responses and its robustness against the uncertainties.
Semiconductor coupled solar photo-Fenton's treatment of dyes and textile effluent
Raji, Jeevitha R.,Palanivelu, Kandasamy Techno-Press 2016 Advances in environmental research Vol.5 No.1
$NanoTiO_2$ was synthesized by ultrasonication assisted sol-gel process and subjected to iron doping and carbon-iron codoping. The synthesized catalysts were characterized by XRD, HR-SEM, EDX, UV-Vis absorption spectroscopy and BET specific surface area analysis. The average crystallite size of pure $TiO_2$ was in the range of 30 - 33 nm, and that of Fe-$TiO_2$ and C-Fe $TiO_2$ was in the range of 7 - 13 nm respectively. The specific surface area of the iron doped and carbon-iron codoped nanoparticles was around $105m^2/g$ and $91m^2/g$ respectively. The coupled semiconductor photo-Fenton's activity of the synthesized catalysts was evaluated by the degradation of a cationic dye (C.I. Basic blue 9) and an anionic dye (C.I. Acid orange 52) with concurrent investigation on the operating variables such as pH, catalyst dosage, oxidant concentration and initial pollutant concentration. The most efficient C-Fe codoped catalyst was found to effectively destruct synthetic dyes and potentially treat real textile effluent achieving 93.4% of COD removal under minimal solar intensity (35-40 kiloLUX). This reveals the practical applicability of the process for the treatment of real wastewater in both high and low insolation regimes.
Atchudan, Raji,Edison, Thomas Nesakumar Jebakumar Immanuel,Perumal, Suguna,Shanmugam, Mani,Lee, Yong Rok Elsevier Sequoia 2017 Journal of photochemistry and photobiology Chemist Vol. No.
<P><B>Abstract</B></P> <P>Zinc oxide nanoparticles decorated graphene oxide (ZnO@GO) nanocomposite was successfully prepared using graphene oxide (GO) and zinc oxide nanoparticles (ZnO NPs) as raw materials by simple solvothermal method. The X-ray diffraction pattern, X-ray photoelectron spectroscopic, Fourier transform infrared spectroscopic, and Raman spectroscopic techniques revealed the formation, elemental composition and the purity of ZnO NPs and ZnO@GO nanocomposite. The ZnO NPs were synthesized via simple thermal oxidation, the synthesized ZnO NPs exhibits an excellent near spherical shape with narrow size distribution and mean size of around 20±5nm which is vividly observed from field emission scanning electron microscopic images. The elemental compositions of ZnO@GO nanocomposite which carbon, oxygen and zinc were revealed by XPS and EDX elemental mapping. The ZnO NPs decorated on GO layers were clearly seen in the high resolution transmission electron microscopic images. The photocatalytic activities of the synthesized pure ZnO NPs and ZnO@GO nanocomposite were investigated by photodegradation of azo-dyes includes neutral red (NR), crystal violet (CV), congo red (CR) and methyl orange (MO) under UV-light irradiation. The results revealed that the ZnO@GO nanocomposite exhibited a remarkably higher photocatalytic efficiency compared to pure ZnO NPs. The enhancement of photocatalytic performance was ascribed to the synergistic effect between ZnO NPs and GO layers. Hence, the synthesized ZnO@GO nanocomposite crucial for efficient degradation of dyes such as NR, CV, CR and MO. The synthesized ZnO@GO nanocomposite exhibits a good photocatalytic activity along with good reproducibility of photodegradation, which is applicable for practical applications.</P> <P><B>Highlights</B></P> <P> <UL> <LI> ZnO@GO nanocomposite was successfully synthesized by facile solvothermal route. </LI> <LI> The ZnO@GO nanocomposite showed excellent photocatalytic activity on azo-dyes. </LI> <LI> This photocatalyst achieves a maximum degradation of ∼100% on NR and CV solution. </LI> <LI> This method of synthesis was an affordable and introduced highly active photocatalyst. </LI> <LI> ZnO@GO exhibits a good reproducibility, which applicable for practical applications. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Atchudan, Raji,Edison, Thomas Nesakumar Jebakumar Immanuel,Aseer, Kanikkai Raja,Perumal, Suguna,Lee, Yong Rok Elsevier 2018 Colloids and Surfaces B Vol.169 No.-
<P><B>Abstract</B></P> <P>The present work illustrates the potential uses of nitrogen-doped multi-fluorescent carbon dots (N-CDs) for Fe<SUP>3+</SUP> sensing, cellular multi-colour imaging, and fluorescent ink. N-CDs were synthesized using <I>Magnolia liliiflora</I> flower by the simple hydrothermal method. The resulted N-CDs was found to be nearly spherical in shape with the size of about 4 ± 1 nm and showed competitive quantum yield around 11%. The synthesized N-CDs with uniform size distribution and high content of nitrogen and oxygen-bearing functional groups exhibit excellent dispersibility in aqueous media. The N-CDs were able to detect a high concentration of Fe<SUP>3+</SUP> ions (1–1000 μM) with a limit of detection is about 1.2 μM by forming N-CDs-Fe<SUP>3+</SUP> complex due to the functional groups such as nitrogen, carbonyl and carboxyl on the surface of N-CDs. Thus they could be used to remove pollutants from industrial wastewater. The electronic charge on the surface of the N-CDs and N-CDs-Fe<SUP>3+</SUP> complex (zeta potential) is around −36 and 18 mV, respectively. In addition, these N-CDs show excitation-dependent fluorescence that was utilized for multi-colour in vitro cellular imaging in rat liver cells (<I>Clone 9 hepatocytes</I>). The N-CDs are rapidly uptake in the cell cytoplasm and showed high cytocompatibility on cellular morphology. Moreover, as the N-CDs possess strong fluorescence and anti-coagulation they could be utilized in fluorescent ink pens.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Hydrothermal conversion of <I>M. liliiflora</I> into N-CDs by one-pot hydrothermal method. </LI> <LI> N-CDs was applied as a fluorescent probe for the effective detection of Fe<SUP>3+</SUP> ions. </LI> <LI> N-CDs could offer a multi-colour cell imaging without any chemical modification. </LI> <LI> N-CDs was used as a fluorescent ink without any pretreatment of the sample. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>N-CDs were synthesized using <I>M. liliiflora</I> flower and were potentially utilized for the detection of Fe<SUP>3+</SUP> ions, multi-colour cellular imaging and fluorescent ink.</P> <P>[DISPLAY OMISSION]</P>